Supported chromium catalysts containing a solid oxide and 0.1 to 15 wt. % chromium, in which the solid oxide or the supported chromium catalyst has a particle size span from 0.5 to 1.4, less than 3 wt. % has a particle size greater than 100 μm, and less than 10 wt. % has a particle size less than 10 μm, can be contacted with an olefin monomer in a loop slurry reactor to produce an olefin polymer. Representative ethylene-based polymers produced using the chromium catalysts have a HLMI of 4 to 70 g/10 min, a density from 0.93 to 0.96 g/cm.sup.3, from 150 to 680 ppm solid oxide (such as silica), from 1.5 to 6.8 ppm chromium, and a film gel count of less than 15 catalyst particle gels per ft.sup.2 of 25 micron thick film and/or a gel count of less than or equal to 50 catalyst particles of greater than 100 μm per five grams of the ethylene polymer.

The instant invention provides a polyolefin composition suitable for sealant applications, sealant compositions, method of producing the same, and films and multilayer structures made therefrom. The polyolefin composition suitable for sealant applications according to the present invention comprises: an ethylene/α-olefin interpolymer composition having a Comonomer Distribution Constant (CDC) in the range of from 40 to 110, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the ethylene-based polymer composition; a zero shear viscosity ratio (ZSVR) in the range of from 1.01 to 2.0; a density in the range of from 0.908 to 0.922 g/cm.sup.3, a melt index (I.sub.2 at 190° C./2.16 kg) in the range of from 0.5 to 5.0 g/10 minutes, a molecular weight distribution (defined as the weight average molecular weight divided by the number average molecular weight, M.sub.w/M.sub.n) in the range of from 2.0 to 4.0, and tan delta at 0.1 radian/second, determined at 190° C., in the range of from 5 to 50.

The instant invention provides a polyolefin composition suitable for sealant applications, sealant compositions, method of producing the same, and films and multilayer structures made therefrom. The polyolefin composition suitable for sealant applications according to the present invention comprises: an ethylene/α-olefin interpolymer composition having a Comonomer Distribution Constant (CDC) in the range of from 40 to 110, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the ethylene-based polymer composition; a zero shear viscosity ratio (ZSVR) in the range of from 1.01 to 2.0; a density in the range of from 0.908 to 0.922 g/cm.sup.3, a melt index (I.sub.2 at 190° C./2.16 kg) in the range of from 0.5 to 5.0 g/10 minutes, a molecular weight distribution (defined as the weight average molecular weight divided by the number average molecular weight, M.sub.w/M.sub.n) in the range of from 2.0 to 4.0, and tan delta at 0.1 radian/second, determined at 190° C., in the range of from 5 to 50.

Provided are novel cross-linked polymers and their use in various materials, including packaging films and injection molded articles. These polymers, which comprise certain hydroxyl-containing crosslinking compounds, as well as optionally adjuvants, show improved creep resistance when compared to conventional ethylene acrylic or methacrylic acid copolymers and their ionomers.

Provided are novel cross-linked polymers and their use in various materials, including packaging films and injection molded articles. These polymers, which comprise certain hydroxyl-containing crosslinking compounds, as well as optionally adjuvants, show improved creep resistance when compared to conventional ethylene acrylic or methacrylic acid copolymers and their ionomers.

The present invention relates to a multimodal polyethylene composition comprising: (A) 40 to 65 parts by weight, preferably 43 to 52 parts by weight, most preferred 44 to 50 parts by′ weight, of the low molecular weight polyethylene having a weight average molecular weight (Mw) of 20,000 to 90,000 g/mol, wherein the low molecular weight polyethylene has a MI2 of 500 to 1,000 g/10 min according to ASTM D 1238; (B) 5 to 17 parts by weight, preferably 10 to 17 parts by weight, most preferred 10 to 15 parts by weight, of the first high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000 g/mol or the first ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000 g/mol; and (C) 30 to 50 parts by weight, preferably 37 to 47 party by weight, most preferably 39 to 45 parts by weight, of the second high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000 g/mol or the second ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000 g/mol, wherein the density of the first high molecular weight polyethylene or the first ultra high molecular weight polyethylene and the second high molecular weight polyethylene or the second ultra high molecular weight polyethylene is in the same range and both densities are in the range from 0.910 to 0.940 g/cm3; and the molecular weight distribution of the multimodal polyethylene composition is from 18 to 30, preferably 20 to 28, measured by gel permeation chromatography, film comprising the multimodal polyethylene composition and the use thereof.

