The present disclosure relates to a polyethylene, which is reacted with chlorine to prepare a chlorinated polyethylene having improved tensile strength and excellent processability during extrusion by optimizing a low molecular region in a molecular structure, and a CPE compound including the same.

The present disclosure relates to a polyethylene, which is reacted with chlorine to prepare a chlorinated polyethylene having improved tensile strength and excellent processability during extrusion by optimizing a low molecular region in a molecular structure, and a CPE compound including the same.

The present disclosure relates to a polyethylene, which is reacted with chlorine to prepare a chlorinated polyethylene having improved tensile strength and excellent processability during extrusion by optimizing a low molecular region in a molecular structure, and a CPE compound including the same.

A nonlimiting example method of forming highly spherical carbon nanomaterial-graft-polyolefin (CNM-g-polyolefin) particles may comprising: mixing a mixture comprising: (a) a CNM-g-polyolefin comprising a polyolefin grafted to a carbon nanomaterial, (b) a carrier fluid that is immiscible with the polyolefin of the CNM-g-polyolefin, optionally (c) a thermoplastic polymer not grafted to a CNM, and optionally (d) an emulsion stabilizer at a temperature greater than a melting point or softening temperature of the polyolefin of the CNM-g-polyolefin and the thermoplastic polymer, when included, and at a shear rate sufficiently high to disperse the CNM-g-polyolefin in the carrier fluid; cooling the mixture to below the melting point or softening temperature to form the CNM-g-polyolefin particles; and separating the CNM-g-polyolefin particles from the carrier fluid.

A nonlimiting example method of forming highly spherical carbon nanomaterial-graft-polyolefin (CNM-g-polyolefin) particles may comprising: mixing a mixture comprising: (a) a CNM-g-polyolefin comprising a polyolefin grafted to a carbon nanomaterial, (b) a carrier fluid that is immiscible with the polyolefin of the CNM-g-polyolefin, optionally (c) a thermoplastic polymer not grafted to a CNM, and optionally (d) an emulsion stabilizer at a temperature greater than a melting point or softening temperature of the polyolefin of the CNM-g-polyolefin and the thermoplastic polymer, when included, and at a shear rate sufficiently high to disperse the CNM-g-polyolefin in the carrier fluid; cooling the mixture to below the melting point or softening temperature to form the CNM-g-polyolefin particles; and separating the CNM-g-polyolefin particles from the carrier fluid.

A method comprising a) contacting a solvent, a carboxylic acid, and a peroxide-containing compound to form an acidic mixture wherein a weight ratio of solvent to carboxylic acid in the acidic mixture is from about 1:1 to about 100:1; b) contacting a titanium-containing compound and the acidic mixture to form a solubilized titanium mixture wherein an equivalent molar ratio of titanium-containing compound to carboxylic acid in the solubilized titanium mixture is from about 1:1 to about 1:4 and an equivalent molar ratio of titanium-containing compound to peroxide-containing compound in the solubilized titanium mixture is from about 1:1 to about 1:20; and c) contacting a chromium-silica support comprising from about 0.1 wt. % to about 20 wt. % water and the solubilized titanium mixture to form an addition product and drying the addition product by heating to a temperature in a range of from about 50° C. to about 150° C. and maintaining the temperature in the range of from about 50° C. to about 150° C. for a time period of from about 30 minutes to about 6 hours to form a pre-catalyst.

A method comprising a) contacting a solvent, a carboxylic acid, and a peroxide-containing compound to form an acidic mixture wherein a weight ratio of solvent to carboxylic acid in the acidic mixture is from about 1:1 to about 100:1; b) contacting a titanium-containing compound and the acidic mixture to form a solubilized titanium mixture wherein an equivalent molar ratio of titanium-containing compound to carboxylic acid in the solubilized titanium mixture is from about 1:1 to about 1:4 and an equivalent molar ratio of titanium-containing compound to peroxide-containing compound in the solubilized titanium mixture is from about 1:1 to about 1:20; and c) contacting a chromium-silica support comprising from about 0.1 wt. % to about 20 wt. % water and the solubilized titanium mixture to form an addition product and drying the addition product by heating to a temperature in a range of from about 50° C. to about 150° C. and maintaining the temperature in the range of from about 50° C. to about 150° C. for a time period of from about 30 minutes to about 6 hours to form a pre-catalyst.

The present disclosure provides borate or aluminate activators comprising cations having linear alkyl groups, catalyst systems comprising, and methods for polymerizing olefins using such activators.

The present disclosure provides borate or aluminate activators comprising cations having linear alkyl groups, catalyst systems comprising, and methods for polymerizing olefins using such activators.

Compression blow formed articles having improved barrier properties and methods of making the same are provided herein.