Patent classifications
C08F255/02
Polyolefin Polyols as Surface Modifying Agents
A functionalized ethylene-based polymer dissolved in an appropriate solvent and applied to a nonpolar surface can change the surface polarity/characteristics of the nonpolar surface. This change to the surface polarity/characteristics of the nonpolar surface allows adhesion of materials, such as paint, to surfaces such as polypropylene, polyethylene and polyolefin elastomers.
THERMOPLASTIC ELASTOMER COMPOSITION
Provided is a thermoplastic elastomer composition excellent in mechanical characteristics, abrasion resistance, etc., comprising: a crosslinked composition (X) obtained by heat-treating, under molten condition, a composition containing 100 pars of a block copolymer or a hydrogenated product thereof, the block copolymer including a polymer block A mainly derived from an aromatic vinyl compound containing 1% by mass or more of an alkylstyrene and a polymer block B mainly derived from a diene compound, 10 to 300 parts of an olefin-based resin, 0.01 to 20 parts of a crosslinking agent, 1 to 50 parts of a crosslinking adjuvant, and 30 to 250 parts of a softener for rubber; and a hydrogenated block copolymer (Y) obtained by hydrogenating a block copolymer having at least two polymer blocks of an aromatic vinyl compound and at least one polymer block of a conjugated diene compound, with the mass ratio of (X)/(Y)=10/90 to 90/10.
THERMOPLASTIC ELASTOMER COMPOSITION
Provided is a thermoplastic elastomer composition excellent in mechanical characteristics, abrasion resistance, etc., comprising: a crosslinked composition (X) obtained by heat-treating, under molten condition, a composition containing 100 pars of a block copolymer or a hydrogenated product thereof, the block copolymer including a polymer block A mainly derived from an aromatic vinyl compound containing 1% by mass or more of an alkylstyrene and a polymer block B mainly derived from a diene compound, 10 to 300 parts of an olefin-based resin, 0.01 to 20 parts of a crosslinking agent, 1 to 50 parts of a crosslinking adjuvant, and 30 to 250 parts of a softener for rubber; and a hydrogenated block copolymer (Y) obtained by hydrogenating a block copolymer having at least two polymer blocks of an aromatic vinyl compound and at least one polymer block of a conjugated diene compound, with the mass ratio of (X)/(Y)=10/90 to 90/10.
THERMOPLASTIC ELASTOMER COMPOSITION AND MOLDED ARTICLE
Provided are: a thermoplastic elastomer composition, excellent in both abrasion resistance and mechanical characteristics, obtained by heat-treating a mixture under molten condition thereof, the mixture including: 100 parts of at least one addition-polymerized block copolymer selected from a block copolymer and a hydrogenated product thereof; the block copolymer has a polymer block mainly including a structural unit derived from an aromatic vinyl compound and containing 1% by mass or more of a structural unit derived from a styrene having an alkyl group bonded to a benzene ring and a polymer block mainly including a structural unit derived from a conjugated diene compound, 10 to 300 parts olefin-based resin, 0.01 to 20 parts crosslinking agent; 1 to 50 parts crosslinking adjuvant containing one methacryloyl group, one acryloyl group, and one or more hydroxyl group, and 30 to 250 parts rubber softener; and a molded article including the said thermoplastic elastomer composition.
THERMOPLASTIC ELASTOMER COMPOSITION AND MOLDED ARTICLE
Provided are: a thermoplastic elastomer composition, excellent in both abrasion resistance and mechanical characteristics, obtained by heat-treating a mixture under molten condition thereof, the mixture including: 100 parts of at least one addition-polymerized block copolymer selected from a block copolymer and a hydrogenated product thereof; the block copolymer has a polymer block mainly including a structural unit derived from an aromatic vinyl compound and containing 1% by mass or more of a structural unit derived from a styrene having an alkyl group bonded to a benzene ring and a polymer block mainly including a structural unit derived from a conjugated diene compound, 10 to 300 parts olefin-based resin, 0.01 to 20 parts crosslinking agent; 1 to 50 parts crosslinking adjuvant containing one methacryloyl group, one acryloyl group, and one or more hydroxyl group, and 30 to 250 parts rubber softener; and a molded article including the said thermoplastic elastomer composition.
COMPOSITE RESIN PARTICLES, PROCESS FOR PRODUCING SAME, EXPANDABLE BEADS, EXPANDED BEADS, FOAMED MOLDED OBJECT, AND AUTOMOTIVE INTERIOR TRIM
Composite resin particles comprising 50 to 800 parts by mass of a polystyrene-based resin with respect to 100 parts by mass of a polyolefin-based resin, wherein: when transmission electron microscope (TEM) images obtained by photographing cross-sections of the composite resin particles using a TEM at a magnification of 1,000 are subjected to a binarization processing and areas in the obtained binarized images which correspond to a cross-sectional area of 437.584 μm.sup.2 of the composite resin particles are subjected to image analysis, the polystyrene-based resin satisfies the following requirements: (1) the number of dispersed particles is 180 or more; (2) the maximum of the areas of dispersed particles is 200 μm.sup.2 or less; and (3) the coefficient of variation in dispersion is 100% or more, and the composite resin particles exhibit an inner morphology that includes a mixture of sea-island structure regions and co-continuous structure regions.
