Patent classifications
C08F259/08
FLUORINATED ETHER COMPOUND, FLUORINATED ETHER COMPOSITION, COATING LIQUID AND ARTICLE
To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid that are able to form a surface layer which is excellent in water/oil repellency, abrasion resistance, fingerprint stain removability, lubricity and outer appearance, and an article having such a surface layer. A fluorinated ether compound represented by A.sup.1-O—(R.sup.f1O).sub.m1-Q.sup.1-[C(O)N(R.sup.1)].sub.p1—R.sup.11—C[—R.sup.12—SiR.sup.13.sub.n1X.sup.1.sub.3-n1].sub.3, wherein A.sup.1 is a C.sub.1-20 perfluoroalkyl group; R.sup.f1 is a fluoroalkylene group having no branched structure; m1 is an integer from 2 to 210; Q.sup.1 is a single bond or a fluoroalkylene group having no branched structure; R.sup.1 is a hydrogen atom, etc.; p1 is 0 or 1; R.sup.11 is a single bond, an alkylene group, etc.; R.sup.12 is an alkylene group, etc.; R.sup.13 is a monovalent hydrocarbon group, etc.; X.sup.1 is a hydrolyzable group; and n1 is an integer of from 0 to 2.
Modified polytetrafluoroethylene fine powder and its manufacturing method, and electric wire and tube using it
To optimize the primary particle size of a modified PTFE fine powder to shorten the sintering time during the extrusion molding. A modified polytetrafluoroethylene fine powder which is a fine powder of a non-melt-processable modified polytetrafluoroethylene comprising units derived from tetrafluoroethylene, units derived from hexafluoropropylene, units derived from a perfluoro(alkyl vinyl ether) represented by CF.sub.2═CFO—C.sub.nF.sub.2n+1 (n is an integer of from 1 to 6) and units derived from a (perfluoalkyl)ethylene represented by CH.sub.2═CH—C.sub.mF.sub.2m+1 (m is an integer of from 3 to 7).
Modified polytetrafluoroethylene fine powder and its manufacturing method, and electric wire and tube using it
To optimize the primary particle size of a modified PTFE fine powder to shorten the sintering time during the extrusion molding. A modified polytetrafluoroethylene fine powder which is a fine powder of a non-melt-processable modified polytetrafluoroethylene comprising units derived from tetrafluoroethylene, units derived from hexafluoropropylene, units derived from a perfluoro(alkyl vinyl ether) represented by CF.sub.2═CFO—C.sub.nF.sub.2n+1 (n is an integer of from 1 to 6) and units derived from a (perfluoalkyl)ethylene represented by CH.sub.2═CH—C.sub.mF.sub.2m+1 (m is an integer of from 3 to 7).
SOLID STATE ELECTROLYTE RECHARGEABLE BATTERY IN NO USE OF SEPARATOR
Solid state solid electrolyte rechargeable battery in no use of separator comprising a positive electrode/a conductive polymer solid state electrolyte layer/a negative electrode in which the solid state electrolyte layer is a composition comprising an inorganic solid electrolyte and a polymer electrolyte composition wherein the polymer electrolyte composition is selected from the group consisting of a polymer electrolyte composition (X.sup.1) obtained by graft polymerizing or living radical polymerization of a molten salt monomer having a polymerizable functional group and having an onium cation and an anion containing a halogen with a fluoro polymer, and a polymer electrolyte composition comprising (X.sup.1) and at least one kind selected from the following (X.sup.2) and (X.sup.3), X.sup.2: a molten salt having an onium cation and an anion containing a halogen, or a molten salt monomer having a polymerizable functional group and having an onium cation, X.sup.3: a polymer or copolymer of a molten salt monomer having a polymerizable functional group and having an onium cation.
By providing this rechargeable battery, the solid electrolyte rechargeable battery without separator which has a descending effect of particle interface resistance between a positive and negative active materials in case of using conductive polymer solid electrolyte, a thin film cell, a less dependence on the temperature and excellent safety in case of happening short circuit can be obtained.
SOLID STATE ELECTROLYTE RECHARGEABLE BATTERY IN NO USE OF SEPARATOR
Solid state solid electrolyte rechargeable battery in no use of separator comprising a positive electrode/a conductive polymer solid state electrolyte layer/a negative electrode in which the solid state electrolyte layer is a composition comprising an inorganic solid electrolyte and a polymer electrolyte composition wherein the polymer electrolyte composition is selected from the group consisting of a polymer electrolyte composition (X.sup.1) obtained by graft polymerizing or living radical polymerization of a molten salt monomer having a polymerizable functional group and having an onium cation and an anion containing a halogen with a fluoro polymer, and a polymer electrolyte composition comprising (X.sup.1) and at least one kind selected from the following (X.sup.2) and (X.sup.3), X.sup.2: a molten salt having an onium cation and an anion containing a halogen, or a molten salt monomer having a polymerizable functional group and having an onium cation, X.sup.3: a polymer or copolymer of a molten salt monomer having a polymerizable functional group and having an onium cation.
