Catalyst system for producing ethylene copolymers in a high temperature solution process, the catalyst system comprising

(i) a metallocene complex of formula (I)

##STR00001## M is Hf or a mixture with Zr, provided that more than 50% by moles of the complex of Formula I has M=Hf X is a sigma ligand R are the same or different from each other and can be saturated linear or branched C.sub.1-C.sub.10 alkyl, C.sub.5-C.sub.10 aryl, C.sub.6-C.sub.20 alkylaryl or C.sub.6-C.sub.20 arylalkyl groups, which can optionally contain up to 2 heteroatoms or silicon atoms R.sup.1 is a C.sub.6-C.sub.20-aryl, which can be unsubstituted or substituted by one or up to 5 linear or branched C.sub.1-C.sub.10 alkyl group(s) R.sup.2 is a saturated linear or cyclic C.sub.3-C.sub.20 alkyl group or a branched CR.sup.3R.sup.4R.sup.5 group, wherein R.sup.3 is hydrogen or an C.sub.1-C.sub.20 alkyl group and R.sup.4 and R.sup.5 are the same or are different and can be an C.sub.1-C.sub.20 alkyl group and (ii) a boron containing cocatalyst.

The present invention relates to an olefin-based polymer satisfying conditions as follow: (1) a melt index (MI, 190° C., 2.16 kg load conditions) is from 0.1 g/10 min to 10.0 g/10 min, (2) a density (d) is from 0.860 g/cc to 0.880 g/cc, and (3) T(90)−T(50)≤50 and T(95)−T(90)≥10 are satisfied when measured by a differential scanning calorimetry precise measurement method (SSA). The olefin-based polymer according to the present invention is a low-density olefin-based polymer introducing a highly crystalline region and showing high mechanical rigidity.

The present invention relates to an olefin-based polymer satisfying conditions as follow: (1) a melt index (MI, 190° C., 2.16 kg load conditions) is from 0.1 g/10 min to 10.0 g/10 min, (2) a density (d) is from 0.860 g/cc to 0.880 g/cc, and (3) T(90)−T(50)≤50 and T(95)−T(90)≥10 are satisfied when measured by a differential scanning calorimetry precise measurement method (SSA). The olefin-based polymer according to the present invention is a low-density olefin-based polymer introducing a highly crystalline region and showing high mechanical rigidity.

The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 80 mol %. The present invention further relates to novel isobutene polymers.

The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 80 mol %. The present invention further relates to novel isobutene polymers.

An olefin-based copolymer and a method of making the same are disclosed herein. In some embodiments, an olefin-based copolymer has a density (d) of 0.85 to 0.89 g/cc, a melt index (MI), measured at 190° C. and 2.16 kg load, of 15 g/10 min to 100 g/10 min, a number of unsaturated functional groups (total V) per 1,000 carbon atoms of 0.8 or less, a vinylene content, and a vinyl content, wherein the vinylene content, the vinyl content and the total V satisfy (a) vinylene content/total V=0.1 to 0.7 and (b) vinylene content/vinyl content=0.8 to 1.6. The olefin-based copolymer has controlled content and kind of an unsaturated functional group in the olefin-based copolymer and thus, has high flowability, and may show improved physical properties of hardness, flexural strength and tensile strength.

An olefin-based copolymer and a method of making the same are disclosed herein. In some embodiments, an olefin-based copolymer has a density (d) of 0.85 to 0.89 g/cc, a melt index (MI), measured at 190° C. and 2.16 kg load, of 15 g/10 min to 100 g/10 min, a number of unsaturated functional groups (total V) per 1,000 carbon atoms of 0.8 or less, a vinylene content, and a vinyl content, wherein the vinylene content, the vinyl content and the total V satisfy (a) vinylene content/total V=0.1 to 0.7 and (b) vinylene content/vinyl content=0.8 to 1.6. The olefin-based copolymer has controlled content and kind of an unsaturated functional group in the olefin-based copolymer and thus, has high flowability, and may show improved physical properties of hardness, flexural strength and tensile strength.

Polyethylene compositions described herein have a density from about 0.900 g/cm.sup.3 to about 0.950 g/cm.sup.3, a MI (I.sub.2, 190° C., 2.16 kg) from about 0.1 g/10 min to about 10 g/10 min, an MIR (I.sub.21/I.sub.2) from about 25 to about 80, an M.sub.z greater than or equal to about 150,000 g/mol, and either an M.sub.z/M.sub.n ratio greater than or equal to about 8.0, an M.sub.z/M.sub.w ratio greater than or equal to about 2.4, or an (I.sub.2*M.sub.z/M.sub.n) from about 3 to about 100. The polyethylene compositions are useful in wire and cable, tape, and filament applications, and could be produced using a gas phase or slurry phase, preferably gas phase, polymerization process.

Polyethylene compositions described herein have a density from about 0.900 g/cm.sup.3 to about 0.950 g/cm.sup.3, a MI (I.sub.2, 190° C., 2.16 kg) from about 0.1 g/10 min to about 10 g/10 min, an MIR (I.sub.21/I.sub.2) from about 25 to about 80, an M.sub.z greater than or equal to about 150,000 g/mol, and either an M.sub.z/M.sub.n ratio greater than or equal to about 8.0, an M.sub.z/M.sub.w ratio greater than or equal to about 2.4, or an (I.sub.2*M.sub.z/M.sub.n) from about 3 to about 100. The polyethylene compositions are useful in wire and cable, tape, and filament applications, and could be produced using a gas phase or slurry phase, preferably gas phase, polymerization process.

Catalyst systems and methods for making and using the same. A method of methylating a catalyst composition while substantially normalizing the entiomeric distribution is provided. The method includes slurrying the organometallic compound in dimethoxyethane (DME), and adding a solution of RMgBr in DME, wherein R is a methyl group or a benzyl group, and wherein the RMgBr is greater than about 2.3 equivalents relative to the organometallic compound. After the addition of the RMgBr, the slurry is mixed for at least about four hours. An alkylated organometallic is isolated, wherein the methylated species has a meso/rac ratio that is between about 0.9 and about 1.2.