C08F2500/07

MULTIMODAL POLYOLEFIN RESIN HAVING HIGH MELT STRENGTH AND MOLDED PRODUCT PREPARED WITH THE SAME

Multimodal polyolefin resin having superior characteristics including moldability, mechanical strength, external appearance, melt strength and a polyolefin resin molded product meeting the requirements: (1) polymerized in the presence of at least two different metallocene compounds as catalysts; (2) matrix index of 2 or less and a melt strength of 4.0 Force (cN) or greater at 190° C.; (3) melt flow index (MIP, 190° C., 5.0 kg load condition) of 0.01 to 5.0 g/10 min; (4) ratio (Mw/Mn, MWD) of weight average molecular weight (Mw) to number average molecular weight (Mn) of 5-35 as measured by gel permeation chromatography; and (5) bimodal or multimodal peaks in a weight average molecular weight distribution measured by gel permeation chromatography, wherein the height ratio of two peaks (the ratio of the height of low molecular weight peak to the height of high molecular weight peak) is 0.7-3.

MULTIMODAL POLYOLEFIN RESIN HAVING HIGH MELT STRENGTH AND MOLDED PRODUCT PREPARED WITH THE SAME

Multimodal polyolefin resin having superior characteristics including moldability, mechanical strength, external appearance, melt strength and a polyolefin resin molded product meeting the requirements: (1) polymerized in the presence of at least two different metallocene compounds as catalysts; (2) matrix index of 2 or less and a melt strength of 4.0 Force (cN) or greater at 190° C.; (3) melt flow index (MIP, 190° C., 5.0 kg load condition) of 0.01 to 5.0 g/10 min; (4) ratio (Mw/Mn, MWD) of weight average molecular weight (Mw) to number average molecular weight (Mn) of 5-35 as measured by gel permeation chromatography; and (5) bimodal or multimodal peaks in a weight average molecular weight distribution measured by gel permeation chromatography, wherein the height ratio of two peaks (the ratio of the height of low molecular weight peak to the height of high molecular weight peak) is 0.7-3.

Polyethylene with controlled wax content, chlorinated polyethylene thereof and molded article produced from the chlorinated polyethylene
09796797 · 2017-10-24 · ·

Disclosed are polyethylene, chlorinated polyethylene thereof and a molded article produced from the chlorinated polyethylene. More specifically, disclosed are polyethylene for preparation of chlorinated polyethylene, the polyethylene having a molecular weight distribution (MWD) of 5 or less, a melting index (5.0 kg) of 0.1 to 10 dg/min, a weight average molecular weight of 50,000 to 300,000 g/mol, a melting temperature of 125 to 135° C., a wax content of 0.0001 to 3% by weight or 0.01 to 0.3% by weight and a density of 0.94 g/cm.sup.3 or more, chlorinated polyethylene thereof and a molded article produced from the chlorinated polyethylene.

Polyethylene with controlled wax content, chlorinated polyethylene thereof and molded article produced from the chlorinated polyethylene
09796797 · 2017-10-24 · ·

Disclosed are polyethylene, chlorinated polyethylene thereof and a molded article produced from the chlorinated polyethylene. More specifically, disclosed are polyethylene for preparation of chlorinated polyethylene, the polyethylene having a molecular weight distribution (MWD) of 5 or less, a melting index (5.0 kg) of 0.1 to 10 dg/min, a weight average molecular weight of 50,000 to 300,000 g/mol, a melting temperature of 125 to 135° C., a wax content of 0.0001 to 3% by weight or 0.01 to 0.3% by weight and a density of 0.94 g/cm.sup.3 or more, chlorinated polyethylene thereof and a molded article produced from the chlorinated polyethylene.

POLYOLEFIN PELLET FOR PREPARING FIBER AND FIBER COMPRISING THE SAME

The present invention relates to a polyolefin pellet for preparing a fiber, and a fiber comprising the same. According to the present invention, provided is a polyolefin, which exhibits a high molecular weight range and a narrow molecular weight distribution and in which the formation of a gel deteriorating the quality of a fiber is reduced. Therefore, by using the polyolefin pellet, the present invention exhibits a molecular weight, a density and a narrow molecular weight distribution, which are equivalent to those of conventional polyolefin, but has high tenacity and an excellent drawing characteristic and can be highly oriented because gel formation is reduced, and therefore, the present invention can be applied to various industrial products due to a high draw ratio and crystallinity during a multifilament operation using the same.

