C08F2500/16

MULTIMODAL POLYETHYLENE THIN FILM

The present invention relates to a reactor system for a multimodal polyethylene polymerization process, comprising; (a) a first reactor; (b) a hydrogen removal unit arranged between the first reactor and a second reactor comprising at least one vessel connected with a depressurization equipment, preferably selected from vacuum pump, compressor, blower, ejector or a combination, thereof, the depressurization equipment allowing to adjust an operating pressure to a pressure in a range of 100-200 kPa (abs); (c) the second reactor; and. (d) a third reactor and the use of a film thereof.

HIGH FLOW HETEROPHASIC POLYOLEFIN COMPOSITIONS HAVING IMPROVED STIFFNESS/IMPACT BALANCE

High flow nucleated heterophasic polyolefin compositions comprising a matrix comprising a propylene homo- and/or copolymer and an elastomeric alpha-olefin copolymer phase dispersed in the matrix, which have rather high melt flow rate, improved impact strength but also an excellent impact/stiffness balance and a process for the preparation of such a heterophasic polyolefin composition, articles made therefrom and uses of the heterophasic polyolefin composition.

HIGH FLOW HETEROPHASIC POLYOLEFIN COMPOSITIONS HAVING IMPROVED STIFFNESS/IMPACT BALANCE

High flow nucleated heterophasic polyolefin compositions comprising a matrix comprising a propylene homo- and/or copolymer and an elastomeric alpha-olefin copolymer phase dispersed in the matrix, which have rather high melt flow rate, improved impact strength but also an excellent impact/stiffness balance and a process for the preparation of such a heterophasic polyolefin composition, articles made therefrom and uses of the heterophasic polyolefin composition.

Processes for Producing High Propylene Content PEDM Using Tetrahydroindacenyl Catalyst Systems

The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene-diene terpolymer typically comprising from 1 to 35 mol % of ethylene, from 98.9 to 65 mol % C3-C.sub.40 olefin, and, optionally, from 0.1 to 10 mol % diene. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.

Processes for Producing High Propylene Content PEDM Using Tetrahydroindacenyl Catalyst Systems

The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene-diene terpolymer typically comprising from 1 to 35 mol % of ethylene, from 98.9 to 65 mol % C3-C.sub.40 olefin, and, optionally, from 0.1 to 10 mol % diene. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.

Processes for Producing High Propylene Content PEDM Having Low Glass Transition Temperatures Using Tetrahydroindacenyl Catalyst Systems

The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene-diene terpolymer typically comprising from 30 to 55 mol % ethylene, from 69.09 to 45 mol % C.sub.3 to C.sub.40 comonomer, and from 0.01 to 7 mol % diene wherein the Tg of the terpolymer is 28 C. or less. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.

Processes for Producing High Propylene Content PEDM Having Low Glass Transition Temperatures Using Tetrahydroindacenyl Catalyst Systems

The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene-diene terpolymer typically comprising from 30 to 55 mol % ethylene, from 69.09 to 45 mol % C.sub.3 to C.sub.40 comonomer, and from 0.01 to 7 mol % diene wherein the Tg of the terpolymer is 28 C. or less. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.

Multiple Non-coordinating Anion Activators For Propylene-ethylene-diene Monomer Polymerization Reactions
20190284319 · 2019-09-19 ·

This invention relates to production of propylene-predominant copolymers using a transition metal complex and at least two different non-coordinating anion activators. An olefinic feed comprising a C.sub.3-C.sub.40 alpha olefin, ethylene, and a diene monomer is contacted under polymerization reaction conditions with a catalyst system comprising a first non-coordinating anion activator, a second non-coordinating borate activator differing from the first non-coordinating anion activator, and a transition metal complex comprising a tetrahydro-s-indacenyl or tetrahydro-as-indacenyl group bound to a group 3-6 transition metal. A molar ratio of the first non-coordinating anion activator to the second non-coordinating anion activator is sufficient to produce a melt flow rate under the polymerization reaction conditions for the resulting copolymer of about 30 g/10 min or below as determined by ASTM D-1238 (230 C., 2.16 kg).

Multiple Non-coordinating Anion Activators For Propylene-ethylene-diene Monomer Polymerization Reactions
20190284319 · 2019-09-19 ·

This invention relates to production of propylene-predominant copolymers using a transition metal complex and at least two different non-coordinating anion activators. An olefinic feed comprising a C.sub.3-C.sub.40 alpha olefin, ethylene, and a diene monomer is contacted under polymerization reaction conditions with a catalyst system comprising a first non-coordinating anion activator, a second non-coordinating borate activator differing from the first non-coordinating anion activator, and a transition metal complex comprising a tetrahydro-s-indacenyl or tetrahydro-as-indacenyl group bound to a group 3-6 transition metal. A molar ratio of the first non-coordinating anion activator to the second non-coordinating anion activator is sufficient to produce a melt flow rate under the polymerization reaction conditions for the resulting copolymer of about 30 g/10 min or below as determined by ASTM D-1238 (230 C., 2.16 kg).

Method for producing stretched film
10273337 · 2019-04-30 · ·

The present invention is a method for producing a stretched film comprising stretching an unstretched film that is formed using a hydrogenated dicyclopentadiene ring-opening polymer at a temperature of 95 to 135 C. and a stretching ratio of 1.2 to 10, followed by heating at a temperature of 150 to 220 C. Since the thus-obtained stretched film has excellent transparency and low coefficient of linear expansion, the stretched film is suitable for not only use in optical applications but also use for electronic materials.