Patent classifications
C08F218/20
Acrylic rubber and crosslinkable composition thereof
An acrylic rubber that is a copolymer in which 1 to 4 wt. % of a reactive halogen group-containing vinyl monomer is copolymerized as a crosslinkable comonomer, wherein 45 to 65 wt. % of n-butyl acrylate, 10 to 35 wt. % of 2-methoxyethyl acrylate and 8 to 30 wt. % of ethoxyethoxyethyl acrylate are copolymerized in 100 wt. % of comonomers other than the crosslinkable comonomer. This ethoxyethoxyethyl acrylate-copolymerized acrylic rubber can suppress the reduction of oil resistance while improving cold resistance represented by a TR-10 value, and by compounding it with a vulcanizing agent corresponding to the crosslinkable group thereof, a crosslinkable composition is formed.
ACRYLIC RUBBER BALE EXCELLENT IN STORAGE STABILITY AND WATER RESISTANCE
An acrylic rubber bale excellent in storage stability and water resistance and a method for producing the same are provided. An acrylic rubber bale, including an acrylic rubber having a reactive group, with a specific ash content, a large proportion of magnesium and phosphorus in the ash, and a specific ratio of magnesium and phosphorus, is highly excellent in storage stability and water resistance. This acrylic rubber bale can be produced by using a specific stabilizer and a specific coagulant in an emulsion polymerization process of an acrylic rubber and performing a process from coagulation process to baling process under specific conditions.
ACRYLIC RUBBER BALE EXCELLENT IN STORAGE STABILITY AND WATER RESISTANCE
An acrylic rubber bale excellent in storage stability and water resistance and a method for producing the same are provided. An acrylic rubber bale, including an acrylic rubber having a reactive group, with a specific ash content, a large proportion of magnesium and phosphorus in the ash, and a specific ratio of magnesium and phosphorus, is highly excellent in storage stability and water resistance. This acrylic rubber bale can be produced by using a specific stabilizer and a specific coagulant in an emulsion polymerization process of an acrylic rubber and performing a process from coagulation process to baling process under specific conditions.
ACRYLIC RUBBER BALE EXCELLENT IN PROCESSABILITY AND WATER RESISTANCE
Acrylic rubber bale having remarkably improved storage stability and water resistance without deteriorating cross-linking properties, a method of production, a rubber mixture obtained by mixing the acrylic rubber bale, a method of production, and a rubber cross-linked product obtained by cross-linking the same is provided. The acrylic rubber bale includes an acrylic rubber, and the acrylic rubber is mainly composed of (meth) acrylic acid ester, and has a weight average molecular weight of 100,000 to 5,000,000, and has a ratio of a Z-average molecular weight and a weight average molecular weight of 1.3 or more, where an ash content is 0.6% by weight or less, and the ash contains a periodic table group 2 metal and phosphorus, and a phosphorus content is 10% by weight or more, and the ratio of the periodic table group 2 metal to phosphorus is in the range of 0.6 to 2 molar ratio.
ACRYLIC RUBBER BALE EXCELLENT IN PROCESSABILITY AND WATER RESISTANCE
Acrylic rubber bale having remarkably improved storage stability and water resistance without deteriorating cross-linking properties, a method of production, a rubber mixture obtained by mixing the acrylic rubber bale, a method of production, and a rubber cross-linked product obtained by cross-linking the same is provided. The acrylic rubber bale includes an acrylic rubber, and the acrylic rubber is mainly composed of (meth) acrylic acid ester, and has a weight average molecular weight of 100,000 to 5,000,000, and has a ratio of a Z-average molecular weight and a weight average molecular weight of 1.3 or more, where an ash content is 0.6% by weight or less, and the ash contains a periodic table group 2 metal and phosphorus, and a phosphorus content is 10% by weight or more, and the ratio of the periodic table group 2 metal to phosphorus is in the range of 0.6 to 2 molar ratio.
ACRYLIC RUBBER AND CROSSLINKABLE COMPOSITION THEREOF
An acrylic rubber that is a copolymer in which 1 to 4 wt. % of a reactive halogen group-containing vinyl monomer is copolymerized as a crosslinkable comonomer, wherein 45 to 65 wt. % of n-butyl acrylate, 10 to 35 wt. % of 2-methoxyethyl acrylate and 8 to 30 wt. % of ethoxyethoxyethyl acrylate are copolymerized in 100 wt. % of comonomers other than the crosslinkable comonomer. This ethoxyethoxyethyl acrylate-copolymerized acrylic rubber can suppress the reduction of oil resistance while improving cold resistance represented by a TR-10 value, and by compounding it with a vulcanizing agent corresponding to the crosslinkable group thereof, a crosslinkable composition is formed.
ACRYLIC RUBBER AND CROSSLINKABLE COMPOSITION THEREOF
An acrylic rubber that is a copolymer in which 1 to 4 wt. % of a reactive halogen group-containing vinyl monomer is copolymerized as a crosslinkable comonomer, wherein 45 to 65 wt. % of n-butyl acrylate, 10 to 35 wt. % of 2-methoxyethyl acrylate and 8 to 30 wt. % of ethoxyethoxyethyl acrylate are copolymerized in 100 wt. % of comonomers other than the crosslinkable comonomer. This ethoxyethoxyethyl acrylate-copolymerized acrylic rubber can suppress the reduction of oil resistance while improving cold resistance represented by a TR-10 value, and by compounding it with a vulcanizing agent corresponding to the crosslinkable group thereof, a crosslinkable composition is formed.
MICROCHANNEL CHIP
To provide a microchannel chip which is a chip provided internally with an inner space that can be used as a flow channel, and which is excellent in drug non-absorption properties of the channel. The microchannel chip has formed therein a plurality of openings H1, H2 and an inner space S connecting the plurality of openings H1, H2, and at least a part of the surface in contact with the inner space S is made of a fluorinated copolymer containing from 5 to 99 mol % of units based on CF.sub.2CFX (X is a fluorine atom, a chlorine atom or CF.sub.3).
MICROCHANNEL CHIP
To provide a microchannel chip which is a chip provided internally with an inner space that can be used as a flow channel, and which is excellent in drug non-absorption properties of the channel. The microchannel chip has formed therein a plurality of openings H1, H2 and an inner space S connecting the plurality of openings H1, H2, and at least a part of the surface in contact with the inner space S is made of a fluorinated copolymer containing from 5 to 99 mol % of units based on CF.sub.2CFX (X is a fluorine atom, a chlorine atom or CF.sub.3).
COMPOUND, RESIN, RESIST COMPOSITION AND METHOD FOR PRODUCING RESIST PATTERN
A compound represented by the formula (I).
##STR00001##
wherein R.sup.1 represents a hydrogen atom, a halogen atom or a C.sub.1 to C.sub.6 alkyl group that may have a halogen atom; R.sup.2 represents a C.sub.1 to C.sub.12 fluorinated saturated hydrocarbon group; W.sup.1 represents a C.sub.5 to C.sub.18 divalent alicyclic hydrocarbon group; A.sup.1 and A.sup.2 independently represents a single bond or *-A.sup.3-X.sup.1-(A.sup.4-X.sup.2).sub.a-; A.sup.3 and A.sup.4 independently represents a C.sub.1 to C.sub.6 alkanediyl group; X.sup.1 and X.sup.2 independently represents O, COO or OCO; a represents 0 or 1; and * represents a bond to an oxygen atom.