POLYOLEFIN PELLET FOR PREPARING FIBER AND FIBER COMPRISING THE SAME

The present invention relates to a polyolefin pellet for preparing a fiber, and a fiber comprising the same. According to the present invention, provided is a polyolefin, which exhibits a high molecular weight range and a narrow molecular weight distribution and in which the formation of a gel deteriorating the quality of a fiber is reduced. Therefore, by using the polyolefin pellet, the present invention exhibits a molecular weight, a density and a narrow molecular weight distribution, which are equivalent to those of conventional polyolefin, but has high tenacity and an excellent drawing characteristic and can be highly oriented because gel formation is reduced, and therefore, the present invention can be applied to various industrial products due to a high draw ratio and crystallinity during a multifilament operation using the same.

Injection stretch blow moulded articles

This invention covers injection stretch blow molded articles prepared from polyethylene resin having a bimodal molecular weight distribution (MWD), defined by the ratio of the weight average molecular weight (Mw) to the number average molecular weight (Mn), of from 2 to 20, comprising two polyethylene fractions A and B, fraction A being substantially free of comonomer and having a lower weight average molecular weight and a higher density than fraction B, each fraction prepared in different reactors of two reactors connected in series in the presence of a metallocene-containing catalyst system.

Injection stretch blow moulded articles

This invention covers injection stretch blow molded articles prepared from polyethylene resin having a bimodal molecular weight distribution (MWD), defined by the ratio of the weight average molecular weight (Mw) to the number average molecular weight (Mn), of from 2 to 20, comprising two polyethylene fractions A and B, fraction A being substantially free of comonomer and having a lower weight average molecular weight and a higher density than fraction B, each fraction prepared in different reactors of two reactors connected in series in the presence of a metallocene-containing catalyst system.

Polyethylene composition suitable for injection moulding applications

The present invention relates to a polyethylene composition comprising—a base resin comprising (A) a first ethylene homo- or copolymer component having a melt flow rate MFR2 (2.16 kg, 190° C.) of equal to or more than 150 g/10 min to equal to or less than 300 g/10 min, determined according to ISO 1133, and (B) a second ethylene homo- or copolymer component, —optional carbon black, —optional further polymer component(s) different to the first ethylene homo- or copolymer components (A) and (B), and —optional additive(s); wherein the first ethylene homo- or copolymer component (A) has a lower weight average molecular weight as the second ethylene homo- or copolymer component (B), and the weight ratio of the first ethylene homo- or copolymer component (A) to the second ethylene homo- or copolymer component (B) is from 40:60 to 47:53; the polyethylene composition has a melt flow rate MFR5 (5 kg, 190° C.) of equal to or more than 0.35 g/10 min to equal to or less than 0.60 g/10 min, determined according to ISO 1133. The invention further relates to a process for the production of such a polyethylene composition, an article, such as a pipe or pipe fitting comprising such a polyethylene composition and the use of such a polyethylene composition for the production of such an article.

Polyethylene composition suitable for injection moulding applications

The present invention relates to a polyethylene composition comprising—a base resin comprising (A) a first ethylene homo- or copolymer component having a melt flow rate MFR2 (2.16 kg, 190° C.) of equal to or more than 150 g/10 min to equal to or less than 300 g/10 min, determined according to ISO 1133, and (B) a second ethylene homo- or copolymer component, —optional carbon black, —optional further polymer component(s) different to the first ethylene homo- or copolymer components (A) and (B), and —optional additive(s); wherein the first ethylene homo- or copolymer component (A) has a lower weight average molecular weight as the second ethylene homo- or copolymer component (B), and the weight ratio of the first ethylene homo- or copolymer component (A) to the second ethylene homo- or copolymer component (B) is from 40:60 to 47:53; the polyethylene composition has a melt flow rate MFR5 (5 kg, 190° C.) of equal to or more than 0.35 g/10 min to equal to or less than 0.60 g/10 min, determined according to ISO 1133. The invention further relates to a process for the production of such a polyethylene composition, an article, such as a pipe or pipe fitting comprising such a polyethylene composition and the use of such a polyethylene composition for the production of such an article.