By providing this rechargeable battery, the solid electrolyte rechargeable battery without separator which has a descending effect of particle interface resistance between a positive and negative active materials in case of using conductive polymer solid electrolyte, a thin film cell, a less dependence on the temperature and excellent safety in case of happening short circuit can be obtained.
FLUORINATED ETHER COMPOUND, FLUORINATED ETHER COMPOSITION, COATING LIQUID AND ARTICLE
To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid that are able to form a surface layer which is excellent in water/oil repellency, abrasion resistance, fingerprint stain removability, lubricity and outer appearance, and an article having such a surface layer. A fluorinated ether compound represented by A.sup.1-O(R.sup.f1O).sub.m1Q.sup.1-[C(O)N(R.sup.1)].sub.p1R.sup.11C[R.sup.12SiR.sup.13.sub.n1X.sup.1.sub.3-n1].sub.3, wherein A.sup.1 is a C.sub.1-20 perfluoroalkyl group; R.sup.f1 is a fluoroalkylene group having no branched structure; m1 is an integer from 2 to 210; Q.sup.1 is a single bond or a fluoroalkylene group having no branched structure; R.sup.1 is a hydrogen atom, etc.; p1 is 0 or 1; R.sup.11 is a single bond, an alkylene group, etc.; R.sup.12 is an alkylene group, etc.; R.sup.13 is a monovalent hydrocarbon group, etc.; X.sup.1 is a hydrolyzable group; and n1 is an integer of from 0 to 2.
FLUORINATED ETHER COMPOUND, FLUORINATED ETHER COMPOSITION, COATING LIQUID AND ARTICLE
To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid that are able to form a surface layer which is excellent in water/oil repellency, abrasion resistance, fingerprint stain removability, lubricity and outer appearance, and an article having such a surface layer. A fluorinated ether compound represented by A.sup.1-O(R.sup.f1O).sub.m1Q.sup.1-[C(O)N(R.sup.1)].sub.p1R.sup.11C[R.sup.12SiR.sup.13.sub.n1X.sup.1.sub.3-n1].sub.3, wherein A.sup.1 is a C.sub.1-20 perfluoroalkyl group; R.sup.f1 is a fluoroalkylene group having no branched structure; m1 is an integer from 2 to 210; Q.sup.1 is a single bond or a fluoroalkylene group having no branched structure; R.sup.1 is a hydrogen atom, etc.; p1 is 0 or 1; R.sup.11 is a single bond, an alkylene group, etc.; R.sup.12 is an alkylene group, etc.; R.sup.13 is a monovalent hydrocarbon group, etc.; X.sup.1 is a hydrolyzable group; and n1 is an integer of from 0 to 2.
Compositions based on fluoropolymers, fluoropolymer-miscible polymers and free radically-curable components
Compositions useful for forming high gloss, transparent, hard, flexible, weather- and dirt-resistant coatings on substrate surfaces are prepared using a) fluoropolymer, such as KYNAR resins and KYNAR Aquatec resins from Arkema Inc, b) fluoropolymer-miscible polymer and c) one or more ethylenically unsaturated compounds capable of being cured by free radical means, such as urethane acrylate oligomers and monomer reactive diluents from Sartomer USA, LLC. The compositions are capable of being cured by free radical polymerization induced by, for example, irradiation or heating.
Compositions based on fluoropolymers, fluoropolymer-miscible polymers and free radically-curable components
Compositions useful for forming high gloss, transparent, hard, flexible, weather- and dirt-resistant coatings on substrate surfaces are prepared using a) fluoropolymer, such as KYNAR resins and KYNAR Aquatec resins from Arkema Inc, b) fluoropolymer-miscible polymer and c) one or more ethylenically unsaturated compounds capable of being cured by free radical means, such as urethane acrylate oligomers and monomer reactive diluents from Sartomer USA, LLC. The compositions are capable of being cured by free radical polymerization induced by, for example, irradiation or heating.
Compositions based on fluoropolymers, fluoropolymer-miscible polymers and free radically-curable components
Compositions useful for forming high gloss, transparent, hard, flexible, weather- and dirt-resistant coatings on substrate surfaces are prepared using a) fluoropolymer, such as KYNAR resins and KYNAR Aquatec resins from Arkema Inc, b) fluoropolymer-miscible polymer and c) one or more ethylenically unsaturated compounds capable of being cured by free radical means, such as urethane acrylate oligomers and monomer reactive diluents from Sartomer USA, LLC. The compositions are capable of being cured by free radical polymerization induced by, for example, irradiation or heating.