C08F230/04

LIVING RADICAL POLYMERIZATION METHOD USING ZINC PHTHALOCYANINE DYE AS NEAR-INFRARED PHOTOCATALYST
20220325008 · 2022-10-13 ·

The invention provides a living radical polymerization method using a zinc phthalocyanine dye as a near-infrared photocatalyst, including subjecting a free radical polymerizable monomer to a near-infrared light-controlled polymerization reaction, in the presence of a chain transfer agent, a cocatalyst and a zinc phthalocyanine dye containing a carbon-carbon double bond, in a solvent at 0-30° C. under the air atmosphere, to obtain a living radical polymerization product. The free radical polymerizable monomer is an acrylate monomer, a methacrylate monomer, an acrylamide monomer or a methacrylamide monomer; the chain transfer agent includes a thiocarbonate; and the cocatalyst includes an organic amine with or without a carbon-carbon double bond. A near-infrared light-responsive functional zinc phthalocyanine dye is used as a near-infrared photocatalyst for the polymerization reaction, and after the polymerization is completed, the polymerizable zinc phthalocyanine dye remains on the polymer chain by polymerization, thereby realizing the cyclic utilization of the near-infrared photocatalyst.

LIVING RADICAL POLYMERIZATION METHOD USING ZINC PHTHALOCYANINE DYE AS NEAR-INFRARED PHOTOCATALYST
20220325008 · 2022-10-13 ·

The invention provides a living radical polymerization method using a zinc phthalocyanine dye as a near-infrared photocatalyst, including subjecting a free radical polymerizable monomer to a near-infrared light-controlled polymerization reaction, in the presence of a chain transfer agent, a cocatalyst and a zinc phthalocyanine dye containing a carbon-carbon double bond, in a solvent at 0-30° C. under the air atmosphere, to obtain a living radical polymerization product. The free radical polymerizable monomer is an acrylate monomer, a methacrylate monomer, an acrylamide monomer or a methacrylamide monomer; the chain transfer agent includes a thiocarbonate; and the cocatalyst includes an organic amine with or without a carbon-carbon double bond. A near-infrared light-responsive functional zinc phthalocyanine dye is used as a near-infrared photocatalyst for the polymerization reaction, and after the polymerization is completed, the polymerizable zinc phthalocyanine dye remains on the polymer chain by polymerization, thereby realizing the cyclic utilization of the near-infrared photocatalyst.

Polymers comprising imidazole derivatives and their use in electrochemical cells

Here are described polymers comprising monomeric units from vinylimidazole derivatives and their use in electrode materials and/or electrolyte compositions, as well as their methods of preparation. Also described are electrode materials, electrodes, and electrochemical cells comprising the polymers and their use.

Polymers comprising imidazole derivatives and their use in electrochemical cells

Here are described polymers comprising monomeric units from vinylimidazole derivatives and their use in electrode materials and/or electrolyte compositions, as well as their methods of preparation. Also described are electrode materials, electrodes, and electrochemical cells comprising the polymers and their use.

Organic polymeric bi-metallic composites

Organic polymeric bi-metallic alkoxide or aryloxide composites are used as dielectric materials in various devices with improved properties such as improved mobility. These composites comprise a poly(meth)acrylate or polyester having metal coordination sites, and the same or different bi-metallic alkoxide or aryloxide molecules that are coordinated with the organic polymer. The bi-metallic alkoxide or aryloxide molecules can be represented by Structure (I) shown herein. Such composites are generally soluble at room temperature in various organic solvents and be provided in homogeneous organic solvent solutions that can be suitably applied to a substrate to form dielectric materials.

Organic polymeric bi-metallic composites

Organic polymeric bi-metallic alkoxide or aryloxide composites are used as dielectric materials in various devices with improved properties such as improved mobility. These composites comprise a poly(meth)acrylate or polyester having metal coordination sites, and the same or different bi-metallic alkoxide or aryloxide molecules that are coordinated with the organic polymer. The bi-metallic alkoxide or aryloxide molecules can be represented by Structure (I) shown herein. Such composites are generally soluble at room temperature in various organic solvents and be provided in homogeneous organic solvent solutions that can be suitably applied to a substrate to form dielectric materials.

METHOD FOR TREATING OR PREVENTING SACCHARIDE-RELATED DISEASES OR DISORDERS

A method for treating or preventing saccharide-related diseases or disorders, comprising administering a therapeutically or prophylactically effective amount of a polymer comprising at least one boronic acid group to a subject having or at risk of having a saccharide-related disease or disorder.

Process for preparation of semi-crystalline functionalized olefin copolymer

The present invention relates to a semi-crystalline functionalized olefin copolymer composition and a process for the preparation of a semi-crystalline functionalized olefin copolymer composition.

Process for preparation of semi-crystalline functionalized olefin copolymer

The present invention relates to a semi-crystalline functionalized olefin copolymer composition and a process for the preparation of a semi-crystalline functionalized olefin copolymer composition.

LATENT CATALYST

A copolymerized crystalline latent catalyst including the reaction product of: (a) at least one crystalline acrylate monomer; (b) at least one copolymerizable catalyst compound; (c) at least one initiator; (d) at least one chain transfer agent; and (e) optionally, at least one solvent to provide a polymerized latent catalyst composition; and a process for making the above latent catalyst.