Patent classifications
C08F2500/21
Method for in-depth profile control and displacement of low-permeability oil reservoirs
The present invention provides a method for in-depth profile control and displacement of low-permeability oil reservoirs, comprising: sequentially injecting a flexible and elastic particle-containing pre-slug, a polymer microsphere-containing main slug and a flexible and elastic particle-containing protective slug into an oil layer, and the three slugs have a volume ratio of total injection amount of 1-2:6-8:1-2. The invention provides a method for in-depth profile control and displacement by using styrene-based flexible and elastic particles in combination with the polyacrylamide polymer microsphere, wherein the flexible elastic particles can block cracks and large pore channels of the oil layer, and the polymer microsphere can displace the remaining oil in the oil layer. In the present invention, different slugs of profile control and displacement system are combined to achieve the objective of blocking cracks and large pore channels, displacing crude oil, and improving oil well recovery.
Thermoplastic vulcanizate compositions
A thermoplastic vulcanizate comprises an isotactic polypropylene matrix phase in which cross-linked rubber particles are dispersed, the rubber particles comprising an ethylene-propylene-diene terpolymer (EPDM) containing at least 40 wt % of ethylene-derived units. A propylene-ethylene-diene terpolymer (PEDM) containing at least 60 wt % propylene-derived units and less than or equal to 25 wt % of ethylene-derived units and having a heat of fusion (H.sub.f) of 2 to 10 J/g is added to compatibilize the propylene/EPDM blend.
Elastomer
An elastomer is provided, which is a product of reacting C.sub.4-12 lactam, poly(C.sub.2-4 alkylene glycol), C.sub.4-12 diacid, and multi-ester aliphatic monomer. The C.sub.4-12 lactam and the poly(C.sub.2-4 alkylene glycol) have a weight ratio of 20:80 to 80:20. The total weight of the C.sub.4-12 lactam and the poly(C.sub.2-4 alkylene glycol) and the weight of the C.sub.4-12 diacid have a ratio of 100:0.5 to 100:10. The total weight of the C.sub.4-12 lactam and the poly(C.sub.2-4 alkylene glycol) and the weight of the multi-ester aliphatic monomer have a ratio of 100:0.01 to 100:5.
THERMOPLASTIC RESIN COMPOSITION
The present invention relates to a thermoplastic resin composition, which includes a first copolymer formed by polymerizing a monomer mixture of a (meth)acrylate-based monomer, a vinyl cyan-based monomer and a maleimide-based monomer, and having a refractive index of 1.5170 or less and a glass transition temperature of 115.0 C. or more; and a second copolymer formed by graft-copolymerizing an aromatic vinyl-based monomer and a vinyl cyan-based monomer onto an acrylic rubber polymer, and the thermoplastic resin composition according to the present invention has improved heat resistance, colorability and scratch resistance.
ETHYLENE/alpha-OLEFIN/NON-CONJUGATED POLYENE COPOLYMER, METHOD FOR PRODUCING THE SAME, AND USE THEREOF
An object of the present invention is to provide a novel ethylene/-olefin/non-conjugated polyene copolymer containing a certain non-conjugated polyene such as VNB as a copolymerization component, having a low long-chain branching content, excellent in cure characteristics in the case of crosslinking by using peroxide, and having good processability. The ethylene/-olefin/non-conjugated polyene copolymer according to the present invention has constitutional units derived from ethylene (A), an -olefin (B) having 3 to 20 carbon atoms, and a non-conjugated polyene (C) having a total of two or more partial structures selected from the group consisting of the following general formulas (I) and (II) in a molecule, and satisfies certain requirements.
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ETHYLENE/alpha-OLEFIN/NON-CONJUGATED POLYENE COPOLYMER, METHOD FOR PRODUCING THE SAME, AND USE THEREOF
An object of the present invention is to provide a novel ethylene/-olefin/non-conjugated polyene copolymer containing a certain non-conjugated polyene such as VNB as a copolymerization component, having a low long-chain branching content, excellent in cure characteristics in the case of crosslinking by using peroxide, and having good processability. The ethylene/-olefin/non-conjugated polyene copolymer according to the present invention has constitutional units derived from ethylene (A), an -olefin (B) having 3 to 20 carbon atoms, and a non-conjugated polyene (C) having a total of two or more partial structures selected from the group consisting of the following general formulas (I) and (II) in a molecule, and satisfies certain requirements.
