Patent classifications
C08F116/12
Method for producing vinyl ether polymer having hydroxyl group on side chain and temperature-responsive polymer mixture
[Object] To provide a method for producing a vinyl ether polymer having a hydroxyl group on the side chain, wherein the vinyl ether polymer having a low viscosity and excellent workability and processability is produced in a simple and efficient method. [Means for solving problem] The present invention relates to a method for producing a vinyl ether polymer having a hydroxyl group on the side chain, characterized in that vinyl ether comprising a hydroxyl group is subjected to radical polymerization by using an oil-soluble azo polymerization initiator, in the presence of a mixed solvent comprising water and an organic solvent selected from alcohol or cyclic ether radical polymerization.
Method for producing vinyl ether polymer having hydroxyl group on side chain and temperature-responsive polymer mixture
[Object] To provide a method for producing a vinyl ether polymer having a hydroxyl group on the side chain, wherein the vinyl ether polymer having a low viscosity and excellent workability and processability is produced in a simple and efficient method. [Means for solving problem] The present invention relates to a method for producing a vinyl ether polymer having a hydroxyl group on the side chain, characterized in that vinyl ether comprising a hydroxyl group is subjected to radical polymerization by using an oil-soluble azo polymerization initiator, in the presence of a mixed solvent comprising water and an organic solvent selected from alcohol or cyclic ether radical polymerization.
Charge transport layer and organic photoelectronic element
To provide a charge transport layer excellent in the external quantum efficiency, and an organic photoelectronic element comprising the charge transport layer. A charge transport layer comprising a film containing a fluorinated polymer and a semiconductor material, wherein the film has a material composition such that E.sub.th is within a range of from 0.010 to 0.080 MV/cm. An organic photoelectronic element comprising the charge transport layer.
VINYL ETHER-BASED INKJET INK PHOTOPOLYMERIZED BY THIOL-ENE CLICK CHEMISTRY USED FOR TOUGHENING OF PHOTOPOLYMERS
The present disclosure provides a range of printed materials comprising discrete layers or segment with distinct compositions, and which can collectively lend to high levels of strength, toughness, and break resistance, and these printed materials may contain thin, ductile layers interspersed between thicker, harder layers, thus in printing such materials, the present disclosure further provides a range of compositions and methods, including low viscosity, air stable, and rapidly solutions amenable to thin layer inkjet printing.
CHARGE TRANSPORT LAYER AND ORGANIC PHOTOELECTRONIC ELEMENT
To provide a charge transport layer excellent in the external quantum efficiency, and an organic photoelectronic element comprising the charge transport layer.
A charge transport layer comprising a film containing a fluorinated polymer and a semiconductor material, wherein the film has a material composition such that E.sub.th is within a range of from 0.010 to 0.080 MV/cm. An organic photoelectronic element comprising the charge transport layer.
REACTIVE SURFACTANT COMPOSITION FOR EMULSION POLYMERIZATION
The present invention is concerned with a reactive surfactant composition for emulsion polymerization, which is able to micronize the particle diameter of a polymer emulsion and to reduce the addition amount of the reactive surfactant composition to be used.
The reactive surfactant composition for emulsion polymerization of the present invention contains a reactive anionic surfactant (component A) represented by the following formula (I), the component A being satisfied with the following requirement R:
##STR00001## wherein AO represents an alkyleneoxy group having a carbon number of 3 or more and 18 or less; EO represents an ethyleneoxy group; p represents an integer of 1 or more and 15 or less; m represents an integer of 0 or more; n represents an integer of 0 or more; W represents a hydrogen ion or a cation; and plural kinds of AOs may coexist.
Requirement R: An average addition molar number m of AO is a number of 1 or more and 50 or less; an average addition molar number n of EO is a number of 0 or more and 200 or less; and when in the component A, a component having an addition molar number of AO of (m3) or less is defined as (component A-1), and a component having an addition molar number of AO of (m+2) or more is defined as (component A-2), X in the following formula (I) is less than 30, provided that when m is less than 3, (m=0) is defined as (component A-1):
X={(molar number of component A-1)+(molar number of component A-2)}(molar number of component A)100(I).
REACTIVE SURFACTANT COMPOSITION FOR EMULSION POLYMERIZATION
The present invention is concerned with a reactive surfactant composition for emulsion polymerization, which is able to micronize the particle diameter of a polymer emulsion and to reduce the addition amount of the reactive surfactant composition to be used.
The reactive surfactant composition for emulsion polymerization of the present invention contains a reactive anionic surfactant (component A) represented by the following formula (I), the component A being satisfied with the following requirement R:
##STR00001## wherein AO represents an alkyleneoxy group having a carbon number of 3 or more and 18 or less; EO represents an ethyleneoxy group; p represents an integer of 1 or more and 15 or less; m represents an integer of 0 or more; n represents an integer of 0 or more; W represents a hydrogen ion or a cation; and plural kinds of AOs may coexist.
Requirement R: An average addition molar number m of AO is a number of 1 or more and 50 or less; an average addition molar number n of EO is a number of 0 or more and 200 or less; and when in the component A, a component having an addition molar number of AO of (m3) or less is defined as (component A-1), and a component having an addition molar number of AO of (m+2) or more is defined as (component A-2), X in the following formula (I) is less than 30, provided that when m is less than 3, (m=0) is defined as (component A-1):
X={(molar number of component A-1)+(molar number of component A-2)}(molar number of component A)100(I).
BRANCHING-TYPE POLYOXYETHYLENE COMPOUND AND CONTACT LENS
Provided is a silicone contact lens having surface hydrophilicity and surface lubricity. The silicone contact lens includes, on its surface, a graft polymer chain derived from a branched polyoxyethylene compound represented by the formula (1):
##STR00001##
where n represents from 3 to 1,150, a represents 0 or 2, and R.sup.1 represents a hydrogen atom or a methyl group.
Ultraviolet-light-emitting device with adhesive having low glass transition temperature
Provided is an adhesive for use in an ultraviolet-light-emitting device using ultraviolet light having a wavelength of from 200 to 400 nm as a light source, which can attach adherends made of a polymer having a fluorine-containing alicyclic structure with excellent adhesiveness which is unlikely to be impaired by exposure to such ultraviolet light or heat. An adhesive for forming an adhesive joint in an ultraviolet-light-emitting device, which is either the following adhesive (A) or the following adhesive (B) comprising a fluoropolymer having a fluorine-containing alicyclic structure: the adhesive (A): an adhesive in which the glass transition temperature of the fluoropolymer is from 30 to 100 C., and which does not contain an ultraviolet-shielding agent; and the adhesive (B): an adhesive comprising the fluoropolymer and an ultraviolet-shielding agent.
METHOD FOR PRODUCING VINYL ETHER POLYMER HAVING HYDROXYL GROUP ON SIDE CHAIN AND TEMPERATURE-RESPONSIVE POLYMER MIXTURE
[Object] To provide a method for producing a vinyl ether polymer having a hydroxyl group on the side chain, wherein the vinyl ether polymer having a low viscosity and excellent workability and processability is produced in a simple and efficient method.
[Means for solving problem] The present invention relates to a method for producing a vinyl ether polymer having a hydroxyl group on the side chain, characterized in that vinyl ether comprising a hydroxyl group is subjected to radical polymerization by using an oil-soluble azo polymerization initiator, in the presence of a mixed solvent comprising water and an organic solvent selected from alcohol or cyclic ether radical polymerization.