C08F2500/24

CATALYST COMPONENT FOR OLEFIN POLYMERIZATION OR COPOLYMERIZATION AND PREPARATION METHOD THEREFOR, AND APPLICATION

The present disclosure relates to olefin polymerization catalysts, and discloses a catalyst component for olefin polymerization or copolymerization and a preparation method therefor, and a catalyst and an application thereof. The catalyst component for olefin polymerization or copolymerization in the present disclosure comprises titanium element, magnesium element, an electron donor, an organic silicon polymer, and an inorganic oxide support, wherein the molecular composition of the organic silicon polymer is [R.sub.xSiO.sub.(4-x)/2].sub.m, wherein R is selected from alkyl, aryl, vinyl or oxygen, x is 0 or more and 2 or less, and the value of m makes the number-average molecular weight of the organic silicon polymer be 1×10.sup.3-1×10.sup.6 g/mol. The catalyst has the characteristics of high activity, good hydrogen-regulating copolymerization performance, high bulk density of resulting polymer powder, and a low content of fine powder in the polymer powder when applied to olefin polymerization, particularly to ethylene and α-olefin polymerization.

Particle size control of supported chromium catalysts in loop slurry polymerization reactors

Supported chromium catalysts containing a solid oxide and 0.1 to 15 wt. % chromium, in which the solid oxide or the supported chromium catalyst has a particle size span from 0.5 to 1.4, less than 3 wt. % has a particle size greater than 100 μm, and less than 10 wt. % has a particle size less than 10 μm, can be contacted with an olefin monomer in a loop slurry reactor to produce an olefin polymer. Representative ethylene-based polymers produced using the chromium catalysts have a HLMI of 4 to 70 g/10 min, a density from 0.93 to 0.96 g/cm.sup.3, from 150 to 680 ppm solid oxide (such as silica), from 1.5 to 6.8 ppm chromium, and a film gel count of less than 15 catalyst particle gels per ft.sup.2 of 25 micron thick film and/or a gel count of less than or equal to 50 catalyst particles of greater than 100 μm per five grams of the ethylene polymer.

Particle size control of supported chromium catalysts in loop slurry polymerization reactors

Supported chromium catalysts containing a solid oxide and 0.1 to 15 wt. % chromium, in which the solid oxide or the supported chromium catalyst has a particle size span from 0.5 to 1.4, less than 3 wt. % has a particle size greater than 100 μm, and less than 10 wt. % has a particle size less than 10 μm, can be contacted with an olefin monomer in a loop slurry reactor to produce an olefin polymer. Representative ethylene-based polymers produced using the chromium catalysts have a HLMI of 4 to 70 g/10 min, a density from 0.93 to 0.96 g/cm.sup.3, from 150 to 680 ppm solid oxide (such as silica), from 1.5 to 6.8 ppm chromium, and a film gel count of less than 15 catalyst particle gels per ft.sup.2 of 25 micron thick film and/or a gel count of less than or equal to 50 catalyst particles of greater than 100 μm per five grams of the ethylene polymer.

Method for producing heterophasic propylene polymerization material particles

Provided is a particle drying method capable of sufficiently removing the volatile component and down-regulating the increase of the viscosity of the particles after the removal of the volatile component. There is provided a method for producing heterophasic propylene polymerization material particles, the method including: (1) performing monomer polymerization in the presence of a catalyst including a solid catalyst component so as to obtain a component I; (2) performing monomer polymerization in the presence of the component I so as to obtain the component II, so that particles including a volatile component are produced; and (3) causing the particles to contact with an inert gas-containing stream so as to remove the volatile component from the particles.

Method for producing heterophasic propylene polymerization material particles

Provided is a particle drying method capable of sufficiently removing the volatile component and down-regulating the increase of the viscosity of the particles after the removal of the volatile component. There is provided a method for producing heterophasic propylene polymerization material particles, the method including: (1) performing monomer polymerization in the presence of a catalyst including a solid catalyst component so as to obtain a component I; (2) performing monomer polymerization in the presence of the component I so as to obtain the component II, so that particles including a volatile component are produced; and (3) causing the particles to contact with an inert gas-containing stream so as to remove the volatile component from the particles.

Particle size control of metallocene catalyst systems in loop slurry polymerization reactors

Catalyst compositions containing a metallocene compound, a solid activator, and a co-catalyst, in which the solid activator or the supported metallocene catalyst has a d50 average particle size of 15 to 50 μm and a particle size distribution of 0.5 to 1.5, can be contacted with an olefin in a loop slurry reactor to produce an olefin polymer. A representative ethylene-based polymer produced using the catalyst composition has excellent dart impact strength and low gels, and can be characterized by a HLMI from 4 to 10 g/10 min, a density from 0.944 to 0.955 g/cm.sup.3, a higher molecular weight component with a Mn from 280,000 to 440,000 g/mol, and a lower molecular weight component with a Mw from 30,000 to 45,000 g/mol and a ratio of Mz/Mw ranging from 2.3 to 3.4.

Particle size control of metallocene catalyst systems in loop slurry polymerization reactors

Catalyst compositions containing a metallocene compound, a solid activator, and a co-catalyst, in which the solid activator or the supported metallocene catalyst has a d50 average particle size of 15 to 50 μm and a particle size distribution of 0.5 to 1.5, can be contacted with an olefin in a loop slurry reactor to produce an olefin polymer. A representative ethylene-based polymer produced using the catalyst composition has excellent dart impact strength and low gels, and can be characterized by a HLMI from 4 to 10 g/10 min, a density from 0.944 to 0.955 g/cm.sup.3, a higher molecular weight component with a Mn from 280,000 to 440,000 g/mol, and a lower molecular weight component with a Mw from 30,000 to 45,000 g/mol and a ratio of Mz/Mw ranging from 2.3 to 3.4.

Bimodal propylene polymers and sequential polymerization

This invention relates to high porosity (≧15%) and/or low pore diameter (PD<165 μm) propylene polymers and propylene polymerization processes using single site catalyst systems with supports having high surface area (SA≧400 m.sup.2/g), low pore volume (PV≦2 mL/g), a specific mean pore diameter range (PD=1-20 nm), and high average particle size (PS≧30 μm).

Bimodal propylene polymers and sequential polymerization

This invention relates to high porosity (≧15%) and/or low pore diameter (PD<165 μm) propylene polymers and propylene polymerization processes using single site catalyst systems with supports having high surface area (SA≧400 m.sup.2/g), low pore volume (PV≦2 mL/g), a specific mean pore diameter range (PD=1-20 nm), and high average particle size (PS≧30 μm).

POLYETHYLENE HOMO- OR COPOLYMER HAVING IMPROVED WEAR PROPERTIES

The present invention relates to a polyethylene homo- or copolymer having improved wear properties. In particular, the invention relates to an ultra-high molecular weight polyethylene having improved wear properties prepared using a heterogeneous Ziegler catalyst system. Said polyethylene homo- or copolymer is characterized in that the abrasion index of said polyethylene is related to the elongational stress according to the formula (I): in which ES=elongational stress as measured according to ISO 11542-2:1998 AI=abrasion index, as measured according to ISO 15527:2010 where the reference material according to ISO 15527:2010 is set to 100; β<1.8; and −0.015<a<−0.017.

[00001] AI < ES - β α ( I )