A method of forming a three-dimensional object comprises the steps of forming a layer of a particulate composition, selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, initiating polymerization, and repeating the steps a plurality of times to form a three-dimensional object. The particulate composition comprises a plurality of first particles that comprise a resin component comprising a first resin, the first resin comprising a first resin polymerizable group, the first resin polymerizable group comprising a carbon-carbon double bond directly attached to an electron withdrawing group, a thermal radical initiator dispersed or dissolved in the resin component, and a retardant dispersed or dissolved in the resin component.

In one aspect, a chelating phosphine-phosphonic diamide (PPDA) ligand is described herein for constructing transition metal complexes operable for catalysis of olefin polymerization, including copolymerization of ethylene with polar monomer.

In one aspect, a chelating phosphine-phosphonic diamide (PPDA) ligand is described herein for constructing transition metal complexes operable for catalysis of olefin polymerization, including copolymerization of ethylene with polar monomer.

A method of forming a three-dimensional object comprises the steps of forming a layer of a particulate composition, selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, initiating polymerization, and repeating the steps a plurality of times to form a three-dimensional object. The particulate composition comprises a plurality of first particles that comprise a resin component comprising a first resin, the first resin comprising a first resin polymerizable group, the first resin polymerizable group comprising a carbon-carbon double bond directly attached to an electron withdrawing group, a thermal radical initiator dispersed or dissolved in the resin component, and a retardant dispersed or dissolved in the resin component.

Embodiments of the disclosure generally provide methods related to articles that display reversible photoresponsive behavior.

A composition of matter includes a mixture of styrene derivative monomers and methacrylate and/or acrylate derivative monomers, which have one or more urethane, carbamate, amide, and/or amine functional groups, and initiators, and the compositions are used to achieve composition control of the forming polymer, with the mole fraction of acrylate/methacrylate and styrene moieties in the forming polymer determined by the chemistry and composition of the feeding monomers.

Provided is a photocurable composition comprising: a) at least one monomer or/and oligomer bearing at least one functional group selected from the group consisting of (meth) acrylate-functional group, vinyl-functional and allyl-functional group or at least one monomer or/and oligomer bearing at least two of said functional groups with one of them being an allyl group, b) at least one polythiol bearing at least one secondary thiol group, and c) at least one photoinitiator. The said composition can be used in coatings, inks, adhesives and varnishes. A finished cured product made of the said composition is suitable for optical, electronic and opto-electronic applications.

The present invention relates to: a sealing gel having a Mooney viscosity (ML1+4 @ 100 C.) in the range from 100 MU to 170 MU, a sealing compound comprising inventive sealing gel, a process for producing this sealing compound, the use of sealing gels for improving viscoelastic properties in sealing compounds, and the use of sealing gel-containing sealing compounds for improving rolling resistance properties in tyres having sealing layers.

The present invention relates to: a sealing gel having a Mooney viscosity (ML1+4 @ 100 C.) in the range from 100 MU to 170 MU, a sealing compound comprising inventive sealing gel, a process for producing this sealing compound, the use of sealing gels for improving viscoelastic properties in sealing compounds, and the use of sealing gel-containing sealing compounds for improving rolling resistance properties in tyres having sealing layers.

A preparation method of a powdery polycarboxylate superplasticizer is provided, including: mixing a superplasticizer monomer with water to produce a mixture, heating and melting the mixture to produce a melt system; carrying out a bulk polymerization reaction by adding an initiator, a chain transfer agent and an unsaturated carboxylic acid into the melt system, forming a polycarboxylate superplasticizer precursor; and neutralizing and pulverizing the polycarboxylate superplasticizer precursor to produce a powdery polycarboxylate superplasticizer. Water is added in the bulk polymerization and reacts with the superplasticizer monomer and the unsaturated carboxylic acid. While the bulk polymerization reaction is guaranteed to be efficiently carried out and the solid polycarboxylate superplasticizer is formed, the viscosity of a bulk polymerization reaction system is reduced. The superplasticizer is suitable for dry-mixed mortar, high-efficiency concrete and other products.