The present invention relates to a continuous process for the production of polyol modified polyalkenylene terephthalates and the application of such polyol modified polyalkylene therephtalate on wire enamels.

The present invention relates to a continuous process for the production of polyol modified polyalkenylene terephthalates and the application of such polyol modified polyalkylene therephtalate on wire enamels.

An object of the present invention is to provide an active energy ray-curable inkjet ink composition that has a low viscosity such that the composition can be ejected as an inkjet ink, and can exhibit sufficient adhesion to a plastic substrate having low surface free energy. The present invention provides an active energy ray-curable inkjet ink composition comprising a polyester resin (A), wherein the polyester resin (A) contains a structural unit (a-1) derived from a polybasic acid and a structural unit (a-2) derived from a polyhydric alcohol, the structural unit (a-2) derived from a polyhydric alcohol contains 20 mol % or more and 100 mol % or less of a structural unit derived from hydrogenated bisphenol A, and the polyester resin (A) has a number average molecular weight (Mn) of 500 to 4,500 and an acid value of 5 to 300.

An object of the present invention is to provide an active energy ray-curable inkjet ink composition that has a low viscosity such that the composition can be ejected as an inkjet ink, and can exhibit sufficient adhesion to a plastic substrate having low surface free energy. The present invention provides an active energy ray-curable inkjet ink composition comprising a polyester resin (A), wherein the polyester resin (A) contains a structural unit (a-1) derived from a polybasic acid and a structural unit (a-2) derived from a polyhydric alcohol, the structural unit (a-2) derived from a polyhydric alcohol contains 20 mol % or more and 100 mol % or less of a structural unit derived from hydrogenated bisphenol A, and the polyester resin (A) has a number average molecular weight (Mn) of 500 to 4,500 and an acid value of 5 to 300.

Laminated steel having a low interface bubble rate, comprising: a substrate with a surface roughness of 0.15-0.25 m and a modified flexible polyester film thermally laminated onto the surface of the substrate. The modified flexible polyester film is obtained by copolymerization modification of ethylene terephthalate with a low-molecular-weight aliphatic polyester. A method for manufacturing the laminated steel having an extremely low interface bubble rate, comprising the steps of: (1) preheating and then heating the substrate; (2) uncoiling the modified flexible polyester film at room temperature, and then thermally laminating same onto the substrate; and (3) cooling and squeeze-drying. The laminated steel having a low interface bubble rate is made of the substrate with a low surface roughness and the modified flexible polyester thermally laminated onto the surface of the substrate, so that the laminated steel has the low interface bubble rate, high product surface quality, excellent adhesion property, and is applicable for forming into deep-drawn containers.

Laminated steel having a low interface bubble rate, comprising: a substrate with a surface roughness of 0.15-0.25 m and a modified flexible polyester film thermally laminated onto the surface of the substrate. The modified flexible polyester film is obtained by copolymerization modification of ethylene terephthalate with a low-molecular-weight aliphatic polyester. A method for manufacturing the laminated steel having an extremely low interface bubble rate, comprising the steps of: (1) preheating and then heating the substrate; (2) uncoiling the modified flexible polyester film at room temperature, and then thermally laminating same onto the substrate; and (3) cooling and squeeze-drying. The laminated steel having a low interface bubble rate is made of the substrate with a low surface roughness and the modified flexible polyester thermally laminated onto the surface of the substrate, so that the laminated steel has the low interface bubble rate, high product surface quality, excellent adhesion property, and is applicable for forming into deep-drawn containers.

The present invention refers to a hybrid photopolymer composition for additive manufacturing, comprising 50-95% by weight of a free radically curable-component, farther comprising at least one (meth)acrylate monomer or oligomer, 5-49% by weight of a cationically curable component, further comprising a cycloaliphatic epoxide, an oxetane mixture, containing a monooxetane compound and a polyoxetane compound, and a thermoplastic polycaprolactone with a molecular weight of 20,000-100,000 g/mol, a free radical photoinitiator, a UV blocker, a cationic photoinitiator, optionally a cationic photosensitiser, and optionally a thermal initiator, wherein the percent by weight is based on the total weight of the photopolymer' composition. The invention also relates to the use of a photopolymer composition according to the present invention for producing a three-dimensional object through additive manufacturing and to a three-dimensional object obtained through additive manufacturing using the photopolymer compositionaccording the present invention.

The present invention refers to a hybrid photopolymer composition for additive manufacturing, comprising 50-95% by weight of a free radically curable-component, farther comprising at least one (meth)acrylate monomer or oligomer, 5-49% by weight of a cationically curable component, further comprising a cycloaliphatic epoxide, an oxetane mixture, containing a monooxetane compound and a polyoxetane compound, and a thermoplastic polycaprolactone with a molecular weight of 20,000-100,000 g/mol, a free radical photoinitiator, a UV blocker, a cationic photoinitiator, optionally a cationic photosensitiser, and optionally a thermal initiator, wherein the percent by weight is based on the total weight of the photopolymer' composition. The invention also relates to the use of a photopolymer composition according to the present invention for producing a three-dimensional object through additive manufacturing and to a three-dimensional object obtained through additive manufacturing using the photopolymer compositionaccording the present invention.

A biodegradable laminate, wherein a polyvinyl alcohol resin layer is laminated on at least one surface of an aliphatic polyester resin layer through an adhesive layer, which is excellent in biodegradability and gas barrier properties, and also excellent in interlayer adhesiveness, is obtained. The adhesive layer comprises, as a main component, a polyester resin (A) which has a polar group and is obtained by graft polymerization of an ,-unsaturated carboxylic acid or an anhydride thereof on a biodegradable polyester resin (A) comprising at least one structural unit selected from structural units represented by the following general formulae (1), (2), and (3): ##STR00001##

A biodegradable laminate, wherein a polyvinyl alcohol resin layer is laminated on at least one surface of an aliphatic polyester resin layer through an adhesive layer, which is excellent in biodegradability and gas barrier properties, and also excellent in interlayer adhesiveness, is obtained. The adhesive layer comprises, as a main component, a polyester resin (A) which has a polar group and is obtained by graft polymerization of an ,-unsaturated carboxylic acid or an anhydride thereof on a biodegradable polyester resin (A) comprising at least one structural unit selected from structural units represented by the following general formulae (1), (2), and (3): ##STR00001##