The present invention relates to a method for preparing a thermoplastic copolymer using monomer droplets, a thermoplastic copolymer prepared therefrom and a thermoplastic resin composition including the same. In the preparation method, monomer droplets including an aromatic vinyl-based monomer are injected after reaching a polymerization conversion ratio of 10% to participate in the reaction after initiating polymerization, and a thermoplastic copolymer having an increased average particle diameter may be prepared in high yield.

The present invention relates to a method for preparing a thermoplastic copolymer using monomer droplets, a thermoplastic copolymer prepared therefrom and a thermoplastic resin composition including the same. In the preparation method, monomer droplets including an aromatic vinyl-based monomer are injected after reaching a polymerization conversion ratio of 10% to participate in the reaction after initiating polymerization, and a thermoplastic copolymer having an increased average particle diameter may be prepared in high yield.

The present disclosure relates to a matting agent including emulsion polymer particles, a matting polymer composition including a matting agent, and a method of producing emulsion polymer particles. The emulsion polymer particles may be produced by a simple process using an emulsion polymerization method, and have the advantage of being relatively easy to control a degree of crosslinking. In addition, in a case where a matting polymer composition is prepared using a matting agent including the emulsion polymer particles, it is possible to manufacture a molded article having excellent appearance and matting effect without deterioration of the existing mechanical properties such as impact strength and tensile strength of a thermoplastic polymer, and in particular, an excellent matting effect may be exerted even in the extrusion processing, which has been difficult to achieve in the related art.

The present disclosure relates to a matting agent including emulsion polymer particles, a matting polymer composition including a matting agent, and a method of producing emulsion polymer particles. The emulsion polymer particles may be produced by a simple process using an emulsion polymerization method, and have the advantage of being relatively easy to control a degree of crosslinking. In addition, in a case where a matting polymer composition is prepared using a matting agent including the emulsion polymer particles, it is possible to manufacture a molded article having excellent appearance and matting effect without deterioration of the existing mechanical properties such as impact strength and tensile strength of a thermoplastic polymer, and in particular, an excellent matting effect may be exerted even in the extrusion processing, which has been difficult to achieve in the related art.

A crosslinking material, the crosslinking material comprising the reaction product of a reaction mixture comprising: (i) a cyclic unsaturated acid anhydride and/or diacid derivative thereof; (ii) an ethylenically unsaturated monomer; and (iii) an alcohol, amine and/or thiol,
wherein the cyclic unsaturated acid anhydride and/or diacid derivative thereof is partially-esterified by reaction with the alcohol, amine and/or thiol; and wherein the wherein the crosslinking material has an acid number of at least 100 mg KOH/g.

A crosslinking material, the crosslinking material comprising the reaction product of a reaction mixture comprising: (i) a cyclic unsaturated acid anhydride and/or diacid derivative thereof; (ii) an ethylenically unsaturated monomer; and (iii) an alcohol, amine and/or thiol,
wherein the cyclic unsaturated acid anhydride and/or diacid derivative thereof is partially-esterified by reaction with the alcohol, amine and/or thiol; and wherein the wherein the crosslinking material has an acid number of at least 100 mg KOH/g.

A viscosity modifier for a condensation polymer may include a chain extender comprising at least one reactive monomer and at least one vinyl monomer copolymerizable with the reactive monomer, the chain extender being present in an amount ranging from 15 to 70 wt % of the viscosity modifier; and a non-condensation carrier resin present in an amount ranging from 30 to 85 wt % of the viscosity modifier. Condensation polymer compositions, methods of forming viscosity modifiers, and methods of molding condensation polymer compositions are also provided.

A viscosity modifier for a condensation polymer may include a chain extender comprising at least one reactive monomer and at least one vinyl monomer copolymerizable with the reactive monomer, the chain extender being present in an amount ranging from 15 to 70 wt % of the viscosity modifier; and a non-condensation carrier resin present in an amount ranging from 30 to 85 wt % of the viscosity modifier. Condensation polymer compositions, methods of forming viscosity modifiers, and methods of molding condensation polymer compositions are also provided.

Provided is a compound that is fluidized by light irradiation and reversibly non-fluidized, is not significantly colored, and improves fixability and exhibits excellent image stability and color reproducibility when used for a toner.

Provided is a compound represented by the following general formula (1), which is fluidized by light irradiation and reversibly non-fluidized:

##STR00001##

wherein

Z.sub.1 and Z.sub.2 are CH or N, and Z.sub.1≠Z.sub.2;

R.sub.1 is an aromatic hydrocarbon group having a substituent R.sub.a selected from the group consisting of an alkyl group, an alkoxy group and a halogen atom at each of two ortho positions with respect to Z.sub.1; and

R.sub.2 is a substituted or unsubstituted aromatic heterocyclic group.

A solvent composition includes an organic solvent including one or more organic solvents (A) and one or more organic solvents (B), and one or more types of core-shell polymer particles each comprising a core layer and a shell layer. The organic sol vents (A) have a polar teen δp of a Hansen solubility parameter of less than 11 and a hydrogen bond term δh of less than 10, and the organic solvents (B) satisfy at least one of 11 or more of the polar term δp or 10 or more of the hydrogen bond term δh. A weight ratio of (A) to (B) ranges from 15:85 to 95:5. Based on a total weight of the solvent composition, a content of the core-shell polymer particles is 20 to 40% by weight and a water content is 1% by weight or less.