The present disclosure relates to an ethylene/alpha-olefin copolymer having excellent processibility. The ethylene/alpha-olefin copolymer according to the present disclosure is excellent in both mechanical properties and processibility.

Disclosed herein is a catalyst compound represented by Formula (I) or Formula (II): ##STR00001##
M is a group 4 metal. Each of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, and R.sup.9 is independently hydrogen, or a C1-C50 substituted or unsubstituted hydrocarbyl, halocarbyl, silylcarbyl, alkoxyl, siloxyl, or one or more of R.sup.1 and R.sup.2, R.sup.2 and R.sup.3, R.sup.3 and R.sup.4, R.sup.5 and R.sup.6, R.sup.6 and R.sup.7, and R.sup.7 and R.sup.8 are joined to form cyclic a saturated or unsaturated ring. Each X is independently a halide or C1-C50 substituted or unsubstituted hydrocarbyl, hydride, amide, alkoxide, sulfide, phosphide, halide, or a combination thereof, or two Xs are joined together to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene. Also disclosed is a method for using the catalyst compound in a catalyst system to produce polyolefin polymers.

This invention relates to a supported catalyst system and process for use thereof. In particular, the catalyst system includes bridged hafnium metallocene compound, an unbridged metallocene compound, a support material and an activator. The catalyst system may be used for preparing polyolefins.

A polyethylene composition comprising from about 0.5 to about 20 wt % of alpha-olefin derived units other than ethylene-derived units, with the balance including ethylene-derived units, total internal unsaturations (Vy1+Vy2+T1) of from about 0.10 to about 0.40 per 1000 carbon atoms, an MI of from about 0.1 to about 6 g/10 min, an HLMI of from about 5.0 to about 40 g/10 min, a density of from about 0.890 to about 0.940 g/ml, a Tw.sub.1-Tw.sub.2 value of from about 25 to about 20 C., an Mw.sub.1/Mw.sub.2 value of from about 1.2 to about 2.0, an Mw/Mn of from about 4.5 to about 12, an Mz/Mw of from about 2.0 to about 3.0, an Mz/Mn of from about 7.0 to about 20, and a g.sub.(vis) greater than 0.90.

The present invention provides an olefin polymer in which LCB (long chain branch) is introduced into mLLDPE (metallocene linear low-density polyethylene) to control the storage modulus, whereby the olefin polymer has excellent bubble stability and processing load characteristics and exhibits excellent processability during preparation of a film, and further has excellent mechanical properties and transparency.

Methods for the production of heterophasic polymers in gas and slurry phase polymerization processes, and polymer compositions made therefrom, are disclosed herein.

This invention relates to metallocene compounds having a group substituted at the 3 position of at least one cyclopentadienyl ring represented by the formula CH.sub.2SiR.sub.3 or CH.sub.2CR.sub.3 and R is a C.sub.1 to C.sub.20 substituted or unsubstituted hydrocarbyl.

Methods for determining the concentration of transition metal compounds in a solution containing more than one transition metal compound are described. Polymerization reactor systems providing real-time monitoring and control of the concentrations of the transition metal components of a multicomponent catalyst system are disclosed, as well as methods for operating such polymerization reactor systems and for improving methods of preparing the multicomponent catalyst system.

The present invention provides polyolefin resin composition exhibiting excellent long term durability as well as improved properties, and an article prepared using the same.

The present invention relates to a catalyst composition for synthesizing an olefin copolymer, including a first metallocene catalyst, a second metallocene catalyst, and a third metallocene catalyst, each having a specific structure, and a method for preparing an olefin copolymer using the catalyst composition for synthesizing an olefin copolymer.