C08F2500/16

Method for producing styrene resin and styrene resin molded article

To provide a method for producing a styrene resin having a syndiotactic structure, including performing addition polymerization of one or more of a vinyl aromatic monomer in the presence of a catalyst containing a half metallocene transition metal compound (A) having at least one kind selected from metals of groups 3 to 5 of the periodic table and lanthanoid transition metals as a central metal, a compound (B) represented by the general formula (1), and a compound (C) selected from at least one kind of an oxygen-containing compound (c1) and a compound (c2) capable of forming an ionic complex through reaction with a transition metal compound, the styrene resin produced having a transition metal content derived from the half metallocene transition metal compound (A) of 1.5 to 12 ppm by mass.

Method for producing styrene resin and styrene resin molded article

To provide a method for producing a styrene resin having a syndiotactic structure, including performing addition polymerization of one or more of a vinyl aromatic monomer in the presence of a catalyst containing a half metallocene transition metal compound (A) having at least one kind selected from metals of groups 3 to 5 of the periodic table and lanthanoid transition metals as a central metal, a compound (B) represented by the general formula (1), and a compound (C) selected from at least one kind of an oxygen-containing compound (c1) and a compound (c2) capable of forming an ionic complex through reaction with a transition metal compound, the styrene resin produced having a transition metal content derived from the half metallocene transition metal compound (A) of 1.5 to 12 ppm by mass.

Door assembly
11821255 · 2023-11-21 · ·

A door assembly. The door assembly may include at least one door panel and a door frame having a plurality of frame members including a header and a pair of side jambs. The invention may also be considered a frame member. The frame member may include a core; and a two-piece top piece adjoining the core to form a structural member. The core and the top piece may be a composite of cellulosic material and at least one other material. The door assembly may further include at least one adjacent panel. Also disclosed are door jamb frame members and mullion frame members.

Metallocene catalyst systems with chemically-treated solid oxides for producing ethylene-based plastomers and elastomers

Polymerization processes for producing ethylene-based plastomers and elastomers having densities less than 0.91 g/cm.sup.3 utilize a metallocene-based catalyst system containing a chemically-treated solid oxide. These polymerization processes can be conducted in a slurry reactor, a solution reactor, and/or a gas phase reactor. Ethylene polymers produced from the polymerization process can be characterized by a density of less than 0.91 g/cm.sup.3, a CY-a parameter of less than 0.2, and a ratio of HLMI/MI of at least 30, or a density less than 0.91 g/cm.sup.3, a CY-a parameter from 0.25 to 0.75, and a ratio of Mw/Mn from 2 to 3.

Metallocene Catalyst Systems With Chemically-Treated Solid Oxides For Producing Ethylene-Based Plastomers And Elastomers
20220177619 · 2022-06-09 ·

Polymerization processes for producing ethylene-based plastomers and elastomers having densities less than 0.91 g/cm.sup.3 utilize a metallocene-based catalyst system containing a chemically-treated solid oxide. These polymerization processes can be conducted in a slurry reactor, a solution reactor, and/or a gas phase reactor. Ethylene polymers produced from the polymerization process can be characterized by a density of less than 0.91 g/cm.sup.3, a CY-a parameter of less than 0.2, and a ratio of HLMI/MI of at least 30, or a density less than 0.91 g/cm.sup.3, a CY-a parameter from 0.25 to 0.75, and a ratio of Mw/Mn from 2 to 3.

Bis(Metallocene) Compounds and Catalyst Compositions Employing Such Compounds

The present invention relates to new bis(metallocene) compounds, new catalyst compositions, process for preparing the new bis(metallocene) compounds and use of said new catalyst compositions to polymerise olefins. The bis(metallocene) compounds of the invention are homo- or hetero bis(metallocene) molecules in which same or different metallocene moieties are connected by a phenylene bridge. The phenylene bridge is either para-substituted, meta-substituted or ortho-substituted by the two metallocene moieties.

Bis(Metallocene) Compounds and Catalyst Compositions Employing Such Compounds

The present invention relates to new bis(metallocene) compounds, new catalyst compositions, process for preparing the new bis(metallocene) compounds and use of said new catalyst compositions to polymerise olefins. The bis(metallocene) compounds of the invention are homo- or hetero bis(metallocene) molecules in which same or different metallocene moieties are connected by a phenylene bridge. The phenylene bridge is either para-substituted, meta-substituted or ortho-substituted by the two metallocene moieties.

Process for Preparing Polypropylene

The present invention relates to a new process for preparing a polypropylene using new bis(metallocene) compounds in catalyst compositions. The bis(metallocene) compounds of the invention are homo- or hetero bis(metallocene) molecules in which same or different metallocene moieties are connected by a phenylene bridge. The phenylene bridge is either para-substituted, meta-substituted or ortho-substituted by the two metallocene moieties

Process for Preparing Polypropylene

The present invention relates to a new process for preparing a polypropylene using new bis(metallocene) compounds in catalyst compositions. The bis(metallocene) compounds of the invention are homo- or hetero bis(metallocene) molecules in which same or different metallocene moieties are connected by a phenylene bridge. The phenylene bridge is either para-substituted, meta-substituted or ortho-substituted by the two metallocene moieties

High Flow Fiber-Reinforced Propylene Composition Having Low Emissions

A fiber-reinforced polymer composition that contains a polymer matrix and a plurality of long reinforcing fibers that are distributed within the polymer matrix is provided. The polymer matrix contains a propylene polymer and constitutes from about 30 wt. % to about 90 wt. % of the composition. The fibers constitute from about 10 wt. % to about 70 wt. % of the composition. Further, the polymer composition exhibits a spiral flow length of about 450 millimeters or more as determined in accordance with ASTM D3123-09 and a volatile organic content of about 100 micrograms per gram or less as determined by VDA 277.