The present invention relates to a continuous process for the production of polyol modified polyalkenylene terephthalates and the application of such polyol modified polyalkylene therephtalate on wire enamels.

The invention relates to novel linear, semi-crystalline, functional fluoropolymers that have been obtained by copolymerizing a fluorinated vinylic monomer and a hydrophilic (meth)acrylic comonomer bearing a halogen functionality.

The invention relates to novel linear, semi-crystalline, functional fluoropolymers that have been obtained by copolymerizing a fluorinated vinylic monomer and a hydrophilic (meth)acrylic comonomer bearing a halogen functionality.

A polylactic acid copolymer having more improved hydrolizability and hydrophilic property than those of the polylactic acid. The polylactic acid copolymer is obtained by the copolymerization of a polylactic acid with an acid-releasing ester polymer capable of releasing an acid other than the lactic acid upon the hydrolysis. The polylactic acid copolymer has a quantity of heat of fusion ΔH of not more than 20 J/g as measured by using the DSC when the temperature is elevated the second time, contains the copolymer units stemming from the acid-releasing ester polymer in an amount of 0.5 to 35% by mass, and has a weight average molecular weight in a range of 15,000 to 40,000.

A polylactic acid copolymer having more improved hydrolizability and hydrophilic property than those of the polylactic acid. The polylactic acid copolymer is obtained by the copolymerization of a polylactic acid with an acid-releasing ester polymer capable of releasing an acid other than the lactic acid upon the hydrolysis. The polylactic acid copolymer has a quantity of heat of fusion ΔH of not more than 20 J/g as measured by using the DSC when the temperature is elevated the second time, contains the copolymer units stemming from the acid-releasing ester polymer in an amount of 0.5 to 35% by mass, and has a weight average molecular weight in a range of 15,000 to 40,000.

A biodegradable polyester is provided. The biodegradable polyester is a transesterification or esterification reaction product of a reactant (a) and a reactant (b). The reactant (a) is a modified linear saccharide oligomer. The reactant (b) is a polyester, or the reactant (b) includes a dicarboxylic acid and a diol. The modified saccharide oligomer is a reaction product of a saccharide oligomer and a modifier.

A biodegradable polyester is provided. The biodegradable polyester is a transesterification or esterification reaction product of a reactant (a) and a reactant (b). The reactant (a) is a modified linear saccharide oligomer. The reactant (b) is a polyester, or the reactant (b) includes a dicarboxylic acid and a diol. The modified saccharide oligomer is a reaction product of a saccharide oligomer and a modifier.

The invention relates to the field of preparing biodegradable polymer slow/controlled release composite, in particular to a biodegradable polymer slow/controlled release binary composite urea-formaldehyde/poly(butylene succinate) and a biodegradable polymer slow/controlled release ternary nanocomposite urea-formaldehyde/poly(butylene succinate)/potassium dihydrogen phosphate. The following steps are included: uniformly mixing two components poly(butylene succinate) and methylol-urea or three components poly(butylene succinate), methylol-urea and potassium dihydrogen phosphate, and then extruding the resulting mixture by an extruder, and the biodegradable polymer slow/controlled release composite urea-formaldehyde/poly(butylene succinate) containing nutrient N and the biodegradable polymer slow/controlled release nanocomposite urea-formaldehyde/poly(butylene succinate)/potassium dihydrogen phosphate containing nutrients of N, P and K are obtained respectively. As one of the raw materials, methylol-urea, the precursor of urea-formaldehyde, can react by way of melt polycondensation to form urea-formaldehyde macromolecular chains with different polymerization degrees at high temperature in the extruder, which are dispersed among the PBS macromolecular chains, thereby obtaining the composite UF/PBS of the present invention; and the hindering effect of the molecular segments of urea-formaldehyde and poly(butylene succinate) and the hydrogen bond interaction between the components result in that potassium dihydrogen phosphate crystals dissolved in the water produced by the polycondensation reaction are restricted to nanoscale during their precipitation process, so as to prepare nanocomposite UF/PBS/MKP. The prepared composites all have excellent mechanical properties, and can be directly used as a biodegradable polymer slow/controlled release fertilizer, or as a matrix polymer to prepare other types of slow release fertilizers, and the formulae with high PBS contents can also replace PBS to prepare other agricultural implements, such as agricultural films, nursery pots and vegetation nets.

The invention relates to the field of preparing biodegradable polymer slow/controlled release composite, in particular to a biodegradable polymer slow/controlled release binary composite urea-formaldehyde/poly(butylene succinate) and a biodegradable polymer slow/controlled release ternary nanocomposite urea-formaldehyde/poly(butylene succinate)/potassium dihydrogen phosphate. The following steps are included: uniformly mixing two components poly(butylene succinate) and methylol-urea or three components poly(butylene succinate), methylol-urea and potassium dihydrogen phosphate, and then extruding the resulting mixture by an extruder, and the biodegradable polymer slow/controlled release composite urea-formaldehyde/poly(butylene succinate) containing nutrient N and the biodegradable polymer slow/controlled release nanocomposite urea-formaldehyde/poly(butylene succinate)/potassium dihydrogen phosphate containing nutrients of N, P and K are obtained respectively. As one of the raw materials, methylol-urea, the precursor of urea-formaldehyde, can react by way of melt polycondensation to form urea-formaldehyde macromolecular chains with different polymerization degrees at high temperature in the extruder, which are dispersed among the PBS macromolecular chains, thereby obtaining the composite UF/PBS of the present invention; and the hindering effect of the molecular segments of urea-formaldehyde and poly(butylene succinate) and the hydrogen bond interaction between the components result in that potassium dihydrogen phosphate crystals dissolved in the water produced by the polycondensation reaction are restricted to nanoscale during their precipitation process, so as to prepare nanocomposite UF/PBS/MKP. The prepared composites all have excellent mechanical properties, and can be directly used as a biodegradable polymer slow/controlled release fertilizer, or as a matrix polymer to prepare other types of slow release fertilizers, and the formulae with high PBS contents can also replace PBS to prepare other agricultural implements, such as agricultural films, nursery pots and vegetation nets.

There is described an acrylic polyester resin, obtainable by grafting an acrylic polymer with a polyester material. The polyester material is obtainable by polymerizing (i) a polyacid component, with (ii) a polyol component, wherein one or both of the polyacid component and the polyol component includes a Tg enhancing monomer. One of the polyacid component or the polyol component comprises a functional monomer operable to impart functionality on to the polyester resin, such that an acrylic polymer may be grafted with the polyester material via the use of said functionality. Also provided is an aqueous or powder coating composition comprising the acrylic polyester resin and a metal packaging containing coated with the composition.