The present invention is directed to film-forming compositions comprising: a) a non-chlorinated, linear polyolefin polymer comprising 0.5 to 10 percent by weight residues of an ethylenically unsaturated anhydride or acid; b) an aminoplast; and c) a component comprising: i) at least one non-chlorinated hydrocarbon having at least 18 carbon atoms and optionally aromatic groups and/or oxygen heteroatoms; and/or ii) an alkyd resin. The present invention is also drawn to methods of improving fuel resistance of a coated article, comprising: (1) applying the film-forming composition to a substrate to form a coated substrate; (2) optionally subjecting the coated substrate to a temperature for a time sufficient to cure the film-forming composition; (3) applying at least one curable film-forming composition to the coated substrate to form a multi-layer coated substrate; and (4) subjecting the multi-layer coated substrate to a temperature and for a time sufficient to cure all of the film-forming compositions.

The present invention is directed to film-forming compositions comprising: a) a non-chlorinated, linear polyolefin polymer comprising 0.5 to 10 percent by weight residues of an ethylenically unsaturated anhydride or acid; b) an aminoplast; and c) a component comprising: i) at least one non-chlorinated hydrocarbon having at least 18 carbon atoms and optionally aromatic groups and/or oxygen heteroatoms; and/or ii) an alkyd resin. The present invention is also drawn to methods of improving fuel resistance of a coated article, comprising: (1) applying the film-forming composition to a substrate to form a coated substrate; (2) optionally subjecting the coated substrate to a temperature for a time sufficient to cure the film-forming composition; (3) applying at least one curable film-forming composition to the coated substrate to form a multi-layer coated substrate; and (4) subjecting the multi-layer coated substrate to a temperature and for a time sufficient to cure all of the film-forming compositions.

Polymerizable liquids are described herein which, in some embodiments, can produce 3D printed articles of high resolution and desirable mechanical properties. In one aspect, a polymerizable liquid comprises an acrylate component, and a composite resin comprising a curable carrier and polymeric particles dispersed in the curable carrier. The polymerizable liquid also comprises a photoinitiator component.

Polymerizable liquids are described herein which, in some embodiments, can produce 3D printed articles of high resolution and desirable mechanical properties. In one aspect, a polymerizable liquid comprises an acrylate component, and a composite resin comprising a curable carrier and polymeric particles dispersed in the curable carrier. The polymerizable liquid also comprises a photoinitiator component.

Disclosed is an ink composition having excellent storage stability and capable of printing printed material having excellent metal tone. This active energy ray curable ink composition includes at least a scaly metal pigment, a polymerizable compound, and a photopolymerization initiator. The scaly metal pigment has a 50% volume average diameter of at least 0.05 μm and less than 0.5 μm, an average thickness of at least 5.0 nm and less than 50.0 nm, and a non-reactive solvent content of 0.01%-5.00% by mass.

Disclosed is an ink composition having excellent storage stability and capable of printing printed material having excellent metal tone. This active energy ray curable ink composition includes at least a scaly metal pigment, a polymerizable compound, and a photopolymerization initiator. The scaly metal pigment has a 50% volume average diameter of at least 0.05 μm and less than 0.5 μm, an average thickness of at least 5.0 nm and less than 50.0 nm, and a non-reactive solvent content of 0.01%-5.00% by mass.

An unsaturated polyester resin composition with low styrene volatility and a molding article thereof are provided. The unsaturated polyester resin composition of includes: 30 to 60 parts by weight of unsaturated polyester resin and 2 to 30 parts by weight of comonomer, and the comonomer includes: (a) methyl styrene, (b) hydroxy acrylate monomer and (c) diallyl phthalate monomer, and the weight ratio of the content (a), (b), and (c) is 6:3:1 in the comonomer.

An unsaturated polyester resin composition with low styrene volatility and a molding article thereof are provided. The unsaturated polyester resin composition of includes: 30 to 60 parts by weight of unsaturated polyester resin and 2 to 30 parts by weight of comonomer, and the comonomer includes: (a) methyl styrene, (b) hydroxy acrylate monomer and (c) diallyl phthalate monomer, and the weight ratio of the content (a), (b), and (c) is 6:3:1 in the comonomer.

There is described an acrylic polyester resin, obtainable by grafting an acrylic polymer with a polyester material. The polyester material is obtainable by polymerizing (i) a polyacid component, with (ii) a polyol component. At least one of the polyacid component and/or the polyol component comprises a monomer having an aliphatic group containing at least 15 carbon atoms. At least one of the polyacid component and/or the polyol component comprises a functional monomer operable to impart functionality on to the polyester resin, such that an acrylic polymer may be grafted with the polyester material via the use of said functionality. Also provided is an aqueous coating composition comprising the acrylic polyester resin and a packaging coated with the composition.

There is described an acrylic polyester resin, obtainable by grafting an acrylic polymer with a polyester material. The polyester material is obtainable by polymerizing (i) a polyacid component, with (ii) a polyol component. At least one of the polyacid component and/or the polyol component comprises a monomer having an aliphatic group containing at least 15 carbon atoms. At least one of the polyacid component and/or the polyol component comprises a functional monomer operable to impart functionality on to the polyester resin, such that an acrylic polymer may be grafted with the polyester material via the use of said functionality. Also provided is an aqueous coating composition comprising the acrylic polyester resin and a packaging coated with the composition.