Patent classifications
C08F2500/16
Multimodal polyethylene composition and a film comprising the same
The present invention relates to a multimodal polyethylene composition comprising: (A) 40 to 65 parts by weight, preferably 43 to 52 parts by weight, most preferred 44 to 50 parts by weight, of the low molecular weight polyethylene, the low molecular weight polyethylene having a weight average molecular weight (Mw) of 20,000 to 90,000 g/mol and having a MFRa from 500 to 1.000 g/10 min according to ASTM D 1238; (B) 8 to 20 parts by weight, preferably 10 to 18 parts by weight, most preferred 10 to 15 parts by weight, of the first high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000 g/mol or the first ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000 g/mol; and (C) 30 to 50 parts by weight, preferably 37 to 47 parts by weight, most preferred 39 to 45 parts by weight, of the second high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000 g/mol or the second ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000 g/mol, wherein the density of the first high molecular weight polyethylene or the first ultra high molecular weight polyethylene and the second high molecular weight polyethylene or the second ultra high molecular weight polyethylene are in the range from 0.920 to 0.950 g/cm3, and wherein the molecular weight distribution of the multimodal polyethylene composition is from 20 to 28, preferably from 24 to 28, measured by gel permeation chromatography, and a film comprising the multimodal polyethylene composition and the use thereof.
Propylene impact copolymer blends with improved gloss
Described herein are polymer blends comprising (a) a propylene impact copolymer comprising a polypropylene component present in a continuous phase and a first elastomeric component present in a disperse phase; and (b) a second elastomeric component, and the interfacial tension between the second elastomeric component and the impact copolymer is at least 1.2 mN/m. The polymer blends of present invention provides improved gloss and impact properties.
Multiple non-coordinating anion activators for propylene-ethylene-diene monomer polymerization reactions
This invention relates to production of propylene-predominant copolymers using a transition metal complex and at least two different non-coordinating anion activators. An olefinic feed comprising a C.sub.3-C.sub.40 alpha olefin, ethylene, and a diene monomer is contacted under polymerization reaction conditions with a catalyst system comprising a first non-coordinating anion activator, a second non-coordinating borate activator differing from the first non-coordinating anion activator, and a transition metal complex comprising a tetrahydro-s-indacenyl or tetrahydro-as-indacenyl group bound to a group 3-6 transition metal. A molar ratio of the first non-coordinating anion activator to the second non-coordinating anion activator is sufficient to produce a melt flow rate under the polymerization reaction conditions for the resulting copolymer of about 30 g/10 min or below as determined by ASTM D-1238 (230 C., 2.16 kg).
Multiple non-coordinating anion activators for propylene-ethylene-diene monomer polymerization reactions
This invention relates to production of propylene-predominant copolymers using a transition metal complex and at least two different non-coordinating anion activators. An olefinic feed comprising a C.sub.3-C.sub.40 alpha olefin, ethylene, and a diene monomer is contacted under polymerization reaction conditions with a catalyst system comprising a first non-coordinating anion activator, a second non-coordinating borate activator differing from the first non-coordinating anion activator, and a transition metal complex comprising a tetrahydro-s-indacenyl or tetrahydro-as-indacenyl group bound to a group 3-6 transition metal. A molar ratio of the first non-coordinating anion activator to the second non-coordinating anion activator is sufficient to produce a melt flow rate under the polymerization reaction conditions for the resulting copolymer of about 30 g/10 min or below as determined by ASTM D-1238 (230 C., 2.16 kg).
Processes for producing high propylene content PEDM having low glass transition temperatures using tetrahydroindacenyl catalyst systems
The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene-diene terpolymer typically comprising from 30 to 55 mol % ethylene, from 69.09 to 45 mol % C.sub.3 to C.sub.40 comonomer, and from 0.01 to 7 mol % diene wherein the Tg of the terpolymer is 28 C. or less. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.
Processes for producing high propylene content PEDM having low glass transition temperatures using tetrahydroindacenyl catalyst systems
The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene-diene terpolymer typically comprising from 30 to 55 mol % ethylene, from 69.09 to 45 mol % C.sub.3 to C.sub.40 comonomer, and from 0.01 to 7 mol % diene wherein the Tg of the terpolymer is 28 C. or less. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.
METHOD FOR PRODUCING STYRENE RESIN AND STYRENE RESIN MOLDED ARTICLE
To provide a method for producing a styrene resin having a syndiotactic structure, including performing addition polymerization of one or more of a vinyl aromatic monomer in the presence of a catalyst containing a half metallocene transition metal compound (A) having at least one kind selected from metals of groups 3 to 5 of the periodic table and lanthanoid transition metals as a central metal, a compound (B) represented by the general formula (1), and a compound (C) selected from at least one kind of an oxygen-containing compound (c1) and a compound (c2) capable of forming an ionic complex through reaction with a transition metal compound, the styrene resin produced having a transition metal content derived from the half metallocene transition metal compound (A) of 1.5 to 12 ppm by mass.
METHOD FOR PRODUCING STYRENE RESIN AND STYRENE RESIN MOLDED ARTICLE
To provide a method for producing a styrene resin having a syndiotactic structure, including performing addition polymerization of one or more of a vinyl aromatic monomer in the presence of a catalyst containing a half metallocene transition metal compound (A) having at least one kind selected from metals of groups 3 to 5 of the periodic table and lanthanoid transition metals as a central metal, a compound (B) represented by the general formula (1), and a compound (C) selected from at least one kind of an oxygen-containing compound (c1) and a compound (c2) capable of forming an ionic complex through reaction with a transition metal compound, the styrene resin produced having a transition metal content derived from the half metallocene transition metal compound (A) of 1.5 to 12 ppm by mass.
DOOR ASSEMBLY
A door assembly. The door assembly may include at least one door panel and a door frame having a plurality of frame members including a header and a pair of side jambs. The invention may also be considered a frame member. The frame member may include a core; and a two-piece top piece adjoining the core to form a structural member. The core and the top piece may be a composite of cellulosic material and at least one other material. The door assembly may further include at least one adjacent panel. Also disclosed are door jamb frame members and mullion frame members.
MACHINE DIRECTION ORIENTED FILMS COMPRISING MULTIMODAL COPOLYMER OF ETHYLENE AND AT LEAST TWO ALPHA-OLEFIN COMONOMERS
A machine direction oriented film comprising a multimodal copolymer of ethylene and at least two alpha-olefin-comonomers having: a) a density of from 906 to 925 kg/m.sup.3 determined according to ISO 1183, b) an MFR.sub.21 of 10-200 g/10 min determined according to ISO1133, wherein the multimodal copolymer of ethylene comprises c) a first copolymer of ethylene and a first alpha-olefin comonomer having 4 to 10 carbon atoms; and d) a second copolymer of ethylene having an alpha-olefin comonomer different from the first copolymer, said second alpha-olefin comonomer having 6 to 10 carbon atoms.