The present application relates to a monomer, a method for preparing a block copolymer, a block copolymer, and uses thereof. Each monomer of the present application exhibits an excellent self-assembling property and is capable of forming a block copolymer to which a variety of required functions are granted as necessary without constraint.

The present application relates to a monomer, a method for preparing a block copolymer, a block copolymer, and uses thereof. Each monomer of the present application exhibits an excellent self-assembling property and is capable of forming a block copolymer to which a variety of required functions are granted as necessary without constraint.

A method for producing a fluoropolymer, which includes polymerizing a fluoromonomer in an aqueous medium in the presence of a polymer (1), the polymer (1) including a polymerized unit derived from a monomer CX.sub.2═CY(—CZ.sub.2—O—Rf-A), wherein X is the same or different and is —H or —F; Y is —H, —F, an alkyl group, or a fluorine-containing alkyl group; Z is the same or different and is —H, —F, an alkyl group, or a fluoroalkyl group; Rf is a C1-C40 fluorine-containing alkylene group or a C—C100 fluorine-containing alkylene group and having an ether bond; and A is —COOM, —SO.sub.3M, or —OSO.sub.3M, wherein M is —H, a metal atom, —NR.sup.7.sub.4, imidazolium optionally having a substituent, pyridinium optionally having a substituent, or phosphonium optionally having a substituent, wherein R.sup.7 is H or an organic group, providing that at least one of X, Y, and Z contains a fluorine atom.

A method for producing a fluoropolymer, which includes polymerizing a fluoromonomer in an aqueous medium in the presence of a polymer (1), the polymer (1) including a polymerized unit derived from a monomer CX.sub.2═CY(—CZ.sub.2—O—Rf-A), wherein X is the same or different and is —H or —F; Y is —H, —F, an alkyl group, or a fluorine-containing alkyl group; Z is the same or different and is —H, —F, an alkyl group, or a fluoroalkyl group; Rf is a C1-C40 fluorine-containing alkylene group or a C—C100 fluorine-containing alkylene group and having an ether bond; and A is —COOM, —SO.sub.3M, or —OSO.sub.3M, wherein M is —H, a metal atom, —NR.sup.7.sub.4, imidazolium optionally having a substituent, pyridinium optionally having a substituent, or phosphonium optionally having a substituent, wherein R.sup.7 is H or an organic group, providing that at least one of X, Y, and Z contains a fluorine atom.

A method for producing a fluoropolymer, which includes polymerizing a fluoromonomer in an aqueous medium in the presence of a polymer (1), the polymer (1) including a polymerized unit derived from a monomer CX.sub.2═CY(—CZ.sub.2—O—Rf-A), wherein X is the same or different and is —H or —F; Y is —H, —F, an alkyl group, or a fluorine-containing alkyl group; Z is the same or different and is —H, —F, an alkyl group, or a fluoroalkyl group; Rf is a C1-C40 fluorine-containing alkylene group or a C—C100 fluorine-containing alkylene group and having an ether bond; and A is —COOM, —SO.sub.3M, or —OSO.sub.3M, wherein M is —H, a metal atom, —NR.sup.7.sub.4, imidazolium optionally having a substituent, pyridinium optionally having a substituent, or phosphonium optionally having a substituent, wherein R.sup.7 is H or an organic group, providing that at least one of X, Y, and Z contains a fluorine atom.

A method for producing a fluoropolymer, which includes polymerizing a fluoromonomer in an aqueous medium in the presence of a polymer (1), the polymer (1) including a polymerized unit derived from a monomer CX.sub.2═CY(—CZ.sub.2—O—Rf-A), wherein X is the same or different and is —H or —F; Y is —H, —F, an alkyl group, or a fluorine-containing alkyl group; Z is the same or different and is —H, —F, an alkyl group, or a fluoroalkyl group; Rf is a C1-C40 fluorine-containing alkylene group or a C-C100 fluorine-containing alkylene group and having an ether bond; and A is —COOM, —SO.sub.3M, or —OSO.sub.3M, wherein M is —H, a metal atom, —NR.sup.7.sub.4, imidazolium optionally having a substituent, pyridinium optionally having a substituent, or phosphonium optionally having a substituent, wherein R.sup.7 is H or an organic group, providing that at least one of X, Y, and Z contains a fluorine atom.

A method for producing a fluoropolymer, which includes polymerizing a fluoromonomer in an aqueous medium in the presence of a polymer (1), the polymer (1) including a polymerized unit derived from a monomer CX.sub.2═CY(—CZ.sub.2—O—Rf-A), wherein X is the same or different and is —H or —F; Y is —H, —F, an alkyl group, or a fluorine-containing alkyl group; Z is the same or different and is —H, —F, an alkyl group, or a fluoroalkyl group; Rf is a C1-C40 fluorine-containing alkylene group or a C-C100 fluorine-containing alkylene group and having an ether bond; and A is —COOM, —SO.sub.3M, or —OSO.sub.3M, wherein M is —H, a metal atom, —NR.sup.7.sub.4, imidazolium optionally having a substituent, pyridinium optionally having a substituent, or phosphonium optionally having a substituent, wherein R.sup.7 is H or an organic group, providing that at least one of X, Y, and Z contains a fluorine atom.

Disclosed are a method for a preparing fluorine- and chlorine-containing conductive polymer resin, a single-side or double-side filled composite film prepared using the fluorine- and chlorine-containing conductive polymer resin, and a method for preparing the film. The fluorine- and chlorine-containing conductive polymer single-side or double-side filled composite film comprises a microporous film skeleton and the fluorine- and a chlorine-containing conductive polymer resin. The composite film is mechanically stronger, more waterproof, more impervious to water and toxic and harmful chemicals, and more moisture permeability. When applied to biochemical protective clothing, it can greatly enhance the combat effectiveness of the soldiers because it is light and more impervious to water and toxic and harmful chemicals, brings about comfort, and keeps the soldiers warm. When applied to fuel cells, it can provide better electrical properties due to its high conductivity and can allow the fuel, such as hydrogen or alcohol, to burn more completely.

The present technology relates to a method for producing a single-ion conducting polymer comprising grafting a thiol functionalized conductor compound onto a polymer compound to obtain the single-ion conducting polymer. In certain embodiments, the thiol functionalized conductor compound can be grafted onto polymers having low Tg which result in single-ion conducting polymers having improved conductivity.

The present technology relates to a method for producing a single-ion conducting polymer comprising grafting a thiol functionalized conductor compound onto a polymer compound to obtain the single-ion conducting polymer. In certain embodiments, the thiol functionalized conductor compound can be grafted onto polymers having low Tg which result in single-ion conducting polymers having improved conductivity.