Patent classifications
C08F116/12
NEW PHENOLIC POLYMERS AND PREPARATION PROCESSES THEREOF
The present invention concerns the use of a compound having the following formula (I), for the preparation of a polymer. The present invention also concerns the polymers obtained from polymerization of compound of formula (I), and their processes of preparation.
##STR00001##
NEW PHENOLIC POLYMERS AND PREPARATION PROCESSES THEREOF
The present invention concerns the use of a compound having the following formula (I), for the preparation of a polymer. The present invention also concerns the polymers obtained from polymerization of compound of formula (I), and their processes of preparation.
##STR00001##
Reactive surfactant composition for emulsion polymerization
The present invention is concerned with a reactive surfactant composition for emulsion polymerization, which is able to micronize the particle diameter of a polymer emulsion and to reduce the addition amount of the reactive surfactant composition to be used. The reactive surfactant composition for emulsion polymerization of the present invention contains a reactive anionic surfactant (component A) represented by the following formula (I): ##STR00001##
wherein AO represents an alkyleneoxy group having a carbon number of 3 or more and 18 or less; EO represents an ethyleneoxy group; p represents an integer of 1 or more and 15 or less; m′ represents an integer of 0 or more; n′ represents an integer of 0 or more; M.sup.+ represents a hydrogen ion or a cation; and plural kinds of AOs may coexist.
Reactive surfactant composition for emulsion polymerization
The present invention is concerned with a reactive surfactant composition for emulsion polymerization, which is able to micronize the particle diameter of a polymer emulsion and to reduce the addition amount of the reactive surfactant composition to be used. The reactive surfactant composition for emulsion polymerization of the present invention contains a reactive anionic surfactant (component A) represented by the following formula (I): ##STR00001##
wherein AO represents an alkyleneoxy group having a carbon number of 3 or more and 18 or less; EO represents an ethyleneoxy group; p represents an integer of 1 or more and 15 or less; m′ represents an integer of 0 or more; n′ represents an integer of 0 or more; M.sup.+ represents a hydrogen ion or a cation; and plural kinds of AOs may coexist.
LIQUID CRYSTALLINE GEL-BASED PHOTOVOLTAIC DEVICES
A photovoltaic device including an interconnecting liquid crystalline polymer network is described. The interconnecting liquid crystalline polymer network is formed using a process including polymerizing a mixture of components with linear or lathe-shaped molecules terminated with two or more crosslinking groups and one or more non-polymerizable liquid crystalline components. The linear or lathe-shaped molecules terminated with two or more crosslinking groups include flexible spacers connecting chromophoric molecular cores to each of the crosslinking groups. The components with linear or lathe-shaped molecules terminated with two or more crosslinking groups make up between twenty and forty percent of said mixture. At least two of the components with linear or lathe-shaped molecules have the same chromophoric core and each of these components make up ten percent or less of said mixture. Subsequently one or more non-polymerizable liquid crystalline components are removed from the polymerized mixture and then replaced with a polymerizable material.
LIQUID CRYSTALLINE GEL-BASED PHOTOVOLTAIC DEVICES
A photovoltaic device including an interconnecting liquid crystalline polymer network is described. The interconnecting liquid crystalline polymer network is formed using a process including polymerizing a mixture of components with linear or lathe-shaped molecules terminated with two or more crosslinking groups and one or more non-polymerizable liquid crystalline components. The linear or lathe-shaped molecules terminated with two or more crosslinking groups include flexible spacers connecting chromophoric molecular cores to each of the crosslinking groups. The components with linear or lathe-shaped molecules terminated with two or more crosslinking groups make up between twenty and forty percent of said mixture. At least two of the components with linear or lathe-shaped molecules have the same chromophoric core and each of these components make up ten percent or less of said mixture. Subsequently one or more non-polymerizable liquid crystalline components are removed from the polymerized mixture and then replaced with a polymerizable material.
REACTIVE SURFACTANT COMPOSITION FOR EMULSION POLYMERIZATION
The present invention is concerned with a reactive surfactant composition for emulsion polymerization, which is able to micronize the particle diameter of a polymer emulsion and to reduce the addition amount of the reactive surfactant composition to be used.
The reactive surfactant composition for emulsion polymerization of the present invention contains a reactive anionic surfactant (component A) represented by the following formula (I), the component A being satisfied with the following requirement R:
##STR00001## wherein AO represents an alkyleneoxy group having a carbon number of 3 or more and 18 or less; E represents an ethyleneoxy group; p represents an integer of 1 or more and 15 or less; m represents an integer of 0 or more; n represents an integer of 0 or more; M.sup.+ represents a hydrogen ion or a cation; and plural kinds of AOs may coexist.
Requirement R: An average addition molar number m of AO is a number of 1 or more and 50 or less; an average addition molar number n of EO is a number of 0 or more and 200 or less; and when in the component A, a component having an addition molar number of AO of (m3) or less is defined as (component A-1), and a component having an addition molar number of AO of (m+2) or more is defined as (component A-2), X in the following formula (I) is less than 30, provided that when m is less than 3, (m=0) is defined as (component A-1):
X={(molar number of component A-1)+(molar number of component A-2)}(molar number of component A)100(I).
REACTIVE SURFACTANT COMPOSITION FOR EMULSION POLYMERIZATION
The present invention is concerned with a reactive surfactant composition for emulsion polymerization, which is able to micronize the particle diameter of a polymer emulsion and to reduce the addition amount of the reactive surfactant composition to be used.
The reactive surfactant composition for emulsion polymerization of the present invention contains a reactive anionic surfactant (component A) represented by the following formula (I), the component A being satisfied with the following requirement R:
##STR00001## wherein AO represents an alkyleneoxy group having a carbon number of 3 or more and 18 or less; E represents an ethyleneoxy group; p represents an integer of 1 or more and 15 or less; m represents an integer of 0 or more; n represents an integer of 0 or more; M.sup.+ represents a hydrogen ion or a cation; and plural kinds of AOs may coexist.
Requirement R: An average addition molar number m of AO is a number of 1 or more and 50 or less; an average addition molar number n of EO is a number of 0 or more and 200 or less; and when in the component A, a component having an addition molar number of AO of (m3) or less is defined as (component A-1), and a component having an addition molar number of AO of (m+2) or more is defined as (component A-2), X in the following formula (I) is less than 30, provided that when m is less than 3, (m=0) is defined as (component A-1):
X={(molar number of component A-1)+(molar number of component A-2)}(molar number of component A)100(I).
Branching-type polyoxyethylene compound and contact lens
Provided is a silicone contact lens having surface hydrophilicity and surface lubricity. The silicone contact lens includes, on its surface, a graft polymer chain derived from a branched polyoxyethylene compound represented by the formula (1): ##STR00001##
where n represents from 3 to 1,150, a represents 0 or 2, and R.sup.1 represents a hydrogen atom or a methyl group.
Branching-type polyoxyethylene compound and contact lens
Provided is a silicone contact lens having surface hydrophilicity and surface lubricity. The silicone contact lens includes, on its surface, a graft polymer chain derived from a branched polyoxyethylene compound represented by the formula (1): ##STR00001##
where n represents from 3 to 1,150, a represents 0 or 2, and R.sup.1 represents a hydrogen atom or a methyl group.