Embodiments are directed towards a use of a supported gas-phase biphenylphenol polymerization catalyst to make a polymer via a gas-phase polymerization process, wherein the supported gas-phase biphenylphenol polymerization catalyst is made from a gas-phase biphenylphenol polymerization precatalyst of Formula I.

Provided are a pellet-type polyethylene resin composition capable of improving pipe pressure resistance property, dimensional stability, and processability at the same time, and a method of preparing the same.

Provided are a pellet-type polyethylene resin composition capable of improving pipe pressure resistance property, dimensional stability, and processability at the same time, and a method of preparing the same.

The invention relates to a pipe comprising a polypropylene composition (P) comprising a terpolymer composition (A), a nucleating agent (B) and optionally a composition comprising pigment (C), wherein the terpolymer composition (A) comprises at least one terpolymer prepared from propylene, ethylene and 1-hexene, wherein the nucleating agent (B) is a nucleating agent comprising a metal salt of hexahydrophthalic acid represented by formula (I) (I) wherein M1 and M2 are the same or different, and may be combined into one cation, and are selected from at least one metal cation of calcium, strontium, lithium, and monobasic aluminum; and wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, and R.sub.10 are either the same or different and are individually selected from the group consisting of hydrogen, C.sub.1-C.sub.9 alkyl, hydroxy, C1-C9alkoxy, C.sub.1-C.sub.9 alkyleneoxy, amine, and C.sub.1-C.sub.9 alkylamine, halogens, and phenyl wherein the polypropylene composition (P) has a melt flow rate in the range from 0.10 to 0.70 dg/min as determined by ISO1133-1:2011 at 230° C. and 2.16 kg.

##STR00001##

The invention relates to a pipe comprising a polypropylene composition (P) comprising a terpolymer composition (A), a nucleating agent (B) and optionally a composition comprising pigment (C), wherein the terpolymer composition (A) comprises at least one terpolymer prepared from propylene, ethylene and 1-hexene, wherein the nucleating agent (B) is a nucleating agent comprising a metal salt of hexahydrophthalic acid represented by formula (I) (I) wherein M1 and M2 are the same or different, and may be combined into one cation, and are selected from at least one metal cation of calcium, strontium, lithium, and monobasic aluminum; and wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, and R.sub.10 are either the same or different and are individually selected from the group consisting of hydrogen, C.sub.1-C.sub.9 alkyl, hydroxy, C1-C9alkoxy, C.sub.1-C.sub.9 alkyleneoxy, amine, and C.sub.1-C.sub.9 alkylamine, halogens, and phenyl wherein the polypropylene composition (P) has a melt flow rate in the range from 0.10 to 0.70 dg/min as determined by ISO1133-1:2011 at 230° C. and 2.16 kg.

##STR00001##

An object of the present invention is to provide a film for a capacitor such that the film excels in high-temperature dielectric breakdown voltage (high-temperature BDV) and has blocking resistance, and bleeding-out of, for instance, a nucleating agent is suppressed even after long-term storage. The present invention pertains to a multilayer polypropylene film for a capacitor, the film including a base layer composed of a propylene polymer composition containing a propylene homopolymer (X) and 0.0001 to 0.05 mass % of a polymer-based α-crystal nucleating agent (C), and a front layer or a back layer composed of a propylene-based polymer (Y) on at least one surface of the base layer, wherein the base layer and the front layer or back layer are stretched.

An object of the present invention is to provide a film for a capacitor such that the film excels in high-temperature dielectric breakdown voltage (high-temperature BDV) and has blocking resistance, and bleeding-out of, for instance, a nucleating agent is suppressed even after long-term storage. The present invention pertains to a multilayer polypropylene film for a capacitor, the film including a base layer composed of a propylene polymer composition containing a propylene homopolymer (X) and 0.0001 to 0.05 mass % of a polymer-based α-crystal nucleating agent (C), and a front layer or a back layer composed of a propylene-based polymer (Y) on at least one surface of the base layer, wherein the base layer and the front layer or back layer are stretched.

A polyethylene-based composition may include an ethylene-based copolymer produced from ethylene and one or more C3-C10 alpha olefin comonomers, wherein the ethylene-based copolymer has: a density ranging from 945 kg/m.sup.3 to 961 kg/m.sup.3 according to ASTM D792, a melt flow rate (MFR.sub.2) ranging from 0.5 g/10 min to 3.0 g/10 min according to ASTM D1238 at 190° C./2.16 kg, a molecular weight distribution (Mw/Mn) ranging from 3 to 25, and a stress exponent (SEx) ranging from 1.0 to 1.8.

A polyethylene-based composition may include an ethylene-based copolymer produced from ethylene and one or more C3-C10 alpha olefin comonomers, wherein the ethylene-based copolymer has: a density ranging from 945 kg/m.sup.3 to 961 kg/m.sup.3 according to ASTM D792, a melt flow rate (MFR.sub.2) ranging from 0.5 g/10 min to 3.0 g/10 min according to ASTM D1238 at 190° C./2.16 kg, a molecular weight distribution (Mw/Mn) ranging from 3 to 25, and a stress exponent (SEx) ranging from 1.0 to 1.8.

The present disclosure relates to a catalyst composition and a process for preparation thereof. The catalyst composition of the present disclosure is stable, and produces polyolefin having narrow molecular weight distribution during the polymerization. The process of the present disclosure is simple, cost-effective, and rapid.