There is described an aqueous coating composition, the aqueous coating composition comprising an acrylic polyester resin, obtainable by grafting an acrylic polymer and a polyester material, the polyester material being obtainable by polymerizing: (i) a polyacid component, with (ii) a polyol component. At least one of the polyacid component and/or the polyol component comprises a functional monomer operable to impart functionality on to the polyester resin, such that an acrylic polymer may be grafted with the polyester material via the use of said functionality. The coating composition further containing a crosslinking material, wherein the crosslinking material comprises material according to formula (I); as shown in claim 1; wherein R.sub.1 is selected from aryl (such as C.sub.4 to C.sub.24 aryl), or aralkyl (such as C.sub.5 to C.sub.25 aralkyl); R.sub.2 to R.sub.5 are each independently hydrogen, alkyl (such as C.sub.1 to C.sub.20 alkyl), aryl (such as C.sub.4 to C.sub.24 aryl), aralkyl (such as C.sub.5 to C.sub.25 aralkyl) or CHR.sub.8OR.sub.9; wherein R.sub.8 and R.sub.9 are each independently hydrogen, alkyl (such as C.sub.1 to C.sub.20 alkyl), aryl (such as C.sub.4 to C.sub.24 aryl), aralkyl (such as C.sub.5 to C.sub.25 aralkyl), alkoxyalkyl (such as C.sub.2 to C.sub.40 alkoxyalkyl) or an alkaryl (such as C.sub.5 to C.sub.25 alkaryl); wherein at least one of R.sub.2 to R.sub.5, is CHR.sub.8OR.sub.9, suitably all of R.sub.2 to R.sub.5, are CHR.sub.8OR.sub.9.

There is described an aqueous coating composition, the aqueous coating composition comprising an acrylic polyester resin, obtainable by grafting an acrylic polymer and a polyester material, the polyester material being obtainable by polymerizing: (i) a polyacid component, with (ii) a polyol component. At least one of the polyacid component and/or the polyol component comprises a functional monomer operable to impart functionality on to the polyester resin, such that an acrylic polymer may be grafted with the polyester material via the use of said functionality. The coating composition further containing a crosslinking material, wherein the crosslinking material comprises material according to formula (I); as shown in claim 1; wherein R.sub.1 is selected from aryl (such as C.sub.4 to C.sub.24 aryl), or aralkyl (such as C.sub.5 to C.sub.25 aralkyl); R.sub.2 to R.sub.5 are each independently hydrogen, alkyl (such as C.sub.1 to C.sub.20 alkyl), aryl (such as C.sub.4 to C.sub.24 aryl), aralkyl (such as C.sub.5 to C.sub.25 aralkyl) or CHR.sub.8OR.sub.9; wherein R.sub.8 and R.sub.9 are each independently hydrogen, alkyl (such as C.sub.1 to C.sub.20 alkyl), aryl (such as C.sub.4 to C.sub.24 aryl), aralkyl (such as C.sub.5 to C.sub.25 aralkyl), alkoxyalkyl (such as C.sub.2 to C.sub.40 alkoxyalkyl) or an alkaryl (such as C.sub.5 to C.sub.25 alkaryl); wherein at least one of R.sub.2 to R.sub.5, is CHR.sub.8OR.sub.9, suitably all of R.sub.2 to R.sub.5, are CHR.sub.8OR.sub.9.

A grafted polylactic acid is provided, wherein the grafted polylactic acid contains carboxylic acid end groups in an amount from 1.0 to 10.0 mg KOH/g and contains epoxide groups in an amount from 0.005 to 0.500 mmol/g.

A grafted polylactic acid is provided, wherein the grafted polylactic acid contains carboxylic acid end groups in an amount from 1.0 to 10.0 mg KOH/g and contains epoxide groups in an amount from 0.005 to 0.500 mmol/g.

Described is a transparent polymer-based composite and a method for preparing a transparent polymer-based composite. The transparent polymer-based composite includes an activated polycarbonate and one or more nanoparticles grafted to the activated polycarbonate. The activated carbonate is formed via a transcarbonation reaction of a mixture of a carbonic acid species having terminal ester groups and a bisphenol-A with sodium hydroxide and ortho-dichlorobenzene. The transparent polymer-based composite may be used to replace the glass front-sheet of solar panels for photovoltaic applications.

Described is a transparent polymer-based composite and a method for preparing a transparent polymer-based composite. The transparent polymer-based composite includes an activated polycarbonate and one or more nanoparticles grafted to the activated polycarbonate. The activated carbonate is formed via a transcarbonation reaction of a mixture of a carbonic acid species having terminal ester groups and a bisphenol-A with sodium hydroxide and ortho-dichlorobenzene. The transparent polymer-based composite may be used to replace the glass front-sheet of solar panels for photovoltaic applications.

Provided is a resin composition capable of providing a three-dimensionally photofabricated object having high heat resistance while having water solubility. The resin composition is a resin composition for three-dimensional photofabrication containing a reactive monomer, a water-soluble polymer, and a photopolymerization initiator. A cured product of the resin composition has a main tan ? peak temperature of 80? C. or higher. A 1-mm-thick cured product of the resin composition exhibits a remaining thickness of 0.7 mm or smaller after 5-hour immersion in water that is at room temperature.

Provided is a resin composition capable of providing a three-dimensionally photofabricated object having high heat resistance while having water solubility. The resin composition is a resin composition for three-dimensional photofabrication containing a reactive monomer, a water-soluble polymer, and a photopolymerization initiator. A cured product of the resin composition has a main tan ? peak temperature of 80? C. or higher. A 1-mm-thick cured product of the resin composition exhibits a remaining thickness of 0.7 mm or smaller after 5-hour immersion in water that is at room temperature.

There is described an acrylic polyester resin, obtainable by grafting an acrylic polymer with a polyester material. The polyester material is obtainable by polymerizing (i) a polyacid component, with (ii) a polyol component, including2,2,4,4-tetraalkyl-cyclobutane-1,3-diol. One of the polyacid component or the polyol component comprises a functional monomer operable to impart functionality on to the polyester resin, such that an acrylic polymer may be grafted with the polyester material via the use of said functionality. Also provided is an aqueous coating composition comprising the acrylic polyester resin and a metal packaging containing coated with the composition.

There is described an acrylic polyester resin, obtainable by grafting an acrylic polymer with a polyester material. The polyester material is obtainable by polymerizing (i) a polyacid component, with (ii) a polyol component, including2,2,4,4-tetraalkyl-cyclobutane-1,3-diol. One of the polyacid component or the polyol component comprises a functional monomer operable to impart functionality on to the polyester resin, such that an acrylic polymer may be grafted with the polyester material via the use of said functionality. Also provided is an aqueous coating composition comprising the acrylic polyester resin and a metal packaging containing coated with the composition.