C08F132/08

FAST PHOTOCURABLE POLYCYCLOOLEFIN COMPOSITIONS AS OPTICAL OR 3D PRINTING MATERIALS
20200377632 · 2020-12-03 · ·

Embodiments in accordance with the present invention encompass compositions encompassing a procatalyst, a photoacid generator, a photosensitizer and one or more monomers which undergo vinyl addition polymerization when said composition is exposed to suitable UV irradiation and heated to a temperature from 50 C. to 100 C. to form a substantially transparent film. The monomers employed therein have a range of refractive index from 1.4 to 1.6 and thus these compositions can be tailored to form transparent films of varied refractive indices. Accordingly, compositions of this invention are useful in various opto-electronic applications, including as coatings, encapsulants, fillers, leveling agents, among others.

Homogeneous catalysts that are recoverable by host-guest interactions

A method for separating a homogeneous catalyst from a solution includes forming a host-guest compound between a first isomer of the catalyst and inclusion compound in the solution and isolating the host-guest compound from the solution. The catalyst may be released from the inclusion compound by converting the first isomer of the catalyst to a second isomer of the catalyst.

Homogeneous catalysts that are recoverable by host-guest interactions

A method for separating a homogeneous catalyst from a solution includes forming a host-guest compound between a first isomer of the catalyst and inclusion compound in the solution and isolating the host-guest compound from the solution. The catalyst may be released from the inclusion compound by converting the first isomer of the catalyst to a second isomer of the catalyst.

COPOLYMER, PRODUCTION METHOD FOR COPOLYMER, RUBBER COMPOSITION, AND TIRE
20200299429 · 2020-09-24 · ·

An object of the present disclosure is to provide a copolymer containing at least an acyclic non-conjugated olefin unit and a conjugated diene unit and capable of improving an elastic modulus of a rubber composition. Specifically, the present disclosure provides a copolymer containing at least an acyclic non-conjugated olefin unit and a conjugated diene unit, wherein the difference (T.sub.emT.sub.im) between an extrapolated melting end temperature (T.sub.em) as measured in accordance with JIS K7121 and an extrapolated melting initiation temperature (T.sub.im) as measured in accordance with JIS K7121 is not higher than 60 C.

COMPOSITIONS AND METHODS FOR STEREOREGULAR RING EXPANSION METATHESIS POLYMERIZATION
20200291051 · 2020-09-17 ·

Disclosed are to metallocyclopropene complexes, methods of making same, methods for ring expansion metathesis polymerization, and polymers prepared by the methods for ring expansion metathesis polymerization.

COMPOSITIONS AND METHODS FOR STEREOREGULAR RING EXPANSION METATHESIS POLYMERIZATION
20200291051 · 2020-09-17 ·

Disclosed are to metallocyclopropene complexes, methods of making same, methods for ring expansion metathesis polymerization, and polymers prepared by the methods for ring expansion metathesis polymerization.

Water soluble homogeneous catalysts that are recoverable by phase selectivity and host-guest interactions

A chemical reaction is catalyzed in an organic solvent using a water soluble N-heterocyclic carbene homogeneous catalyst to form a reaction mixture. An aqueous phase in the reaction mixture. A solvent in which the catalyst is insoluble is added to the reaction mixture, causing the catalyst to migrate to the aqueous phase to form a catalyst-laden aqueous phase. The catalyst is extracted from the catalyst-laden aqueous phase.

Water soluble homogeneous catalysts that are recoverable by phase selectivity and host-guest interactions

A chemical reaction is catalyzed in an organic solvent using a water soluble N-heterocyclic carbene homogeneous catalyst to form a reaction mixture. An aqueous phase in the reaction mixture. A solvent in which the catalyst is insoluble is added to the reaction mixture, causing the catalyst to migrate to the aqueous phase to form a catalyst-laden aqueous phase. The catalyst is extracted from the catalyst-laden aqueous phase.

COPOLYMER, POLYMER, MOLDING MATERIAL AND RESIN MOLDED BODY

The present invention provides:

a copolymer (A) which is a copolymer obtained by copolymerizing one or plural cycloolefin monomers and one or plural acyclic olefin monomers, or a copolymer obtained by copolymerizing two or more cycloolefin monomers, wherein the glass transition temperature (Tg) of the copolymer is 100 C. or higher, the refractive index of the copolymer is 1.545 or higher, and the Abbe's number of the copolymer is 50 or larger, and at least one of the cycloolefin monomers is a deltacyclene.

COPOLYMER, POLYMER, MOLDING MATERIAL AND RESIN MOLDED BODY

The present invention provides:

a copolymer (A) which is a copolymer obtained by copolymerizing one or plural cycloolefin monomers and one or plural acyclic olefin monomers, or a copolymer obtained by copolymerizing two or more cycloolefin monomers, wherein the glass transition temperature (Tg) of the copolymer is 100 C. or higher, the refractive index of the copolymer is 1.545 or higher, and the Abbe's number of the copolymer is 50 or larger, and at least one of the cycloolefin monomers is a deltacyclene.