Patent classifications
C08F2420/06
SUPPORTED HYBRID CATALYST AND METHOD FOR PREPARING OLEFIN POLYMER USING THE SAME
The present invention relates to a supported hybrid catalyst and a method for preparing olefin polymer using the same. Using the supported hybrid catalyst, olefin polymer that maintains excellent mechanical strength of olefin polymer polymerized with the existing metallocene catalyst, but exhibits remarkably improved processibility compared to the existing olefin polymer, can be provided.
TRANSITION METAL COMPLEXES, CATALYST COMPOSITIONS INCLUDING THE SAME, AND METHOD FOR PREPARING POLYOLEFINS THEREWITH
The present invention relates to a transition metal complex that exhibits high activity in the polymerization reaction of olefin monomers and improved copolymerization activity, thus enabling the preparation of a low density, high molecular weight polyolefin, a catalyst composition including the same, and a method for preparing a polyolefin using the composition.
Transition metal compound having heteroatom, catalyst composition including the same and preparation method of polymer using the catalyst composition
The present invention discloses a transition metal compound including a heteroatom and having a novel structure, a catalyst composition including the same, and a preparation method of a polymer using the catalyst composition. The transition metal compound according to an embodiment of the present invention may be used as a catalyst having good copolymerization properties, and a polymer having a high molecular weight at a low density region may be prepared.
Metallocene compound, catalyst composition including the same, and method of preparing olefin-based polymer using the same
Provided are a novel metallocene compound, a catalyst composition including the same, and a method of preparing an olefin-based polymer using the same. The metallocene compound according to the present invention or the catalyst composition including the same may be used for the preparation of an olefin-based polymer, may have excellent polymerization ability, and may produce an olefin-based polymer having a high molecular weight. In particular, when the metallocene compound according to the present invention is employed, an olefin-based polymer having a high molecular weight may be polymerized because the metallocene compound shows high polymerization activity even when it is supported on a support and maintains high activity even in the presence of hydrogen because of its low hydrogen reactivity.
Metallocene compound, catalyst composition including the same, and method of preparing polyolefin using the same
Provided are a novel metallocene compound, a catalyst composition including the same, and a method of preparing a polyolefin using the same. The metallocene compound according to the present invention and the catalyst composition including the same may be used for the preparation of a polyolefin, may have excellent polymerization ability, and may produce a polyolefin having an ultra-high molecular weight. In particular, when the metallocene compound according to the present invention is employed, an olefin-based polymer having an ultra-high molecular weight may be polymerized because the metallocene compound shows high polymerization activity even when it is supported on a support.
Method for preparing polyolefin and polyolefin prepared thereby
The present invention relates to a method for preparing polyolefin that can easily and effectively prepare polyolefin having high molecular weight and various molecular weight distributions, which was difficult to prepare using the existing metallocene catalyst, and polyolefin prepared thereby. The method for preparing polyolefin comprises the step of polymerizing olefin monomers, in the presence of a metallocene supported catalyst wherein a metallocene compound having a specific chemical structure is supported in a carrier, and hydrogen gas.
Method of preparing polyolefin, and polyolefin prepared thereby
A method of preparing a polyolefin, wherein the method is used to more effectively prepare a polyolefin which has a high molecular weight and multimodal molecular weight distribution, thereby being preferably used for blow-molding or the like, and a polyolefin prepared thereby, are provided.
Metallocene complex and method for producing olefin polymer
The present invention provides a metallocene complex capable of producing a homopolypropylene having a high melting point in the homopolymerization of propylene, and a production method of an olefin polymer using the same. The metallocene complex of the present invention is represented by formula [I].
Hybrid supported metallocene catalyst and process for preparing polyethylene copolymer using the same
The present disclosure provides a hybrid supported metallocene catalyst useful for preparing a polyethylene copolymer capable of producing an mLLDPE shrink film having excellent shrinkage and processability with excellent mechanical properties, and a process for preparing a polyethylene copolymer using the same. The hybrid supported metallocene catalyst comprises at least one first metallocene compound selected from compounds represented by the following Chemical Formula 1 and at least one second metallocene compound selected from compounds represented by the following Chemical Formula 2: ##STR00001## wherein the variables are described herein.
Supported catalyst for propylene polymerization and method for producing polypropylene resin using same
The present invention relates to a supported catalyst for propylene polymerization in which a first transition metal compound contributing to the production of crystalline polypropylene and a second transition metal compound contributing to the production of rubbery polypropylene are co-supported, and a method for producing a polypropylene resin using same. By using the supported catalyst, according to the present invention, it is possible to produce, by a single step of propylene polymerization, a polypropylene resin in which crystalline polypropylene and rubbery polypropylene are simultaneously formed.