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Thermoplastic elastomer composition and molded body thereof
A thermoplastic elastomer composition contains components (A) to (D), wherein the content of the component (A), (B), (C) and (D) is, respectively, 26% by weight or more and 59% by weight or less, 2% by weight or more and 9% by weight or less, 16% by weight or more and 61% by weight or less and 11% by weight or more and 56% by weight or less, when the total amount of the components (A) to (D) is 100% by weight, and the ratio of the content of the component (C) to the content of the component (D) is over 1 and 5 or less.
Olefin polymerization catalyst, preparation method thereof, olefin polymerization catalyst system, use thereof, and method of preparing polyolefin resin
The present invention provides modified olefin polymerization catalyst, preparation method thereof, olefin polymerization catalyst system, use thereof and method of preparing polyolefin resin. The catalyst comprises an olefin polymerization catalyst and an organosilane, which is represented by a general formula R.sup.1.sub.mSiX.sub.n(OR.sup.2).sub.k, where R.sup.1 is a C.sub.2-C.sub.20 alkyl group and a terminal of R.sup.1 has an -olefin double bond, a norbornene group, a cycloolefin group or a dicyclopentadiene group, X is a halogen element, R.sup.2 is a C.sub.1-C.sub.20 linear chain, branched chain or isomerized alkyl group, m is an integer from 1-3, n is an integer from 1-3, k is an integer within a range of 0-2, and m+n+k=4. High-performance polyolefin resins, including homopolymerized polyolefin resin with high melt and mechanical strength, polyolefin elastomer with high rubber phase content, and polyolefin elastomer with a rubber phase in a crosslinked structure, etc., can be obtained through polymerization with the catalyst.
Olefin polymerization catalyst, preparation method thereof, olefin polymerization catalyst system, use thereof, and method of preparing polyolefin resin
The present invention provides modified olefin polymerization catalyst, preparation method thereof, olefin polymerization catalyst system, use thereof and method of preparing polyolefin resin. The catalyst comprises an olefin polymerization catalyst and an organosilane, which is represented by a general formula R.sup.1.sub.mSiX.sub.n(OR.sup.2).sub.k, where R.sup.1 is a C.sub.2-C.sub.20 alkyl group and a terminal of R.sup.1 has an -olefin double bond, a norbornene group, a cycloolefin group or a dicyclopentadiene group, X is a halogen element, R.sup.2 is a C.sub.1-C.sub.20 linear chain, branched chain or isomerized alkyl group, m is an integer from 1-3, n is an integer from 1-3, k is an integer within a range of 0-2, and m+n+k=4. High-performance polyolefin resins, including homopolymerized polyolefin resin with high melt and mechanical strength, polyolefin elastomer with high rubber phase content, and polyolefin elastomer with a rubber phase in a crosslinked structure, etc., can be obtained through polymerization with the catalyst.
POLYMERIZATION CATALYST COMPOSITION, POLYMER MANUFACTURING METHOD, POLYMER, RUBBER COMPOSITION, AND TIRE
To provide a catalyst composition having high polymerization activity. To provide a polymer manufacturing method. To provide a polymer manufactured by the polymer manufacturing method. To provide a rubber composition including the polymer. To provide a tire using the rubber composition. A catalyst composition including a compound represented by Structural Formula I below, wherein the compound has an OH group at at least one position of the bipyridyl ring; M is a transition metal, a lanthanoid, scandium, or yttrium; R.sup.1 and R.sup.2 are a hydrocarbon group having one or more carbon atoms or a halogen atom; and R.sup.1 and R.sup.2 may be the same or different from each other. A polymer manufacturing method including a step of polymerizing one or more selected from the group consisting of a conjugated diene compound and a compound having an ethylenically unsaturated double bond in the presence of the catalyst composition. A polymer manufactured by the manufacturing method. A rubber composition including the polymer. A tire using the rubber composition.
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