Provided is a polymerizable composition including (a) a polymerizable component comprising a diol bis(allyl carbonate) and/or a pre-polymer thereof; and (b) a polymerization initiator component including: (i) a di(C.sub.6-C.sub.10 alkyl) peroxydicarbonate, and (ii) an organic peroxide having one peroxy, one peroxycarbonate, or one peroxybenzoate group and a 1,1-dimethylalkyl group bonded to a peroxy oxygen, where (ii) comprises a molecular weight ranging from 200 to 250 g/mole, the polymerization initiator (b) is free of diisopropyl peroxydicarbonate, (i) comprises an amount ranging from 4.87% to 7.90% by weight relative to the total solids of the polymerizable composition and (ii) comprises an amount within the range defined by the following formula: (4.406X.sup.2?0.592X+0.021)?Y?(0.726X.sup.2?0.121X+0.009) where X corresponds to the weight fraction of (i) and Y corresponds to the weight fraction of (ii). Also provided is a method of making an optical article from the polymerizable composition.

Provided is a polymerizable composition including (a) a polymerizable component comprising a diol bis(allyl carbonate) and/or a pre-polymer thereof; and (b) a polymerization initiator component including: (i) a di(C.sub.6-C.sub.10 alkyl) peroxydicarbonate, and (ii) an organic peroxide having one peroxy, one peroxycarbonate, or one peroxybenzoate group and a 1,1-dimethylalkyl group bonded to a peroxy oxygen, where (ii) comprises a molecular weight ranging from 200 to 250 g/mole, the polymerization initiator (b) is free of diisopropyl peroxydicarbonate, (i) comprises an amount ranging from 4.87% to 7.90% by weight relative to the total solids of the polymerizable composition and (ii) comprises an amount within the range defined by the following formula: (4.406X.sup.2?0.592X+0.021)?Y?(0.726X.sup.2?0.121X+0.009) where X corresponds to the weight fraction of (i) and Y corresponds to the weight fraction of (ii). Also provided is a method of making an optical article from the polymerizable composition.

A polymerizable composition according to the present invention includes a compound (A) including two or more allyloxycarbonyl groups represented by Formula (1); at least one kind of polymerization initiator (B) selected from the group consisting of a peroxyketal-based radical polymerization initiator, a peroxy monocarbonate-based radical polymerization initiator, and a peroxyester-based radical polymerization initiator; and at least one kind of photochromic compound (C) selected from a naphthopyran compound group.

A polymerizable composition according to the present invention includes a compound (A) including two or more allyloxycarbonyl groups represented by Formula (1); at least one kind of polymerization initiator (B) selected from the group consisting of a peroxyketal-based radical polymerization initiator, a peroxy monocarbonate-based radical polymerization initiator, and a peroxyester-based radical polymerization initiator; and at least one kind of photochromic compound (C) selected from a naphthopyran compound group.

A polymerizable composition for an optical material of the present invention includes a compound (A) represented by General Formula (1) including two or more allyloxycarbonyl groups; an ultraviolet absorbing agent (B) represented by General Formula (i); at least one kind of radical polymerization initiator (C) selected from the group consisting of a peroxyketal-based radical polymerization initiator, a peroxymonocarbonate-based radical polymerization initiator, and a peroxyester-based radical polymerization initiator; at least one kind of dye (D) selected from an anthraquinone-based dye, a perinone-based dye, a monoazo-based dye, a diazo-based dye, and a phthalocyanine-based dye.

##STR00001##

A polymerizable composition for an optical material of the present invention includes a compound (A) represented by General Formula (1) including two or more allyloxycarbonyl groups; an ultraviolet absorbing agent (B) represented by General Formula (i); at least one kind of radical polymerization initiator (C) selected from the group consisting of a peroxyketal-based radical polymerization initiator, a peroxymonocarbonate-based radical polymerization initiator, and a peroxyester-based radical polymerization initiator; at least one kind of dye (D) selected from an anthraquinone-based dye, a perinone-based dye, a monoazo-based dye, a diazo-based dye, and a phthalocyanine-based dye.

