Metallocene complexes represented by the structure below are useful for alpha olefin oligomerization in the presence of an activator to generate polyalphaolefins having a high percentage of vinylidene termination and relatively low Mn values. ##STR00001##
M is a group 4 transition metal. A is a bridging group having one bridging atom extending between a first indenyl ring and a second indenyl ring. Each X is independently an anionic ligand, or two Xs are joined and bound to M to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand. R.sup.1, R.sup.1′, R.sup.3, R.sup.3′, R.sup.4, R.sup.4′, R.sup.7 and R.sup.7′ are hydrogen. R.sup.5, R.sup.5′, R.sup.6, and R.sup.6′ are independently a C.sub.1-C.sub.10, optionally substituted, hydrocarbyl group, or R.sup.5 and R.sup.6 and/or R.sup.5′ and R.sup.6′ are bonded together to form an optionally substituted hydrocarbyl ring structure.

Metallocene complexes represented by the structure below are useful for alpha olefin oligomerization in the presence of an activator to generate polyalphaolefins having a high percentage of vinylidene termination and relatively low Mn values. ##STR00001##
M is a group 4 transition metal. A is a bridging group having one bridging atom extending between a first indenyl ring and a second indenyl ring. Each X is independently an anionic ligand, or two Xs are joined and bound to M to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand. R.sup.1, R.sup.1′, R.sup.3, R.sup.3′, R.sup.4, R.sup.4′, R.sup.7 and R.sup.7′ are hydrogen. R.sup.5, R.sup.5′, R.sup.6, and R.sup.6′ are independently a C.sub.1-C.sub.10, optionally substituted, hydrocarbyl group, or R.sup.5 and R.sup.6 and/or R.sup.5′ and R.sup.6′ are bonded together to form an optionally substituted hydrocarbyl ring structure.

A spray-dried zirconocene catalyst system comprising a zirconocene catalyst and a hydrophobic fumed silica, which supports the zirconocene catalyst. A spray-drying method of making same. Polyolefins; methods of making and using same; and articles containing same.

Process for obtaining polyethylene with an MFI (190° C./2.16 kg) of at least 4 g/10 minutes and a melt strength (190° C.) of at least 8.0 cN, said process involving extrusion of low density polyethylene (LDPE) with an MFI of at least 5 g/10 minutes and a vinyl content of less than 0.25 terminal vinyl groups per 1000 C-atoms (measured with NMR in deuterated tetrachloroethane solution)—in the presence of 500-5,000 ppm, based on the weight of low density polyethylene, of an organic peroxide.

Process for obtaining polyethylene with an MFI (190° C./2.16 kg) of at least 4 g/10 minutes and a melt strength (190° C.) of at least 8.0 cN, said process involving extrusion of low density polyethylene (LDPE) with an MFI of at least 5 g/10 minutes and a vinyl content of less than 0.25 terminal vinyl groups per 1000 C-atoms (measured with NMR in deuterated tetrachloroethane solution)—in the presence of 500-5,000 ppm, based on the weight of low density polyethylene, of an organic peroxide.

Process for obtaining polyethylene with an MFI (190° C./2.16 kg) of at least 4 g/10 minutes and a melt strength (190° C.) of at least 8.0 cN, said process involving extrusion of low density polyethylene (LDPE) with an MFI of at least 5 g/10 minutes and a vinyl content of less than 0.25 terminal vinyl groups per 1000 C-atoms (measured with NMR in deuterated tetrachloroethane solution)—in the presence of 500-5,000 ppm, based on the weight of low density polyethylene, of an organic peroxide.

Methods and (articles of manufacture therefrom) including forming an elastic film from a polymer composition; tensioning the elastic film to a stretch ratio of between 2 and 6 in the MD; laminating the elastic film to an extensible facing to provide an elastomeric laminate having a CD hysteresis loss of 70% or less and an MD hysteresis loss of 50% or less.

There is provided a method for preparing a metallocene-supported catalyst that exhibits catalytic activity, and yet, can decrease fine generation, and thus, can minimize fouling and chunk generation, and can stably prepare polyethylene having excellent properties.

There is provided a method for preparing a metallocene-supported catalyst that exhibits catalytic activity, and yet, can decrease fine generation, and thus, can minimize fouling and chunk generation, and can stably prepare polyethylene having excellent properties.

A biaxially-oriented film for thermoforming is disclosed including at least 75% by weight polyethylene and at least 95% by weight polyolefins, based on the total mass of the film. The polyethylene has an elongation at break of at least 7 in the stress-strain diagram, wherein the stress-strain diagram is measured at a temperature of 10° C. below the melting point of the polyethylene and the melting point is determined by differential scanning calorimetry using a heating rate of 10° C. per minute. A process for producing such films and to the use thereof are disclosed. A process for producing shaped bodies from such films and to the shaped bodies themselves are disclosed.