The ethylene/1-hexene copolymer according to the present invention has excellent processability and mechanical properties, and thus can be applied to various fields such as food containers.

The present invention relates to a supported hybrid catalyst system for ethylene slurry polymerization and a method for preparing ethylene polymer therewith. The supported hybrid catalyst system according to the present invention may exhibit high activity during ethylene slurry polymerization, and enables preparation of an ethylene polymer having a narrow molecular weight distribution but excellent processability.

The present invention relates to a supported hybrid catalyst and a method for preparing olefin polymer using the same. Using the supported hybrid catalyst, olefin polymer that maintains excellent mechanical strength of olefin polymer polymerized with the existing metallocene catalyst, but exhibits remarkably improved processibility compared to the existing olefin polymer, can be provided.

The present invention relates to a catalyst composition for synthesizing an olefin copolymer, including a first metallocene catalyst, a second metallocene catalyst, and a third metallocene catalyst, each having a specific structure, and a method for preparing an olefin copolymer using the catalyst composition for synthesizing an olefin copolymer.

A preparation method for a metallocene compound is provided. The method includes: stirring at least one compound I among compounds expressed by the following chemical formula (I) and a hydrogenation reaction catalyst of 0.10 to 0.55 parts by weight based on 100 parts by weight of the compound I under a hydrogen atmosphere; and obtaining a metallocene compound containing at least one first compound among the compounds expressed by the following chemical formula (1). Chemical formula (I) and (1) are provided in the specification.

Butadiene-isoprene diblock copolymer formed by a block of crystalline polybutadiene (hard block) and by a block of amorphous polyisoprene (soft block). Said butadiene-isoprene diblock copolymer can be advantageously used both in the footwear industry (for example, in the production of shoe soles), and in the production of tires for motor vehicles and/or trucks.

The present disclosure provides a novel transition metal compound having excellent structural stability together with polymerization reactivity, and thereby is useful as a catalyst in preparing an olefin-based polymer, particularly, a high molecular weight and low density olefin-based polymer, and a catalyst composition including the same.

The present invention relates to a metallocene complex with a heteroatom-containing -ligand, having a chemical structure represented by formula (I) as below:

##STR00001## wherein M is a transition metal element from Group 3, Group 4, Group 5 and Group 6 in the periodic table, including lanthanides and actinides; X, being the same as or different from each other, is selected from hydrogen, halogen, an alkyl group R, an alkoxyl group OR, a mercapto group SR, a carboxyl group OCOR, an amino group NR.sub.2, a phosphino group PR.sub.2, OR.sup.O and OSO.sub.2CF.sub.3; n is an integer from 1 to 4 and is not zero; the charge number resulted from multiplying n by the charge number of X equals to the charge number of the central metal atom M minus 2; Q is a divalent radical; A is a -ligand; and Z is a -ligand; the process for producing the same; a catalyst system of the same; and use of the catalyst system.

The present disclosure provides a novel transition metal compound having excellent structural stability together with polymerization reactivity, and thereby is useful as a catalyst in preparing an olefin-based polymer, particularly, a low density olefin-based polymer, and a catalyst composition including the same.

The present disclosure relates to a supported hybrid metallocene catalyst and a method for preparing a polyolefin using the same. When the supported hybrid metallocene catalyst according to the present disclosure is used, a polyolefin with a multimodal molecular weight distribution and excellent environmental stress crack resistance can be prepared.