COMPOSITE RESIN PARTICLES, PROCESS FOR PRODUCING SAME, EXPANDABLE BEADS, EXPANDED BEADS, FOAMED MOLDED OBJECT, AND AUTOMOTIVE INTERIOR TRIM
Composite resin particles comprising 50 to 800 parts by mass of a polystyrene-based resin with respect to 100 parts by mass of a polyolefin-based resin, wherein: when transmission electron microscope (TEM) images obtained by photographing cross-sections of the composite resin particles using a TEM at a magnification of 1,000 are subjected to a binarization processing and areas in the obtained binarized images which correspond to a cross-sectional area of 437.584 μm.sup.2 of the composite resin particles are subjected to image analysis, the polystyrene-based resin satisfies the following requirements: (1) the number of dispersed particles is 180 or more; (2) the maximum of the areas of dispersed particles is 200 μm.sup.2 or less; and (3) the coefficient of variation in dispersion is 100% or more, and the composite resin particles exhibit an inner morphology that includes a mixture of sea-island structure regions and co-continuous structure regions.
CROSSLINKABLE COMPOSITION COMPRISING POLYETHYLENE AND USE THEREOF FOR ROTATIONAL MOLDING
Crosslinkable composition comprising: (a) from 80% by weight to 98% by weight, preferably from 85% by weight to 95% by weight, of at least one high density polyethylene (HDPE); (b) from 2% by weight to 20% by weight, preferably from 5% by weight to 15% by weight, of at least one linear low density polyethylene (LLDPE); (c) from 0.2 parts by weight to 1.5 parts by weight, preferably from 0.5 parts by weight to 0.8 parts by weight, with respect to 100 parts by weight of (a)+(b), of at least one crosslinking agent selected from organic peroxides; (d) from 0.2 parts by weight to 2.5 parts by weight, preferably from 0.5 parts by weight to 1.0 parts by weight, with respect to 100 parts by weight of (a)+(b), of at least one co-crosslinking agent selected from allyl compounds. Said crosslinkable composition can advantageously be used in rotational molding (“rotomolding”).
COMPOSITION FOR ELECTRIC WIRE COATING MATERIAL, INSULATED ELECTRIC WIRE, AND WIRE HARNESS
Provided is an insulated electric wire, a wire harness, and a composition for an electric wire coating material with which the amount of a filler, which is the flame retardant, can be reduced as much as possible without using electron beam crosslinking, the composition having a high heat resistance, a high gel fraction, flexibility, and good workability of assembling a wire harness. An electric wire coating material is made of a composition comprising (A) a silane-grafted polyolefin obtained by grafting a silane coupling agent onto a polyolefin having a density of 0.855 to 0.885 g/cm.sup.3, (B) an unmodified polyolefin having a density of 0.890 to 0.955 g/cm.sup.3, (C) a modified polyolefin modified by one or more functional groups selected from a carboxylic acid group, an acid anhydride group, an amino group, an acrylic group, a methacrylic group, and an epoxy group, (D) a bromine-based flame retardant and antimony trioxide, (E) a crosslinking catalyst batch, (F) zinc oxide and an imidazole-based compound, or zinc sulfide, (G) an antioxidant, (H) a metal deactivator, and (I) a lubricant.
COMPOSITION FOR ELECTRIC WIRE COATING MATERIAL, INSULATED ELECTRIC WIRE, AND WIRE HARNESS
Provided is an insulated electric wire, a wire harness, and a composition for an electric wire coating material with which the amount of a filler, which is the flame retardant, can be reduced as much as possible without using electron beam crosslinking, the composition having a high heat resistance, a high gel fraction, flexibility, and good workability of assembling a wire harness. An electric wire coating material is made of a composition comprising (A) a silane-grafted polyolefin obtained by grafting a silane coupling agent onto a polyolefin having a density of 0.855 to 0.885 g/cm.sup.3, (B) an unmodified polyolefin having a density of 0.890 to 0.955 g/cm.sup.3, (C) a modified polyolefin modified by one or more functional groups selected from a carboxylic acid group, an acid anhydride group, an amino group, an acrylic group, a methacrylic group, and an epoxy group, (D) a bromine-based flame retardant and antimony trioxide, (E) a crosslinking catalyst batch, (F) zinc oxide and an imidazole-based compound, or zinc sulfide, (G) an antioxidant, (H) a metal deactivator, and (I) a lubricant.