A monomer composition containing an unsaturated polyalkylene glycol ether-based monomer is provided having excellent stability. The monomer composition contains an unsaturated polyalkylene glycol ether-based monomer represented by the following chemical formula (1):
YO(R.sup.1O).sub.nR.sup.2  (1)
[in the formula, Y represents an alkenyl group having 2 to 7 carbon atoms; R.sup.1O represents one or two or more types of oxyalkylene groups having 2 to 18 carbon atoms; n represents an average addition mole number of oxyalkylene groups and is a number of 5 to 500; and R.sup.2 represents a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms], an organic acid, and water, and having a pH of 4 to 13.

A photoacid generating polymer (PAG polymer) comprises i) a first repeat unit of capable of reacting with a photogenerated acid to form a carboxylic acid containing repeat unit, ii) a second repeat unit of capable of forming the photogenerated acid, and iii) a third repeat unit comprising a norbornyl ester, wherein a norbornyl ring of the norbornyl ester comprises a monovalent substituent having the formula *-L′-C(CF.sub.3).sub.2(OH). L′ is a divalent linking group comprising at least one carbon and the starred bond of L′ is linked to the norbornyl ring. The first repeat unit, second repeat unit, and the third repeat unit are covalently bound repeat units of the PAG polymer.

A photoacid generating polymer (PAG polymer) comprises i) a first repeat unit of capable of reacting with a photogenerated acid to form a carboxylic acid containing repeat unit, ii) a second repeat unit of capable of forming the photogenerated acid, and iii) a third repeat unit comprising a norbornyl ester, wherein a norbornyl ring of the norbornyl ester comprises a monovalent substituent having the formula *-L′-C(CF.sub.3).sub.2(OH). L′ is a divalent linking group comprising at least one carbon and the starred bond of L′ is linked to the norbornyl ring. The first repeat unit, second repeat unit, and the third repeat unit are covalently bound repeat units of the PAG polymer.

This invention relates to monodisperse magnetic hydrogel polymer particles comprising a magnetic material and a polymer formed from (a) a hydrophilic vinylic monomer having a log P.sub.oct/wat (log P) of less than about 0.5; and (b) a crosslinker comprising at least two vinyl groups. The invention also relates to monodisperse coated hydrogel polymer particles comprising a polymer formed from (a) a hydrophilic vinylic monomer having a log P.sub.oct/wat (log P) of less than about 0.5; and (b) a crosslinker comprising at least two vinyl groups; and a coating. Also provided are methods of forming the monodisperse magnetic hydrogel polymer particles and monodisperse coated polymer particles.

This invention relates to monodisperse magnetic hydrogel polymer particles comprising a magnetic material and a polymer formed from (a) a hydrophilic vinylic monomer having a log P.sub.oct/wat (log P) of less than about 0.5; and (b) a crosslinker comprising at least two vinyl groups. The invention also relates to monodisperse coated hydrogel polymer particles comprising a polymer formed from (a) a hydrophilic vinylic monomer having a log P.sub.oct/wat (log P) of less than about 0.5; and (b) a crosslinker comprising at least two vinyl groups; and a coating. Also provided are methods of forming the monodisperse magnetic hydrogel polymer particles and monodisperse coated polymer particles.

Radically polymerizable material, which contains (a) 0.01 to 5 wt.-% of at least one transfer reagent, (b) 5 to 60 wt.-% of at least one multifunctional (meth)acrylate or a mixture of mono- and multifunctional (meth)acrylates, (c) 0.01 to 3.0 wt.-% of a mixture of at least one monomolecular and at least one bimolecular photoinitiator, (d) 30 to 90 wt.-% of at least one filler, and (e) optionally additive(s), wherein the material contains as transfer reagent (a) at least one allyl sulfone of Formula I and/or a vinyl sulfone ester of Formula II.

Disclosed is a graft copolymer, and a graft copolymer including a rubbery polymer, wherein the rubbery polymer includes a conjugated diene-based monomer unit and a soft domain, the graft copolymer includes an alkyl (meth)acrylate-based monomer unit, an aromatic vinyl-based monomer unit, and an alkali metal sulfonate-based monomer unit, the soft domain is formed by including a mineral-based oil, the mineral-based oil includes 70 wt % to 100 wt % of a mineral oil and 0 wt % to 30 wt % of a silicone-based oil, the mineral-based oil is included in 0.2 parts by weight to 0.5 parts by weight based on 100 parts by weight of the rubbery polymer, and the alkali metal sulfonate-based monomer unit is included in 0.8 wt % to 1.5 wt % based on the graft copolymer, a method for preparing the same, and a resin composition including the same.

Disclosed is a graft copolymer, and a graft copolymer including a rubbery polymer, wherein the rubbery polymer includes a conjugated diene-based monomer unit and a soft domain, the graft copolymer includes an alkyl (meth)acrylate-based monomer unit, an aromatic vinyl-based monomer unit, and an alkali metal sulfonate-based monomer unit, the soft domain is formed by including a mineral-based oil, the mineral-based oil includes 70 wt % to 100 wt % of a mineral oil and 0 wt % to 30 wt % of a silicone-based oil, the mineral-based oil is included in 0.2 parts by weight to 0.5 parts by weight based on 100 parts by weight of the rubbery polymer, and the alkali metal sulfonate-based monomer unit is included in 0.8 wt % to 1.5 wt % based on the graft copolymer, a method for preparing the same, and a resin composition including the same.

Disclosed is a graft copolymer, and a graft copolymer including a rubbery polymer, wherein the rubbery polymer includes a conjugated diene-based monomer unit and a soft domain, the graft copolymer includes an alkyl (meth)acrylate-based monomer unit, an aromatic vinyl-based monomer unit, and an alkali metal sulfonate-based monomer unit, the soft domain is formed by including a mineral-based oil, the mineral-based oil includes 70 wt % to 100 wt % of a mineral oil and 0 wt % to 30 wt % of a silicone-based oil, the mineral-based oil is included in 0.2 parts by weight to 0.5 parts by weight based on 100 parts by weight of the rubbery polymer, and the alkali metal sulfonate-based monomer unit is included in 0.8 wt % to 1.5 wt % based on the graft copolymer, a method for preparing the same, and a resin composition including the same.

A pressure sensitive adhesive comprising the polymerization product of a polymerizable composition comprising: (a) one or more (meth)acrylate ester monomers; (b) one or more hydrophilic non-acidic monomers; and (c) reactive, ionic surfactant. Also articles comprising such adhesives and methods for making such adhesives and such articles.