A tire with improved wear resistance, rolling resistance and cohesion, comprises a rubber composition based on at least one elastomeric matrix comprising predominantly a random copolymer comprising ethylene units and conjugated diene units, the mole fraction of ethylene units in the copolymer being within a range extending from 50% to 95%; a peroxide; and a specific polyfunctional acrylate; the contents of polyfunctional acrylate and of peroxide being such that the ratio of the peroxide content to the polyfunctional acrylate content is greater than or equal to 0.08; said composition comprising from 5 to less than 65 phr of reinforcing filler; the ratio of the filler content to the polyfunctional acrylate content being greater than or equal to 1.25.

A tire with improved wear resistance, rolling resistance and cohesion, comprises a rubber composition based on at least one elastomeric matrix comprising predominantly a random copolymer comprising ethylene units and conjugated diene units, the mole fraction of ethylene units in the copolymer being within a range extending from 50% to 95%; a peroxide; and a specific polyfunctional acrylate; the contents of polyfunctional acrylate and of peroxide being such that the ratio of the peroxide content to the polyfunctional acrylate content is greater than or equal to 0.08; said composition comprising from 5 to less than 65 phr of reinforcing filler; the ratio of the filler content to the polyfunctional acrylate content being greater than or equal to 1.25.

A modified conjugated diene-based polymer, and more particularly, a modified conjugated diene-based polymer having a unimodal molecular weight distribution curve measured by gel permeation chromatography (GPC), molecular weight distribution (PDI; MWD) of less than 1.7, and a Si content of 100 ppm or more based on weight, and including a repeating unit derived from an aromatic vinyl monomer in an amount of 30 wt % or more, and a rubber composition including the same.

The present disclosure provides catalyst systems having a bridged metallocene compound and a transition metal pyridyldiamide compound for use in alkene polymerization to produce multimodal polyolefins, such as multimodal ethylene, propylene, diene monomer copolymers. In some embodiments, the present disclosure provides for polyolefins and processes for producing a polyolefin composition including contacting at least one olefin with a catalyst system of the present disclosure.

The present disclosure provides catalyst systems having a bridged metallocene compound and a transition metal pyridyldiamide compound for use in alkene polymerization to produce multimodal polyolefins, such as multimodal ethylene, propylene, diene monomer copolymers. In some embodiments, the present disclosure provides for polyolefins and processes for producing a polyolefin composition including contacting at least one olefin with a catalyst system of the present disclosure.

A film formed from a polyethylene copolymer using a reduced chromium oxide catalyst, ethylene monomers and a co-monomer selected from butene monomers or 1-hexene, where the polyethylene copolymer has a density in the range of from about 0.935 to about 0.950 g/cm.sup.3 and an I.sub.21/I.sub.5 in a range of about 18.0 to about 30.0. The film formed from the polyethylene copolymer has a dart drop impact (g/m) that significantly greater as compared to a film of the polyethylene copolymer formed using a silyl chromate catalyst in place of the reduced chromium oxide catalyst. A method of making such films is also provided.

A film formed from a polyethylene copolymer using a reduced chromium oxide catalyst, ethylene monomers and a co-monomer selected from butene monomers or 1-hexene, where the polyethylene copolymer has a density in the range of from about 0.935 to about 0.950 g/cm.sup.3 and an I.sub.21/I.sub.5 in a range of about 18.0 to about 30.0. The film formed from the polyethylene copolymer has a dart drop impact (g/m) that significantly greater as compared to a film of the polyethylene copolymer formed using a silyl chromate catalyst in place of the reduced chromium oxide catalyst. A method of making such films is also provided.

Provided are use of organosilane, and polyolefin resin and preparation method thereof. The method of preparing the polyolefin resin comprises: conducting olefin polymerization of olefin monomers in the presence of a catalyst, and adding organosilane to a polymerization system before the olefin polymerization and/or during the olefin polymerization, wherein the organosilane is represented by a general formula of R.sup.1.sub.mSiX.sub.n(OR.sup.2).sub.k, wherein R.sup.1 is a C.sub.2-C.sub.20 alkyl, and a terminal of R.sup.1 has an -olefin double bond, a norbornene group, a cycloalkene group, or a dicyclopentadiene group; X is a halogen element; R.sup.2 is a C.sub.1-C.sub.20 straight chain, a C.sub.1-C.sub.20 branched chain, or an isomerized alkyl group; m is an integer from 1-3; n is an integer from 1-3; k is an integer from 0-2; and m, n, and k satisfy the following condition: m+n+k=4. The polyolefin resin obtained by the above method has higher melt strength and mechanical strength.

Provided are use of organosilane, and polyolefin resin and preparation method thereof. The method of preparing the polyolefin resin comprises: conducting olefin polymerization of olefin monomers in the presence of a catalyst, and adding organosilane to a polymerization system before the olefin polymerization and/or during the olefin polymerization, wherein the organosilane is represented by a general formula of R.sup.1.sub.mSiX.sub.n(OR.sup.2).sub.k, wherein R.sup.1 is a C.sub.2-C.sub.20 alkyl, and a terminal of R.sup.1 has an -olefin double bond, a norbornene group, a cycloalkene group, or a dicyclopentadiene group; X is a halogen element; R.sup.2 is a C.sub.1-C.sub.20 straight chain, a C.sub.1-C.sub.20 branched chain, or an isomerized alkyl group; m is an integer from 1-3; n is an integer from 1-3; k is an integer from 0-2; and m, n, and k satisfy the following condition: m+n+k=4. The polyolefin resin obtained by the above method has higher melt strength and mechanical strength.

A tire including a circular tire frame containing a resin composition, the resin composition containing a polypropylene having a melting temperature of 160 C. or higher, an ethylene-propylene rubber, and a styrene-containing elastomer, in which a content of the polypropylene having a melting temperature of 160 C. or higher being 60% by mass or less with respect to the resin composition as a whole, and a content of a styrene component being 5% by mass or more with respect to the resin composition as a whole.