C08F210/14

DUAL METALLOCENE BIMODAL HDPE RESINS WITH IMPROVED STRESS CRACK RESISTANCE

Ethylene-based polymers having a density from 0.94 to 0.96 g/cm.sup.3, a Mn from 5,000 to 14,000 g/mol, a ratio of Mw/Mn from 18 to 40, and at least one of a PENT value at 2.4 MPa of at least 11,500 hr and/or a W90 from 7.5 to 15 wt. % are disclosed. Additional ethylene polymers can have the same density, Mn, and Mw/Mn values, as well as a relaxation time from 0.5 to 3.5 sec, a CY-a parameter from 0.48 to 0.68, a HLMI from 5 to 11 g/10 min, a viscosity at HLMI from 3,000 to 7,500 Pa-sec, and a higher molecular weight component (HMW) and a lower molecular weight (LMW) component, in which a ratio of the number of SCBs at Mp of the HMW component to the number of SCBs at Mp of the LMW component is from 3.5 to 8.

DUAL METALLOCENE BIMODAL HDPE RESINS WITH IMPROVED STRESS CRACK RESISTANCE

Ethylene-based polymers having a density from 0.94 to 0.96 g/cm.sup.3, a Mn from 5,000 to 14,000 g/mol, a ratio of Mw/Mn from 18 to 40, and at least one of a PENT value at 2.4 MPa of at least 11,500 hr and/or a W90 from 7.5 to 15 wt. % are disclosed. Additional ethylene polymers can have the same density, Mn, and Mw/Mn values, as well as a relaxation time from 0.5 to 3.5 sec, a CY-a parameter from 0.48 to 0.68, a HLMI from 5 to 11 g/10 min, a viscosity at HLMI from 3,000 to 7,500 Pa-sec, and a higher molecular weight component (HMW) and a lower molecular weight (LMW) component, in which a ratio of the number of SCBs at Mp of the HMW component to the number of SCBs at Mp of the LMW component is from 3.5 to 8.

DRAG REDUCING AGENT

This invention relates to drag reducing agents used in case of transportation of crude oil products, in particular, to solid dry poly(meth)acrylate with dry poly alpha-olefins powders based agents. The technical result of the solution involves the preparation of an effective, fast-dissolving, stable solid dry drag reducing agent suitable for use in heavy crude oil. The drag reducing agents compositions have better drag reducing performance in heavy crude applications as compared with traditional drag reducing slurries is also disclosed, which consists of the following components, wt%: a mixture of at least two drag reducing polymers, from 65 to 90 a separating agent from 3 to 25 anti-agglomerating agent from 3 to 25 a surfactant from 3 to 25,where the first polymer is poly(meth)acrylate, the second polymer is poly alpha-olefin, the ratio of the polyacrylate weight and polyalphaolefin weight varies in the range from 2:1 to 5:1.

DRAG REDUCING AGENT

This invention relates to drag reducing agents used in case of transportation of crude oil products, in particular, to solid dry poly(meth)acrylate with dry poly alpha-olefins powders based agents. The technical result of the solution involves the preparation of an effective, fast-dissolving, stable solid dry drag reducing agent suitable for use in heavy crude oil. The drag reducing agents compositions have better drag reducing performance in heavy crude applications as compared with traditional drag reducing slurries is also disclosed, which consists of the following components, wt%: a mixture of at least two drag reducing polymers, from 65 to 90 a separating agent from 3 to 25 anti-agglomerating agent from 3 to 25 a surfactant from 3 to 25,where the first polymer is poly(meth)acrylate, the second polymer is poly alpha-olefin, the ratio of the polyacrylate weight and polyalphaolefin weight varies in the range from 2:1 to 5:1.

Polymer Composition and Methods of Making and Using Same

A bimodal polymer composition comprising a lower molecular weight homopolymer and a higher molecular weight copolymer wherein the bimodal polymer composition has a density of from about 0.930 gram per cubic centimeter (g/cc) to about 0.970 g/cc, a ratio of high load melt index:melt index of from about 10 to about 150 and an Environmental Stress Crack Resistance (ESCR) of from about 25 hours to about 300 hours when measured in accordance with ASTM D1693 or ASTM D2561. A chromium-catalyzed polymer composition comprising (i) a lower molecular weight homopolymer and (ii) a higher molecular weight copolymer, wherein the bimodal polymer composition has an Environmental Stress Crack Resistance (ESCR) of from about 25 hours to about 300 hours when measured in accordance with ASTM D1693 or ASTM D2561.

Polymer Composition and Methods of Making and Using Same

A bimodal polymer composition comprising a lower molecular weight homopolymer and a higher molecular weight copolymer wherein the bimodal polymer composition has a density of from about 0.930 gram per cubic centimeter (g/cc) to about 0.970 g/cc, a ratio of high load melt index:melt index of from about 10 to about 150 and an Environmental Stress Crack Resistance (ESCR) of from about 25 hours to about 300 hours when measured in accordance with ASTM D1693 or ASTM D2561. A chromium-catalyzed polymer composition comprising (i) a lower molecular weight homopolymer and (ii) a higher molecular weight copolymer, wherein the bimodal polymer composition has an Environmental Stress Crack Resistance (ESCR) of from about 25 hours to about 300 hours when measured in accordance with ASTM D1693 or ASTM D2561.

BLOWN FILM

Blown films, especially monolayer blown films, with an improved property profile, the blown films comprising at least 95.0 wt% of a specific heterophasic propylene copolymer (TERHECO).

BLOWN FILM

Blown films, especially monolayer blown films, with an improved property profile, the blown films comprising at least 95.0 wt% of a specific heterophasic propylene copolymer (TERHECO).

POLYMER FOR POWER CABLE INSULATION

A multimodal polyethylene composition having a lower molecular weight (LMW) ethylene homo or copolymer component (A) and a higher molecular weight ethylene copolymer component (B); wherein the lower molecular weight component comprises: (ai) a first fraction which comprises an ethylene homo or copolymer of ethylene and one or more C3-10 alpha olefins; and (aii) a N second fraction which comprises a different ethylene homo or copolymer of ethylene and one or more C3-10 alpha olefins; wherein the multimodal polymer composition has a density of 930 kg/m.sup.3 or more (ISO1183), such as 938 to 955 kg/m.sup.3, an MFR2 (ISO1133 at 190° C. and 2.16 kg load) in the range of 0.05 to 10 g/10 min, and a flexural modulus of up to 800 MPa, such as 300 to 800 MPa (ISO 178:2010).

POLYMER FOR POWER CABLE INSULATION

A multimodal polyethylene composition having a lower molecular weight (LMW) ethylene homo or copolymer component (A) and a higher molecular weight ethylene copolymer component (B); wherein the lower molecular weight component comprises: (ai) a first fraction which comprises an ethylene homo or copolymer of ethylene and one or more C3-10 alpha olefins; and (aii) a N second fraction which comprises a different ethylene homo or copolymer of ethylene and one or more C3-10 alpha olefins; wherein the multimodal polymer composition has a density of 930 kg/m.sup.3 or more (ISO1183), such as 938 to 955 kg/m.sup.3, an MFR2 (ISO1133 at 190° C. and 2.16 kg load) in the range of 0.05 to 10 g/10 min, and a flexural modulus of up to 800 MPa, such as 300 to 800 MPa (ISO 178:2010).