##STR00001##

The present invention disclose a blue-light-proof optical resin lens, comprising resin monomers, a blue light absorber and a polymerization initiator; the mass ratio of the resin monomers to the blue light absorber to the polymerization initiator is 100:0.01-2.00:1.00-4.00; the resin monomers are the mixture of allyl diglycol carbonate (ADC) and polymers thereof; the blue light absorber is a benzophenone type ultraviolet light absorber and/or indole type blue light absorber; the polymerization initiator is selected from one or two of tert-butyl peroxy-2-ethylhexyl carbonate, tert-amyl peroxy-2-ethylhexyl carbonate and 1,1-di-(tert-butylperoxy)-3,3,5-trimethylcyclo hexane. A preparation method includes the following steps: weighing the resin monomers, the blue light absorber and the polymerization initiator by ratio, sealing the mixture at room temperature, uniformly stirring the mixture at vacuum, filtering the stirred mixture with a filter core, and then vacuuming; (2) immediate pouring, molding by thermocuring; (3) mold opening, washing the obtained product; (4) annealing the obtained product, and inspecting the product. The blue-light-proof optical resin lens prepared by the method has a blue light absorbency (380-500 nm) of 15%-40%.

The present invention disclose a blue-light-proof optical resin lens, comprising resin monomers, a blue light absorber and a polymerization initiator; the mass ratio of the resin monomers to the blue light absorber to the polymerization initiator is 100:0.01-2.00:1.00-4.00; the resin monomers are the mixture of allyl diglycol carbonate (ADC) and polymers thereof; the blue light absorber is a benzophenone type ultraviolet light absorber and/or indole type blue light absorber; the polymerization initiator is selected from one or two of tert-butyl peroxy-2-ethylhexyl carbonate, tert-amyl peroxy-2-ethylhexyl carbonate and 1,1-di-(tert-butylperoxy)-3,3,5-trimethylcyclo hexane. A preparation method includes the following steps: weighing the resin monomers, the blue light absorber and the polymerization initiator by ratio, sealing the mixture at room temperature, uniformly stirring the mixture at vacuum, filtering the stirred mixture with a filter core, and then vacuuming; (2) immediate pouring, molding by thermocuring; (3) mold opening, washing the obtained product; (4) annealing the obtained product, and inspecting the product. The blue-light-proof optical resin lens prepared by the method has a blue light absorbency (380-500 nm) of 15%-40%.

An exemplary polymerizable composition includes the reaction product of (a) diethyleneglycol bischloroformate; (b) allyl alcohol; (c) a cyclic polyol selected from the group consisting of a cycloaliphatic polyol having at least one secondary hydroxyl group, a heterocyclic polyol having primary and/or secondary hydroxyl groups, and mixtures thereof; (d) optionally, ethyleneglycol bischloroformate; and (e) optionally, at least one linear or branched aliphatic polyol having two to six hydroxyl groups. Another exemplary polymerizable composition includes the reaction product of (a) allyl alcohol; (b) a cyclic polyol selected from the group consisting of a cycloaliphatic polyol having at least one secondary hydroxyl group, a heterocyclic polyol having primary and/or secondary hydroxyl groups, and mixtures thereof; (c) ethyleneglycol bischloroformate; and (d) optionally, at least one linear or branched aliphatic polyol having two to six hydroxyl groups is also described. A reaction product, a polymerizate including the polymerizable composition, and an optical article including the polymerizable composition are also provided.

A light filtering material including at least one matrix material; and semi-conductive nanoparticles which are dispersed in the matrix material. The light filtering material has: a local maximum absorbance of highest wavelength in the range from 350 to 500 nm, the local maximum has an absorbance value A.sub.max for a wavelength .sub.max; a value of 0.9A.sub.max for a wavelength .sub.0.9, .sub.0.9 being greater than .sub.max; a value of 0.5A.sub.max for a wavelength .sub.0.5, .sub.0.5 being greater than .sub.0.9; and |.sub.0.5.sub.0.9| is less than 15 nm.