A film formed from a polyethylene copolymer using a reduced chromium oxide catalyst, ethylene monomers and a co-monomer selected from butene monomers or 1-hexene, where the polyethylene copolymer has a density in the range of from about 0.935 to about 0.950 g/cm.sup.3 and an I.sub.21/I.sub.5 in a range of about 18.0 to about 30.0. The film formed from the polyethylene copolymer has a dart drop impact (g/.sub.im) that significantly greater as compared to a film of the polyethylene copolymer formed using a silyl chromate catalyst in place of the reduced chromium oxide catalyst. A method of making such films is also provided.

A shoe sole composition and method for making a shoe sole are provided. The shoe sole includes a composition comprising a foamed silane-crosslinked polyolefin elastomer having a density less than 0.50 g/cm.sup.3. The shoe sole exhibits a compression set of from about 5.0% to about 20.0%, as measured according to ASTM D 395 (6 hrs @ 50 C.). The foamed silane-crosslinked polyolefin elastomer can be produced from a blend including a first polyolefin having a density less than 0.86 g/cm.sup.3, a second polyolefin, having a crystallinity less than 40%, a silane crosslinker, a grafting initiator, a condensation catalyst, and a foaming agent.

An elastomeric article is provided that includes a composition having a silane-crosslinked polyolefin elastomer with a density less than 0.90 g/cm.sup.3. The elastomeric article can exhibit a compression set of from about 5.0% to about 35.0%, as measured according to ASTM D 395 (22 hrs @ 70 C.). The silane-crosslinked polyolefin elastomer can include a first polyolefin having a density less than 0.86 g/cm.sup.3, a second polyolefin having a crystallinity less than 40%, a silane crosslinker, a grafting initiator, and a condensation catalyst.

This elastomer material for medical devices contains: a first fluorine-based elastomer that is a ternary copolymer comprising three kinds of monomers A, B and C; and a second fluorine-based elastomer that is a ternary copolymer comprising the monomers A and B and a monomer D which is different from any one of the monomers A, B and C. The monomer C and the monomer D have side chains that have structures different from each other.

An ethylene/butadiene copolymer comprising statistically distributed ethylene units butadiene units, and trans-1,2-cyclohexane units is provided. The molar fraction of ethylene units in the copolymer is greater than or equal to 50%, relative to the total number of moles of ethylene, butadiene and trans-1,2-cyclohexane units. The microstructure of the copolymer is homogeneous.

A process for preparing such a copolymer and also to the uses of this copolymer, in particular in rubber compositions for tires, is also provided.

Provided herein are multimodal elastomer compositions comprising a first polymer fraction and a second polymer fraction, and methods for making such compositions. The elastomer compositions are preferably ethylene, -olefin, copolymers or ethylene, -olefin, polyene terpolymers. The elastomer compositions have high Mooney viscosity, thereby providing for improved elastomeric properties in compounds and other articles formed from the elastomer compositions. Surprisingly, the high Mooney viscosity compositions exhibit a much lower than expected viscosity when formulated into elastomer compounds. Thus, the processing detriments typically associated with high Mooney viscosity elastomers are minimized through the use of the elastomer compositions, and methods for making them, disclosed herein.

Provided herein are multimodal elastomer compositions comprising a first polymer fraction and a second polymer fraction, and methods for making such compositions. The elastomer compositions are preferably ethylene, -olefin, copolymers or ethylene, -olefin, polyene terpolymers. The elastomer compositions have high Mooney viscosity, thereby providing for improved elastomeric properties in compounds and other articles formed from the elastomer compositions. Surprisingly, the high Mooney viscosity compositions exhibit a much lower than expected viscosity when formulated into elastomer compounds. Thus, the processing detriments typically associated with high Mooney viscosity elastomers are minimized through the use of the elastomer compositions, and methods for making them, disclosed herein.

The invention pertains to a method for manufacturing a (per)fluoroelastomer [fluoroelastomer (A)] comprising the following steps: step (a): polymerizing in an aqueous emulsion in the presence of a surfactant by feeding in a first reactor comprising feeding the following ingredients: (i) a monomer mixture [mixture (M1)] comprising at least one fluoromonomer [monomer (F)], (ii) at least one iodinated and/or brominated chain-transfer agent(s), (iii) at least one branching agent possessing at least two ethylenic unsaturations; and (iv) at least one radical initiator, so as to obtain a pre-polymer latex [latex (P)]; step (b): recovering the said latex (P) from the said first reactor and storing the same in a storage tank; and step (c): feeding the said latex (P) from the said storage tank to a second reactor; step (d): polymerizing in the said second reactor at least a second monomer mixture [mixture (M2)] comprising at least one monomer (F) in the presence of a radical initiator, so as to obtain a final latex [latex (F)]; and step (d): recovering the (per)fluoroelastomer from the said latex (F).

The invention provides a composition comprising a first composition that comprises an ethylene/alpha-olefin/non-conjugated polyene interpolymer that has the following properties: A) a Mw greater than, or equal to, 150,000 g/mole; and B) a peak area from 21.3 ppm to 21.8 ppm that is greater than, or equal to, 3.0 percent of the total integral area from 19.5 ppm to 22.0 ppm, as determined by 13C NMR; and wherein the first composition has a tan delta (190 C at 0.1 rad/sec) less than, or equal to, 1.0.

The invention provides a composition comprising a first composition that comprises an ethylene/alpha-olefin/non-conjugated polyene interpolymer that has the following properties: A) a Mw greater than, or equal to, 150,000 g/mole; and B) a peak area from 21.3 ppm to 21.8 ppm that is greater than, or equal to, 3.0 percent of the total integral area from 19.5 ppm to 22.0 ppm, as determined by 13C NMR; and wherein the first composition has a tan delta (190 C at 0.1 rad/sec) less than, or equal to, 1.0.