Patent classifications
C08F255/02
POLYOLEFIN/(METH)ACRYLIC COMPOSITE POLYMER COMPOSITION AND METHOD OF PREPARING SAME
A composite polymer composition comprising: the emulsion polymerization product of: (i) an aqueous polyolefin dispersion comprising the melt kneading product of one or more polyolefins, from 0.5 to 25 wt % of one or more dispersion stabilizing agents and water, and (ii) one or more (meth)acrylic monomers; wherein the one or more polyolefins have a Tg equal to or less than 50° C.; wherein the melt kneading product (i) comprises polymer particles having a volume average particle size between 50 nm and 2000 nm dispersed in the water; wherein the one or more dispersion stabilizing agents comprises a fatty acid or fatty acid salt stabilizing agent; and wherein the one or more (meth)acrylic monomers graft onto the polymer particles form composite polymer particles is provide. Also provided is a method of making the composition and impact modifiers comprising the composition.
POLYOLEFIN/(METH)ACRYLIC COMPOSITE POLYMER COMPOSITION AND METHOD OF PREPARING SAME
A composite polymer composition comprising: the emulsion polymerization product of: (i) an aqueous polyolefin dispersion comprising the melt kneading product of one or more polyolefins, from 0.5 to 25 wt % of one or more dispersion stabilizing agents and water, and (ii) one or more (meth)acrylic monomers; wherein the one or more polyolefins have a Tg equal to or less than 50° C.; wherein the melt kneading product (i) comprises polymer particles having a volume average particle size between 50 nm and 2000 nm dispersed in the water; wherein the one or more dispersion stabilizing agents comprises a fatty acid or fatty acid salt stabilizing agent; and wherein the one or more (meth)acrylic monomers graft onto the polymer particles form composite polymer particles is provide. Also provided is a method of making the composition and impact modifiers comprising the composition.
Carbon fiber bundle for resin reinforcement, and method for manufacturing carbon fiber bundle for resin reinforcement, carbon-fiber-reinforced thermoplastic resin composition, and molded body
A carbon fiber bundle for resin reinforcement, wherein there are adhered by 0.1-5.0 mass % to a carbon fiber bundle in which multiple lengths of filament are bundled, a mixture created by mixing an organic polymer (A) having a mass-average molecular weight of 10000 or more and an organic compound (B) the thermal reduction rate specified in claim 1 of which is 5 mass % or more or an organic compound (B) the thermal reduction rate specified in claim 2 of which is 0.8 mass % or more, the amount of the organic polymer (A) adhered being 0.1 mass % or more.
Carbon fiber bundle for resin reinforcement, and method for manufacturing carbon fiber bundle for resin reinforcement, carbon-fiber-reinforced thermoplastic resin composition, and molded body
A carbon fiber bundle for resin reinforcement, wherein there are adhered by 0.1-5.0 mass % to a carbon fiber bundle in which multiple lengths of filament are bundled, a mixture created by mixing an organic polymer (A) having a mass-average molecular weight of 10000 or more and an organic compound (B) the thermal reduction rate specified in claim 1 of which is 5 mass % or more or an organic compound (B) the thermal reduction rate specified in claim 2 of which is 0.8 mass % or more, the amount of the organic polymer (A) adhered being 0.1 mass % or more.
Crosslinked polyolefin separator and method for manufacturing the same
A method for manufacturing a crosslinked polyolefin separator and the crosslinked polyolefin separator obtained by the method are provided. The method includes (S1) mixing polyolefin, a diluting agent, an initiator and alkoxysilane containing a carbon-carbon double bonded group to an extruder, and then carrying out extrusion to obtain a silane-grafted polyolefin composition; (S2) molding and orienting the extruded silane-grafted polyolefin composition in the form of a sheet; (S3) introducing the oriented sheet to an extraction water bath containing a crosslinking catalyst to extract the diluting agent and perform aqueous crosslinking; and (S4) thermally fixing a resultant aqueous crosslinked product. The method can provide a separator having a high meltdown temperature and improved heat shrinkage.
