Embodiments of the present disclosure directed towards titanium biphenylphenol polymerization precatalysts of Formula (I).

A slurry polymerization process for the preparation of polyethylene in a reactor cascade of two or more polymerization reactors wherein monomers are polymerized in the polymerization reactors which include a reactor outlet arranged in each reactor bottom for feeding a reactor slurry to a subsequent polymerization reactor and for emptying the polymerization reactor.

A slurry polymerization process for the preparation of polyethylene in a reactor cascade of two or more polymerization reactors wherein monomers are polymerized in the polymerization reactors which include a reactor outlet arranged in each reactor bottom for feeding a reactor slurry to a subsequent polymerization reactor and for emptying the polymerization reactor.

The present invention relates to heterophasic polypropylene compositions comprising a propylene homo- or copolymer forming a crystalline fraction as a matrix and an amorphous propylene ethylene elastomer as a soluble fraction dispersed in said matrix. The heterophasic polypropylene compositions further comprise an elastomeric ethylene/alpha-olefin random copolymer. The heterophasic polypropylene compositions have a well-balanced relation between stiffness and impact strength, low volatile and semi-volatile emissions and good processability.

The present invention relates to heterophasic polypropylene compositions comprising a propylene homo- or copolymer forming a crystalline fraction as a matrix and an amorphous propylene ethylene elastomer as a soluble fraction dispersed in said matrix. The heterophasic polypropylene compositions further comprise an elastomeric ethylene/alpha-olefin random copolymer. The heterophasic polypropylene compositions have a well-balanced relation between stiffness and impact strength, low volatile and semi-volatile emissions and good processability.

The catalyst system includes a heterogeneous procatalyst, an electron donor, and a hydrogenation procatalyst. The heterogeneous procatalyst includes a titanium species, an aluminum species, and a magnesium chloride component. The hydrogenation procatalyst has the formula Cp.sub.2TiX.sub.nTiCp.sub.2 or Cp.sub.2TiX.sub.n. In formula Cp.sub.2TiX.sub.n, each Cp is a cyclopentadienyl substituted with at least one R.sup.1, wherein R.sup.1 is (C.sub.1-C.sub.10)alkyl; and each X is independently monoanionic or neutral, wherein each X is independently (C.sub.1-C.sub.40)hydrocarbon, (C.sub.1-C.sub.40)heterohydrocarbon, (C.sub.1-C.sub.40)hydrocarbyl, (C.sub.1—C.sub.40)heterohydrocarbyl, or a halogen atom.

The catalyst system includes a heterogeneous procatalyst, an electron donor, and a hydrogenation procatalyst. The heterogeneous procatalyst includes a titanium species, an aluminum species, and a magnesium chloride component. The hydrogenation procatalyst has the formula Cp.sub.2TiX.sub.nTiCp.sub.2 or Cp.sub.2TiX.sub.n. In formula Cp.sub.2TiX.sub.n, each Cp is a cyclopentadienyl substituted with at least one R.sup.1, wherein R.sup.1 is (C.sub.1-C.sub.10)alkyl; and each X is independently monoanionic or neutral, wherein each X is independently (C.sub.1-C.sub.40)hydrocarbon, (C.sub.1-C.sub.40)heterohydrocarbon, (C.sub.1-C.sub.40)hydrocarbyl, (C.sub.1—C.sub.40)heterohydrocarbyl, or a halogen atom.

A composition comprising an ethylene/alpha-olefin interpolymer that comprises the following properties: a) a total unsaturation/1000C≥0.30; b) a molecular weight distribution (MWD)≤3.0; c) a TGIC broadness parameter B.sub.1/4≤8.0. A solution N polymerization process to prepare an ethylene/alpha-olefin/interpolymer, said process comprising polymerizing, in one reactor, at a reactor temperature ≥150° C., a reaction mixture comprising ethylene, an alpha-olefin, a solvent, and a metal complex as described herein. A method to determine the TGIC broadness parameter B.sub.1/x of a polymer composition comprising one or more olefin-based polymers.

A composition comprising an ethylene/alpha-olefin interpolymer that comprises the following properties: a) a total unsaturation/1000C≥0.30; b) a molecular weight distribution (MWD)≤3.0; c) a TGIC broadness parameter B.sub.1/4≤8.0. A solution N polymerization process to prepare an ethylene/alpha-olefin/interpolymer, said process comprising polymerizing, in one reactor, at a reactor temperature ≥150° C., a reaction mixture comprising ethylene, an alpha-olefin, a solvent, and a metal complex as described herein. A method to determine the TGIC broadness parameter B.sub.1/x of a polymer composition comprising one or more olefin-based polymers.

A process to prepare an alpha composition comprising a first ethylene/alpha-olefin/interpolymer fraction and a second ethylene/alpha-olefin/interpolymer fraction; said process comprising polymerizing, in one reactor, a reaction mixture, comprising ethylene and an alpha-olefin, a biphenyl phenol metal complex selected from Structure 1, as described herein, and a biphenyl phenol metal complex selected from Structure 2, as described herein; and alpha compositions prepared therefrom.