The present invention relates to an olefin-based polymer satisfying requirements: (1) a melt index (MI, 190° C., 2.16 kg load conditions) ranging from 1.0 to 10.0 g/10 min; (2) a density (d) ranging from 0.875 to 0.895 g/cc; (3) 0.5 J/g≤dH(100)≤3.0 J/g and 1.0 J/g≤dH(90)≤6.0 J/g as measured by successive self-nucleation/annealing (SSA) using a differential scanning calorimeter (DSC); (4) 15≤T(90)−T(50)≤30 and 50° C.≤T(50)≤75° C. as measured by SSA using a DSC; and (5) a melting point (Tm) of 55° C.≤Tm≤80° C. as measured using a DSC. The olefin-based polymer according to the present invention is a low-density olefin-based polymer and has a highly crystalline region introduced therein, thereby exhibiting high mechanical stiffness.

A process for the continuous solution polymerization including the step of polymerizing a first olefin monomer of formula CH.sub.2═CHR.sup.1, wherein R.sup.1 is hydrogen or a hydrocarbon radical having from 1 to 8 carbon atoms with a second olefin monomer of formula CH.sub.2═CHR.sup.2, wherein R.sup.2 is a hydrocarbon radical having from 3 to 8 carbon atoms, in the presence of a polymerization catalyst and in the absence of an inert solvent, at a polymerization temperature (Tp) satisfying the following relationship:

Tp≥Tm+20° C.

wherein Tm is the melting temperature of the obtained polymer.

A process for the continuous solution polymerization including the step of polymerizing a first olefin monomer of formula CH.sub.2═CHR.sup.1, wherein R.sup.1 is hydrogen or a hydrocarbon radical having from 1 to 8 carbon atoms with a second olefin monomer of formula CH.sub.2═CHR.sup.2, wherein R.sup.2 is a hydrocarbon radical having from 3 to 8 carbon atoms, in the presence of a polymerization catalyst and in the absence of an inert solvent, at a polymerization temperature (Tp) satisfying the following relationship:

Tp≥Tm+20° C.

wherein Tm is the melting temperature of the obtained polymer.

The present invention relates to heterophasic polypropylene compositions comprising a propylene homo- or copolymer forming a crystalline fraction as a matrix and an amorphous propylene ethylene elastomer as a soluble fraction dispersed in said matrix. The heterophasic polypropylene compositions further comprise an elastomeric ethylene/alpha-olefin random copolymer. The heterophasic polypropylene compositions have a well-balanced relation between stiffness and impact strength, low volatile and semi-volatile emissions and good processability.

The present invention relates to heterophasic polypropylene compositions comprising a propylene homo- or copolymer forming a crystalline fraction as a matrix and an amorphous propylene ethylene elastomer as a soluble fraction dispersed in said matrix. The heterophasic polypropylene compositions further comprise an elastomeric ethylene/alpha-olefin random copolymer. The heterophasic polypropylene compositions have a well-balanced relation between stiffness and impact strength, low volatile and semi-volatile emissions and good processability.

A composition comprising an ethylene/alpha-olefin interpolymer that comprises the following properties: a) a total unsaturation/1000C≥0.30; b) a molecular weight distribution (MWD)≤3.0; c) a TGIC broadness parameter B.sub.1/4≤8.0. A solution N polymerization process to prepare an ethylene/alpha-olefin/interpolymer, said process comprising polymerizing, in one reactor, at a reactor temperature ≥150° C., a reaction mixture comprising ethylene, an alpha-olefin, a solvent, and a metal complex as described herein. A method to determine the TGIC broadness parameter B.sub.1/x of a polymer composition comprising one or more olefin-based polymers.

A composition comprising an ethylene/alpha-olefin interpolymer that comprises the following properties: a) a total unsaturation/1000C≥0.30; b) a molecular weight distribution (MWD)≤3.0; c) a TGIC broadness parameter B.sub.1/4≤8.0. A solution N polymerization process to prepare an ethylene/alpha-olefin/interpolymer, said process comprising polymerizing, in one reactor, at a reactor temperature ≥150° C., a reaction mixture comprising ethylene, an alpha-olefin, a solvent, and a metal complex as described herein. A method to determine the TGIC broadness parameter B.sub.1/x of a polymer composition comprising one or more olefin-based polymers.

A process to prepare an alpha composition comprising a first ethylene/alpha-olefin/interpolymer fraction and a second ethylene/alpha-olefin/interpolymer fraction; said process comprising polymerizing, in one reactor, a reaction mixture, comprising ethylene and an alpha-olefin, a biphenyl phenol metal complex selected from Structure 1, as described herein, and a biphenyl phenol metal complex selected from Structure 2, as described herein; and alpha compositions prepared therefrom.

A process to prepare an alpha composition comprising a first ethylene/alpha-olefin/interpolymer fraction and a second ethylene/alpha-olefin/interpolymer fraction; said process comprising polymerizing, in one reactor, a reaction mixture, comprising ethylene and an alpha-olefin, a biphenyl phenol metal complex selected from Structure 1, as described herein, and a biphenyl phenol metal complex selected from Structure 2, as described herein; and alpha compositions prepared therefrom.

The present invention relates to an olefin-based polymer, which has (1) a density (d) ranging from 0.850 to 0.865 g/cc, (2) a melt index (MI, 190° C., 2.16 kg load conditions) ranging from 0.1 g/10 min to 3.0 g/10 min, and (3) a soluble fraction (SF) of 10 wt % or more at −20° C. in cross-fractionation chromatography (CFC), in which a weight average molecular weight (Mw) of the soluble fraction is in a range of 50,000 g/mol to 500,000 g/mol. The olefin-based polymer according to the present invention exhibits improved anti-blocking properties as a low-density olefin-based polymer.