Crosslinked polyolefin separator and method for manufacturing the same
A method for manufacturing a crosslinked polyolefin separator and the crosslinked polyolefin separator obtained by the method are provided. The method includes (S1) mixing polyolefin, a diluting agent, an initiator and alkoxysilane containing a carbon-carbon double bonded group to an extruder, and then carrying out extrusion to obtain a silane-grafted polyolefin composition; (S2) molding and orienting the extruded silane-grafted polyolefin composition in the form of a sheet; (S3) introducing the oriented sheet to an extraction water bath containing a crosslinking catalyst to extract the diluting agent and perform aqueous crosslinking; and (S4) thermally fixing a resultant aqueous crosslinked product. The method can provide a separator having a high meltdown temperature and improved heat shrinkage.
Crosslinked polyolefin separator and method for manufacturing the same
A method for manufacturing a crosslinked polyolefin separator and the crosslinked polyolefin separator obtained by the method are provided. The method includes (S1) mixing polyolefin, a diluting agent, an initiator and alkoxysilane containing a carbon-carbon double bonded group to an extruder, and then carrying out extrusion to obtain a silane-grafted polyolefin composition; (S2) molding and orienting the extruded silane-grafted polyolefin composition in the form of a sheet; (S3) introducing the oriented sheet to an extraction water bath containing a crosslinking catalyst to extract the diluting agent and perform aqueous crosslinking; and (S4) thermally fixing a resultant aqueous crosslinked product. The method can provide a separator having a high meltdown temperature and improved heat shrinkage.
Adhesive film, composition for forming same and electronic device
Provided are an adhesive film, a composition for forming the same and an electronic device. The composition includes: a thermoplastic polymeric resin and an antistatic agent, the antistatic agent is an amide organic compound represented by Formula (I). The above antistatic agent contains a strong-polarity amide group and an optional polar group. The amide group may form an intramolecular hydrogen bond, which has a shorter bond length, and a dipole electric field generated by positive and negative ions formed after ionization is strong and a voltage generated by an external electrostatic field may be counteracted, such that the antistatic agent has a better antistatic property. The optional polar group may improve the above antistatic property: The thermoplastic polymeric resin has good thermal processability, and after it and the antistatic agent are subjected to melt extrusion, the adhesive film with the better antistatic property and processability may be formed.
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Adhesive film, composition for forming same and electronic device
Provided are an adhesive film, a composition for forming the same and an electronic device. The composition includes: a thermoplastic polymeric resin and an antistatic agent, the antistatic agent is an amide organic compound represented by Formula (I). The above antistatic agent contains a strong-polarity amide group and an optional polar group. The amide group may form an intramolecular hydrogen bond, which has a shorter bond length, and a dipole electric field generated by positive and negative ions formed after ionization is strong and a voltage generated by an external electrostatic field may be counteracted, such that the antistatic agent has a better antistatic property. The optional polar group may improve the above antistatic property: The thermoplastic polymeric resin has good thermal processability, and after it and the antistatic agent are subjected to melt extrusion, the adhesive film with the better antistatic property and processability may be formed.
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GRAFTING-MODIFIED POLYPROPYLENE MATERIAL AND PREPARATION METHOD THEREFOR
The invention belongs to the field of polymers, and relates to a grafting-modified polypropylene material for an insulating material and preparation method thereof. The grafting-modified polypropylene material comprises structural units derived from a polypropylene copolymer and structural units derived from an alkenyl-containing polymerizable monomer; the content of the structural units derived from the alkenyl-containing polymerizable monomer and in a grafted state in the grafting-modified polypropylene material is 0.1 to 14 wt %; the polypropylene copolymer has at least one of the following characteristics: the comonomer content is 0.5 to 40 mol %; the content of xylene solubles is 2 to 80 wt %; the comonomer content in the xylene solubles is 10 to 70 wt %; the intrinsic viscosity ratio of the xylene solubles to the polypropylene copolymer is 0.3 to 5. The grafting-modified polypropylene material of the invention can give consideration to both mechanical property and electrical property at a higher working temperature.