The present invention refers to a hybrid photopolymer composition for additive manufacturing, —comprising 50-95% by weight of a free radically curable-component, farther comprising at least one (meth)acrylate monomer or oligomer, 5-49% by weight of a cationically curable component, further comprising a cycloaliphatic epoxide, an oxetane mixture, containing a monooxetane compound and a polyoxetane compound, and a thermoplastic polycaprolactone with a molecular weight of 20,000-100,000 g/mol, a free radical photoinitiator, a UV blocker, a cationic photoinitiator, optionally a cationic photosensitiser, and optionally a thermal initiator, wherein the percent by weight is based on the total weight of the photopolymer' composition. The invention also relates to the use of a photopolymer composition according to the present invention for producing a three-dimensional object through additive manufacturing and to a three-dimensional object obtained through additive manufacturing using the photopolymer composition—according the present invention.

The present invention relates to a photopolymer composition comprising: a polymer matrix or a precursor thereof including a reaction product of a polyol including a polyrotaxane compound and a compound containing at least one isocyanate group; a photoreactive monomer; and a photoinitiator. The present invention also relates to a hologram recording medium produced from the photopolymer composition, an optical element comprising the hologram recording medium, and a holographic recording method using the photopolymer composition.

The present disclosure provides an aqueous dispersion. The aqueous dispersion includes a) water; b) a surfactant having at least one ethylenically unsaturated group; and c) polyester particles dispersed in the water. The polyester particles include a water-insoluble polyester having a weight average molecular weight of 20 kiloDaltons or greater, and the polyester particles have an average diameter that is submicron in size. Further, the present disclosure provides a method of making the aqueous dispersion. The method includes a) dissolving a water-insoluble polyester in a water-immiscible solvent to form a polyester solution; b) combining the polyester solution with an aqueous solution including water and a surfactant; and c) removing at least a portion of the water-immiscible solvent to form the aqueous dispersion including polyester particles dispersed in the water. The present disclosure also provides a photopolymerizable composition including a) water; b) a surfactant; c) polyester particles dispersed in the water; d) a photoinitiator; e) at least one ethylenically unsaturated monomer dispersed in the water; and f) an optional polymerization inhibitor. The present disclosure also provides coatings and articles prepared from the aqueous dispersion or photopolymerizable composition.

The present disclosure provides an aqueous dispersion. The aqueous dispersion includes a) water; b) a surfactant having at least one ethylenically unsaturated group; and c) polyester particles dispersed in the water. The polyester particles include a water-insoluble polyester having a weight average molecular weight of 20 kiloDaltons or greater, and the polyester particles have an average diameter that is submicron in size. Further, the present disclosure provides a method of making the aqueous dispersion. The method includes a) dissolving a water-insoluble polyester in a water-immiscible solvent to form a polyester solution; b) combining the polyester solution with an aqueous solution including water and a surfactant; and c) removing at least a portion of the water-immiscible solvent to form the aqueous dispersion including polyester particles dispersed in the water. The present disclosure also provides a photopolymerizable composition including a) water; b) a surfactant; c) polyester particles dispersed in the water; d) a photoinitiator; e) at least one ethylenically unsaturated monomer dispersed in the water; and f) an optional polymerization inhibitor. The present disclosure also provides coatings and articles prepared from the aqueous dispersion or photopolymerizable composition.

A liquid repellent laminate according to an embodiment includes a transparent substrate having a first principal face and a second principal face as a rear face of the first principal face, and a liquid repellent membrane supported on the first principal face of the transparent substrate. The liquid repellent membrane is a monomolecular membrane of a fluorine-containing organic compound that binds to a surface of the transparent substrate through a binding moiety represented by —Z—O—* (wherein Z represents an atomic group containing a Si atom, and * represents a binding site to the surface of the transparent substrate) and includes a perfluoroalkyl group having 4 or less carbon atoms at a terminal, and the fluorine-containing organic compound undergoes intermolecular bonding between the fluorine-containing organic compounds adjacent to each other by mutual binding of Z in the formula.

A liquid repellent laminate according to an embodiment includes a transparent substrate having a first principal face and a second principal face as a rear face of the first principal face, and a liquid repellent membrane supported on the first principal face of the transparent substrate. The liquid repellent membrane is a monomolecular membrane of a fluorine-containing organic compound that binds to a surface of the transparent substrate through a binding moiety represented by —Z—O—* (wherein Z represents an atomic group containing a Si atom, and * represents a binding site to the surface of the transparent substrate) and includes a perfluoroalkyl group having 4 or less carbon atoms at a terminal, and the fluorine-containing organic compound undergoes intermolecular bonding between the fluorine-containing organic compounds adjacent to each other by mutual binding of Z in the formula.

A grafted polylactic acid is provided, wherein the grafted polylactic acid contains carboxylic acid end groups in an amount from 1.0 to 10.0 mg KOH/g and contains epoxide groups in an amount from 0.005 to 0.500 mmol/g.

A grafted polylactic acid is provided, wherein the grafted polylactic acid contains carboxylic acid end groups in an amount from 1.0 to 10.0 mg KOH/g and contains epoxide groups in an amount from 0.005 to 0.500 mmol/g.

A grafted polylactic acid is provided, wherein the grafted polylactic acid contains carboxylic acid end groups in an amount from 1.0 to 10.0 mg KOH/g and contains epoxide groups in an amount from 0.005 to 0.500 mmol/g.

The present invention relates to a continuous process for the production of polyol modified polyalkenylene terephthalates and the application of such polyol modified polyalkylene therephtalate on wire enamels.