Modification of functional groups along a polymer backbone to render the groups activatable upon exposure to actinic radiation is described. The polymers are typically controlled architecture polymers. Also described are adhesives containing the modified architectured polymers and related methods of use.

The present invention provides a preparing method of a polymer which is low-toxic, environmental-friendly, highly controllable, and low cost to obtain a polymer with high molecular weight. The preparing method comprises conducting a controlled radical polymerization process of monomer (Y). In the controlled radical polymerization process, organic compound (A) which has the formula (I) and radical initiator (B) are existing in a mole ratio (B/A) ranged from 0.5 to 25,

##STR00001## wherein R.sup.1 is a hydrogen atom, alkyl group, aryl group, or hydroxyl group, the alkyl group can be alkyl having substituents or alkyl substituent, and the aryl group can be aryl having substituents or aryl substituent.

A pressure-sensitive adhesive composition includes a block copolymer containing a polymer block (A) and a (meth)acrylic polymer block (B), wherein the polymer block (A) contains either or both of a maleimide compound and an amide group-containing vinyl compound as a constitutional monomer thereof and has a glass transition temperature of 100° C. or higher, and the (meth)acrylic polymer block (B) contains at least one selected from compounds represented by general formula (1) as a major constitutional monomer thereof and has a glass transition temperature of 10° C. or below.
CH.sub.2═CR.sup.1—C(═O)O(R.sup.2O).sub.n—R.sup.3  (1)
(wherein, R.sup.1 represents hydrogen or a methyl group; R.sup.2 represents a linear or branched C.sub.2-6 alkylene group; R.sup.3 represents hydrogen, a C.sub.1-20 alkyl group, or a C.sub.6-20 aryl group; and n represents 0 or an integer from 1 to 100.)

The invention relates to a novel type of sacrificial polymer or support material for 3D printing, comprising a block copolymer consisting of: at least one partially or totally hydrophilic elastomeric block, with a Tg of less than 30° C. and comprising at least one hydrophilic monomer, and at least one water-soluble thermoplastic block with a Tg of greater than 30° C. and comprising at least one monomer bearing a carboxyl group, said copolymer being extrudable and granulable, said copolymer being partially or totally soluble in water or in aqueous medium, and the mass proportion of the thermoplastic block being greater than 50% of the weight of said copolymer.

The invention relates to the field of block copolymers, particularly to the field of water-soluble or water-dispersible copolymers consisting of two blocks, of which the major block is a hydrophilic thermoplastic block. More particularly, the invention relates to a block copolymer consisting of a partially or totally hydrophilic elastomeric block, with a Tg of less than 30° C. and comprising at least one hydrophilic monomer, and a water-soluble thermoplastic block with a Tg of greater than 30° C. and comprising at least one monomer bearing a carboxyl group, said copolymer being partially or totally soluble in water or in aqueous medium, and the mass proportion of the thermoplastic block being greater than 50% of the weight of said copolymer.

Provided is a triblock copolymer represented by General Formula (I):
CNR-PEG-CNR  (1)
or a polycation thereof, wherein each CNR is independently a polymer segment having a repeating unit containing as part of a pendant group a cyclic nitroxide radical that binds to the polymer main chain via a linking group having at least one imino group or ether bond, and PEG is a segment containing poly(ethylene glycol).

Composite particles comprising at least one type of polymer particles having surfaces that have thereon coatings formed of finely-disintegrated cellulose, with the polymer particles and the finely-disintegrated cellulose being inseparably bonded together.

Low-temperature radical polymerisation of alkoxyamines

The present invention relates to a process for the radical polymerization of alkoxyamines at low temperature, typically at temperatures as low as −50° C., in the presence of a nitroxide reducing agent.

The presently claimed invention relates to an amine-modified polymer and method for preparation thereof. The presently claimed invention is also directed to the use of the polymer as dispersant in ink and coating compositions. Polyacrylate polymer is obtained by controlled free radical polymerization of a mixture comprising at least one acrylate monomer. The post-modification of polyacrylate polymers yields amine-modified polymers that provide improved viscosity parameters, without sacrificing the advantages of a well-defined polymer structure.

Process for the preparation of a diene polymer or a random vinyl arene-diene copolymer comprising anionically (co)polymerising at least one conjugated diene monomer, optionally in the presence of at least one vinyl arene, in the presence of at least one hydrocarbon solvent, at least one lithium-based initiator and at least one organic compound containing at least one nitroxide group having general formula (I) or (II): wherein: R.sup.1, R.sup.2, R.sup.3 and R.sup.4, mutually identical or different, represent a hydrogen atom; or are selected from C.sub.1-C.sub.20, preferably C.sub.1-C.sub.8, linear or branched alkyl groups optionally containing heteroatoms such as, for example, oxygen, nitrogen,sulphur,optionally substituted cycloalkyl groups, optionally substituted C.sub.1-C.sub.20, preferably C.sub.1-C.sub.8, linear or branched alkoxy groups, optionally substituted aryl groups; −x is an integer ranging from 0 to 7, preferably ranging from 4 to 5; −y is an integer ranging from 1 to 3, preferably ranging from 1 to 2.

##STR00001##