A method for preparing a biomass-based conductive hydrogel by 3D printing is provided. Firstly, a cellulose-based macromonomer, a rosin-based monomer, an acrylic acid monomer and an initiator are mixed in a certain proportion, stirred, and dissolved at 25-70° C. Then, diisocyanate in an amount of 5-10 wt % of a total mass of the monomers is added to the mixed solution and mixed uniformly to prepare a 3D printing photosensitive resin solution. An SLA light-curing 3D printer is used to print a hydrogel precursor 1 with a complex shape. Next, the hydrogel precursor 1 is heated to obtain a hydrogel precursor 2 with a dual-curing network. Finally, the obtained hydrogel precursor 2 is swelled in a 1-15 wt % alkaline solution at 5-60° C. for 0.1-10 hours to obtain the biomass-based conductive hydrogel.

A method for preparing a biomass-based conductive hydrogel by 3D printing is provided. Firstly, a cellulose-based macromonomer, a rosin-based monomer, an acrylic acid monomer and an initiator are mixed in a certain proportion, stirred, and dissolved at 25-70° C. Then, diisocyanate in an amount of 5-10 wt % of a total mass of the monomers is added to the mixed solution and mixed uniformly to prepare a 3D printing photosensitive resin solution. An SLA light-curing 3D printer is used to print a hydrogel precursor 1 with a complex shape. Next, the hydrogel precursor 1 is heated to obtain a hydrogel precursor 2 with a dual-curing network. Finally, the obtained hydrogel precursor 2 is swelled in a 1-15 wt % alkaline solution at 5-60° C. for 0.1-10 hours to obtain the biomass-based conductive hydrogel.

A method for preparing a biomass-based conductive hydrogel by 3D printing is provided. Firstly, a cellulose-based macromonomer, a rosin-based monomer, an acrylic acid monomer and an initiator are mixed in a certain proportion, stirred, and dissolved at 25-70° C. Then, diisocyanate in an amount of 5-10 wt % of a total mass of the monomers is added to the mixed solution and mixed uniformly to prepare a 3D printing photosensitive resin solution. An SLA light-curing 3D printer is used to print a hydrogel precursor 1 with a complex shape. Next, the hydrogel precursor 1 is heated to obtain a hydrogel precursor 2 with a dual-curing network. Finally, the obtained hydrogel precursor 2 is swelled in a 1-15 wt % alkaline solution at 5-60° C. for 0.1-10 hours to obtain the biomass-based conductive hydrogel.

Provided are a composite for cellulose fiber dispersion that can inexpensively and sufficiently disperse cellulose fibers, particularly nanocellulose, in a hydrophobic resin and a cellulose fiber composition containing the composite. A composite for cellulose fiber dispersion according to the present invention has a structure in which a vinyl polymer is grafted to a cellulose derivative. A cellulose fiber composition according to the present invention contains the composite and cellulose fibers and more specifically also contains an organic solvent, a resin precursor, or a resin.

Provided are a composite for cellulose fiber dispersion that can inexpensively and sufficiently disperse cellulose fibers, particularly nanocellulose, in a hydrophobic resin and a cellulose fiber composition containing the composite. A composite for cellulose fiber dispersion according to the present invention has a structure in which a vinyl polymer is grafted to a cellulose derivative. A cellulose fiber composition according to the present invention contains the composite and cellulose fibers and more specifically also contains an organic solvent, a resin precursor, or a resin.

Provided are a composite for cellulose fiber dispersion that can inexpensively and sufficiently disperse cellulose fibers, particularly nanocellulose, in a hydrophobic resin and a cellulose fiber composition containing the composite. A composite for cellulose fiber dispersion according to the present invention has a structure in which a vinyl polymer is grafted to a cellulose derivative. A cellulose fiber composition according to the present invention contains the composite and cellulose fibers and more specifically also contains an organic solvent, a resin precursor, or a resin.

Provided herein is a cellulose nanofiber that can be easily combined with a compound having a reactive double-bond group and that can provide a molded article which contains only a small amount of an uncured material that acts as a plasticizer in a molded product, using a simple producing method that does not require any process involving solvent displacement or solvent removal. A high-strength resin composition or molded body prepared by using the cellulose nanofiber is also provided. In refining cellulose in the presence of a compound having a reactive double bond and a hydroxyl value of 200 KOHmg/g or more, the cellulose has a moisture content of 4 to 25 parts by mass with respect to 100 parts by mass of the amount of the cellulose converted on the assumption that the percentage moisture of the cellulose is 0%.

Provided herein is a cellulose nanofiber that can be easily combined with a compound having a reactive double-bond group and that can provide a molded article which contains only a small amount of an uncured material that acts as a plasticizer in a molded product, using a simple producing method that does not require any process involving solvent displacement or solvent removal. A high-strength resin composition or molded body prepared by using the cellulose nanofiber is also provided. In refining cellulose in the presence of a compound having a reactive double bond and a hydroxyl value of 200 KOHmg/g or more, the cellulose has a moisture content of 4 to 25 parts by mass with respect to 100 parts by mass of the amount of the cellulose converted on the assumption that the percentage moisture of the cellulose is 0%.

A cellulose nanofiber (CNF) powder of the present invention contains cellulose nanofibers, and a hydrophobic polymer that is chemically bonded to at least some of the —OH groups of the cellulose nanofibers. The CNF powder has the ability to be dispersed in water and to return to a powder form again when an aqueous dispersion of the CNF powder is dried. The distance between the fibers in the CNF powder in a dry state is 3 nm or more, and preferably 8 to 12 nm. Since the distance between the fibers in the conventional cellulose nanofibers is about 1 nm, the present invention reduces the Van der Waals force between the fibers (i.e., the force of attraction between the fibers) to one millionth of that of the conventional cellulose nanofibers. Thus, the present invention provides the CNF powder that can be used in a powder form, and that can also be reversibly changed between a powder state and a dispersed state in water, and a method for producing the CNF powder.

A cellulose nanofiber (CNF) powder of the present invention contains cellulose nanofibers, and a hydrophobic polymer that is chemically bonded to at least some of the —OH groups of the cellulose nanofibers. The CNF powder has the ability to be dispersed in water and to return to a powder form again when an aqueous dispersion of the CNF powder is dried. The distance between the fibers in the CNF powder in a dry state is 3 nm or more, and preferably 8 to 12 nm. Since the distance between the fibers in the conventional cellulose nanofibers is about 1 nm, the present invention reduces the Van der Waals force between the fibers (i.e., the force of attraction between the fibers) to one millionth of that of the conventional cellulose nanofibers. Thus, the present invention provides the CNF powder that can be used in a powder form, and that can also be reversibly changed between a powder state and a dispersed state in water, and a method for producing the CNF powder.