Patent classifications
C08F110/14
NEW POLYOLEFIN CATALYST AND USE THEREOF
Disclosed is a new polyolefin catalyst and preparation therefor. Specifically, disclosed is a catalytic system comprising a new complex of iron, cobalt, nickel, palladium, and platinum. In the presence of the catalytic system, oily polyethylene can be efficiently obtained from simple olefins such as ethylene under mild conditions, highly branched oily alkane mixture is then obtained after hydrogenation. The alkane mixture can be used as a processing aid and a high-performance lubricant base oil. The present invention also provides a method for preparing the catalyst, a method for preparing the highly branched oily alkane mixture and a method for preparing functional polyolefin oil.
NEW POLYOLEFIN CATALYST AND USE THEREOF
Disclosed is a new polyolefin catalyst and preparation therefor. Specifically, disclosed is a catalytic system comprising a new complex of iron, cobalt, nickel, palladium, and platinum. In the presence of the catalytic system, oily polyethylene can be efficiently obtained from simple olefins such as ethylene under mild conditions, highly branched oily alkane mixture is then obtained after hydrogenation. The alkane mixture can be used as a processing aid and a high-performance lubricant base oil. The present invention also provides a method for preparing the catalyst, a method for preparing the highly branched oily alkane mixture and a method for preparing functional polyolefin oil.
Process for the production of end-saturated polyalfaolefin lubricants
This invention relates to novel and improved catalyst and catalysts systems for the oligomerization of the higher olefins, which produce lubricants having improved properties, such as end-saturated oligomer chains which are needless to hydrogenation process, low kinematic viscosity and/or high viscosity index, low pour point, and high flash point lubricants.
Process for the production of end-saturated polyalfaolefin lubricants
This invention relates to novel and improved catalyst and catalysts systems for the oligomerization of the higher olefins, which produce lubricants having improved properties, such as end-saturated oligomer chains which are needless to hydrogenation process, low kinematic viscosity and/or high viscosity index, low pour point, and high flash point lubricants.
Process for the production of end-saturated polyalfaolefin lubricants
This invention relates to novel and improved catalyst and catalysts systems for the oligomerization of the higher olefins, which produce lubricants having improved properties, such as end-saturated oligomer chains which are needless to hydrogenation process, low kinematic viscosity and/or high viscosity index, low pour point, and high flash point lubricants.
NOVEL METALLOCENE COMPOUND, CATALYST COMPOSITION COMPRISING THE SAME, AND METHOD FOR PREPARING OLEFIN POLYMER USING THE SAME
This invention relates to a novel metallocene compound, a catalyst composition comprising the metallocene compound, and a method for preparing olefin polymer using the catalyst composition.
NOVEL METALLOCENE COMPOUND, CATALYST COMPOSITION COMPRISING THE SAME, AND METHOD FOR PREPARING OLEFIN POLYMER USING THE SAME
This invention relates to a novel metallocene compound, a catalyst composition comprising the metallocene compound, and a method for preparing olefin polymer using the catalyst composition.
PROCESS FOR PRODUCING OLEFIN POLYMER AND OLEFIN POLYMER
[Problem to be Solved]
There is provided a process for producing an olefin polymer that is capable of producing an olefin polymer having high heat resistance and high molecular weight with excellent catalytic activity.
[Solution to Problem]
The process for producing an olefin polymer includes a step of polymerizing at least one olefin selected from ethylene and α-olefins having 4 to 30 carbon atoms in the presence of an olefin polymerization catalyst containing a transition metal compound represented by the general formula [I], the olefin polymer including constituent units derived from ethylene and α-olefins having 4 to 30 carbon atoms in a total amount between more than 50 mol % and not more than 100 mol %,
##STR00001##
[in the formula [I], R.sup.1, R.sup.3 and R.sup.5 to R.sup.16 are each independently a hydrogen atom, a hydrocarbon group or the like; R.sup.2 is a hydrocarbon group or the like; R.sup.4 is a hydrogen atom; M is a transition metal of Group IV; Q is a halogen atom or the like; and j is an integer of 1 to 4].
PROCESS FOR PRODUCING OLEFIN POLYMER AND OLEFIN POLYMER
[Problem to be Solved]
There is provided a process for producing an olefin polymer that is capable of producing an olefin polymer having high heat resistance and high molecular weight with excellent catalytic activity.
[Solution to Problem]
The process for producing an olefin polymer includes a step of polymerizing at least one olefin selected from ethylene and α-olefins having 4 to 30 carbon atoms in the presence of an olefin polymerization catalyst containing a transition metal compound represented by the general formula [I], the olefin polymer including constituent units derived from ethylene and α-olefins having 4 to 30 carbon atoms in a total amount between more than 50 mol % and not more than 100 mol %,
##STR00001##
[in the formula [I], R.sup.1, R.sup.3 and R.sup.5 to R.sup.16 are each independently a hydrogen atom, a hydrocarbon group or the like; R.sup.2 is a hydrocarbon group or the like; R.sup.4 is a hydrogen atom; M is a transition metal of Group IV; Q is a halogen atom or the like; and j is an integer of 1 to 4].
PROCESS FOR PRODUCING OLEFIN POLYMER AND OLEFIN POLYMER
[Problem to be Solved]
There is provided a process for producing an olefin polymer that is capable of producing an olefin polymer having high heat resistance and high molecular weight with excellent catalytic activity.
[Solution to Problem]
The process for producing an olefin polymer includes a step of polymerizing at least one olefin selected from ethylene and α-olefins having 4 to 30 carbon atoms in the presence of an olefin polymerization catalyst containing a transition metal compound represented by the general formula [I], the olefin polymer including constituent units derived from ethylene and α-olefins having 4 to 30 carbon atoms in a total amount between more than 50 mol % and not more than 100 mol %,
##STR00001##
[in the formula [I], R.sup.1, R.sup.3 and R.sup.5 to R.sup.16 are each independently a hydrogen atom, a hydrocarbon group or the like; R.sup.2 is a hydrocarbon group or the like; R.sup.4 is a hydrogen atom; M is a transition metal of Group IV; Q is a halogen atom or the like; and j is an integer of 1 to 4].