Patent classifications
C08F297/06
Manufacturing method for propylene block copolymer
A method for producing a propylene-based block copolymer produces a propylene-based copolymer that exhibits excellent stereoregularity, rigidity, and impact resistance in a convenient and efficient manner while achieving high polymerization activity. The method for producing a propylene-based block copolymer includes bringing a catalyst into contact with propylene, or propylene and an -olefin, and bringing an electron donor compound into contact with the resulting product to produce a propylene-based block copolymer, the catalyst including a solid catalyst component that includes titanium, magnesium, a halogen, and an internal electron donor compound, a specific organoaluminum compound, and a specific external electron donor compound.
Manufacturing method for propylene block copolymer
A method for producing a propylene-based block copolymer produces a propylene-based copolymer that exhibits excellent stereoregularity, rigidity, and impact resistance in a convenient and efficient manner while achieving high polymerization activity. The method for producing a propylene-based block copolymer includes bringing a catalyst into contact with propylene, or propylene and an -olefin, and bringing an electron donor compound into contact with the resulting product to produce a propylene-based block copolymer, the catalyst including a solid catalyst component that includes titanium, magnesium, a halogen, and an internal electron donor compound, a specific organoaluminum compound, and a specific external electron donor compound.
Manufacturing method for propylene block copolymer
A method for producing a propylene-based block copolymer produces a propylene-based copolymer that exhibits excellent stereoregularity, rigidity, and impact resistance in a convenient and efficient manner while achieving high polymerization activity. The method for producing a propylene-based block copolymer includes bringing a catalyst into contact with propylene, or propylene and an -olefin, and bringing an electron donor compound into contact with the resulting product to produce a propylene-based block copolymer, the catalyst including a solid catalyst component that includes titanium, magnesium, a halogen, and an internal electron donor compound, a specific organoaluminum compound, and a specific external electron donor compound.
Process for producing thermoplastic elastomer, and thermoplastic elastomer
A method for producing a thermoplastic elastomer includes forming a first block by copolymerizing a C4-C7 isoolefin monomer and alkylstyrene in the presence of a polymerization initiator; and forming a second block by polymerizing aromatic vinyl monomers. The thermoplastic elastomer comprises the first block and the second block. An amount of unreacted portion of the alkylstyrene during the formation of the first block is maintained at a molar ratio of not more than 1/90 relative to a total amount of the isoolefin monomer. The alkylstyrene is represented by the general formula (1), and the polymerization initiator is represented by the general formula (2).
Metallic complex catalyst, polymerization methods employing same and polymer products thereof
Metallic complexes having indenyl ligands can be used as an ingredient of a catalyst system. The catalyst system can be used in polymerizations of ethylenically unsaturated hydrocarbon monomers that include both olefins and polyenes. Embodiments of the catalyst system can provide interpolymers that include polyene mer and from 40 to 75 mole percent ethylene mer, with a plurality of the ethylene mer being randomly distributed. The catalyst system also can be used in solution polymerizations conducted in C.sub.5-C.sub.12 alkanes, yielding interpolymers that include at least 10 mole percent ethylene mer.
Metallic complex catalyst, polymerization methods employing same and polymer products thereof
Metallic complexes having indenyl ligands can be used as an ingredient of a catalyst system. The catalyst system can be used in polymerizations of ethylenically unsaturated hydrocarbon monomers that include both olefins and polyenes. Embodiments of the catalyst system can provide interpolymers that include polyene mer and from 40 to 75 mole percent ethylene mer, with a plurality of the ethylene mer being randomly distributed. The catalyst system also can be used in solution polymerizations conducted in C.sub.5-C.sub.12 alkanes, yielding interpolymers that include at least 10 mole percent ethylene mer.
Light as catalytic switch: metal-organic insertion/light initiated radical (MILRad) polymerization
A method of polymerizing a first, and a second class of monomers to form product polymer. The first class of monomers polymerize via a radical pathway in the presence of light, and the second class of monomers polymerize via an insertion pathway in the absence of light.
POLYURETHANE ACRYLATE PROTECTIVE DISPLAY FILM
A display film includes a transparent cross-linked polyurethane acrylate layer. The transparent cross-linked polyurethane acrylate layer having a glass transition temperature of 10 degrees Celsius or less and a Tan Delta peak value of 0.5 or greater.
POLYURETHANE ACRYLATE PROTECTIVE DISPLAY FILM
A display film includes a transparent cross-linked polyurethane acrylate layer. The transparent cross-linked polyurethane acrylate layer having a glass transition temperature of 10 degrees Celsius or less and a Tan Delta peak value of 0.5 or greater.
Polymeric compositions as pour point depressants for crude oils
Polymeric compositions obtainable by free-radical polymerization of at least two different alkyl (meth)acrylates in the presence of at least one ethylene-vinyl ester copolymer, the alkyl (meth)acrylates used being a mixture comprising alkyl (meth)acrylates having linear C.sub.12- to C.sub.60-alkyl radicals and different alkyl (meth)acrylates having linear C.sub.1- to C.sub.11-alkyl radicals and/or branched C.sub.4- to C.sub.60-alkyl radicals and/or cyclic C.sub.5- to C.sub.20-alkyl radicals. The use of such polymeric compositions as pour point depressants for crude oils, mineral oils or mineral oil products.