Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (Ia):

##STR00001##

Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (Ia):

##STR00001##

Provided in this disclosure is an ethylene interpolymer composition. The ethylene interpolymer composition includes a first ethylene interpolymer, a second ethylene interpolymer, and a third ethylene interpolymer. Further, the ethylene interpolymer composition has a density of at least 0.945 g/cm3; an environmental stress crack resistance (ESCR), measured according to ASTM D1693, Condition B, 10% IGEPAL CO-360, of at least 90 hours; and an Izod impact strength of at least 80 J/m, as measured according to ASTM D256.

Provided in this disclosure is an ethylene interpolymer composition. The ethylene interpolymer composition includes a first ethylene interpolymer, a second ethylene interpolymer, and a third ethylene interpolymer. Further, the ethylene interpolymer composition has a density of at least 0.945 g/cm3; an environmental stress crack resistance (ESCR), measured according to ASTM D1693, Condition B, 10% IGEPAL CO-360, of at least 90 hours; and an Izod impact strength of at least 80 J/m, as measured according to ASTM D256.

This disclosure relates to ethylene interpolymer products comprising a Melt Flow-Intrinsic Viscosity Index value, MFIVI, of from ≥0.05 to ≤0.80; a first derivative of a melt flow distribution function, formula (I) of form ≥−1.85 to ≤−1.51; an unsaturation ratio, UR, of from >0.06 to ≤0.60; and a residual catalytic metal of from ≥0.03 to ≤5 ppm of hafnium. Ethylene interpolymer products comprise at least two ethylene interpolymers. Ethylene interpolymer products are characterized by a melt index (I.sub.2) from 0.3 to 500 dg/minute, a density from 0.855 to 0.975 g/cc and from 0 to 25 mole percent of one or more a-olefins. Ethylene interpolymer products have polydispersity, M.sub.w/M.sub.n, from 1.7 to 25; and CDBI.sub.50 values from 1% to 98%. These ethylene interpolymer products have utility in flexible and rigid applications.

[00001]$\begin{array}{cc}\frac{d\mathrm{Log}\left(1/I_n\right)}{d\mathrm{Log}\left(\mathrm{loading}\right)}& \left(I\right)\end{array}$

This disclosure relates to ethylene interpolymer products comprising a Melt Flow-Intrinsic Viscosity Index value, MFIVI, of from ≥0.05 to ≤0.80; a first derivative of a melt flow distribution function, formula (I) of form ≥−1.85 to ≤−1.51; an unsaturation ratio, UR, of from >0.06 to ≤0.60; and a residual catalytic metal of from ≥0.03 to ≤5 ppm of hafnium. Ethylene interpolymer products comprise at least two ethylene interpolymers. Ethylene interpolymer products are characterized by a melt index (I.sub.2) from 0.3 to 500 dg/minute, a density from 0.855 to 0.975 g/cc and from 0 to 25 mole percent of one or more a-olefins. Ethylene interpolymer products have polydispersity, M.sub.w/M.sub.n, from 1.7 to 25; and CDBI.sub.50 values from 1% to 98%. These ethylene interpolymer products have utility in flexible and rigid applications.

[00001]$\begin{array}{cc}\frac{d\mathrm{Log}\left(1/I_n\right)}{d\mathrm{Log}\left(\mathrm{loading}\right)}& \left(I\right)\end{array}$

Ziegler-Natta (pro)catalyst systems made with an external electron donor compound, methods of synthesis of same, methods of olefin polymerization using same, and polyolefin polymers made thereby. The external electron donor compound is an azaheterocycle.

Ziegler-Natta (pro)catalyst systems made with an external electron donor compound, methods of synthesis of same, methods of olefin polymerization using same, and polyolefin polymers made thereby. The external electron donor compound is an azaheterocycle.

Ziegler-Natta (pro)catalyst systems made with an external electron donor compound, methods of synthesis of same, methods of olefin polymerization using same, and polyolefin polymers made thereby. The external electron donor compound is a (multi-alkoxy)silane.

Ziegler-Natta (pro)catalyst systems made with an external electron donor compound, methods of synthesis of same, methods of olefin polymerization using same, and polyolefin polymers made thereby. The external electron donor compound is a (multi-alkoxy)silane.