The present invention relates to a multimodal polyethylene composition comprising: (A) 40 to 65 parts by weight, preferably 43 to 52 parts by weight, most preferred 44 to 50 parts by′ weight, of the low molecular weight polyethylene having a weight average molecular weight (Mw) of 20,000 to 90,000 g/mol, wherein the low molecular weight polyethylene has a MI2 of 500 to 1,000 g/10 min according to ASTM D 1238; (B) 5 to 17 parts by weight, preferably 10 to 17 parts by weight, most preferred 10 to 15 parts by weight, of the first high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000 g/mol or the first ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000 g/mol; and (C) 30 to 50 parts by weight, preferably 37 to 47 party by weight, most preferably 39 to 45 parts by weight, of the second high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000 g/mol or the second ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000 g/mol, wherein the density of the first high molecular weight polyethylene or the first ultra high molecular weight polyethylene and the second high molecular weight polyethylene or the second ultra high molecular weight polyethylene is in the same range and both densities are in the range from 0.910 to 0.940 g/cm3; and the molecular weight distribution of the multimodal polyethylene composition is from 18 to 30, preferably 20 to 28, measured by gel permeation chromatography, film comprising the multimodal polyethylene composition and the use thereof.

The instant invention provides a linear low density polyethylene composition suitable for cast film, films made therefrom, and packaging devices comprising one or more such film layers. The linear low density polyethylene composition suitable for cast film according to the present invention comprises an ethylene/α-olefin interpolymer composition having a Comonomer Distribution Constant (CDC) in the range of from 40 to 200, for example from 40 to 150, a vinyl unsaturation of less than 0.12 vinyls per one thousand carbon atoms present in the backbone of the ethylene-based polymer composition; a zero shear viscosity ratio (ZSVR) in the range from 1.2 to 5, for example from 1.5 to 4; a density in the range of from 0.910 to 0.935, for example from 0.915 to 0.925, g/cm.sup.3, a melt index (I.sub.2) in a range of from 1 to 10, for example from 2 to 6 g/10 minutes, a molecular weight distribution (M.sub.w/M.sub.n) in the range of from 2 to 3.5.

The instant invention provides a linear low density polyethylene composition suitable for cast film, films made therefrom, and packaging devices comprising one or more such film layers. The linear low density polyethylene composition suitable for cast film according to the present invention comprises an ethylene/α-olefin interpolymer composition having a Comonomer Distribution Constant (CDC) in the range of from 40 to 200, for example from 40 to 150, a vinyl unsaturation of less than 0.12 vinyls per one thousand carbon atoms present in the backbone of the ethylene-based polymer composition; a zero shear viscosity ratio (ZSVR) in the range from 1.2 to 5, for example from 1.5 to 4; a density in the range of from 0.910 to 0.935, for example from 0.915 to 0.925, g/cm.sup.3, a melt index (I.sub.2) in a range of from 1 to 10, for example from 2 to 6 g/10 minutes, a molecular weight distribution (M.sub.w/M.sub.n) in the range of from 2 to 3.5.

Catalyst systems and methods for making and using the same. A method of polymerizing olefins to produce a polyolefin polymer with a multimodal composition distribution, includes contacting ethylene and a comonomer with a catalyst system. The catalyst system includes a first catalyst compound and a second catalyst compound that are co-supported to form a commonly supported catalyst system. The first catalyst compound includes a compound with the general formula (C.sub.5H.sub.aR.sup.1.sub.b)(C.sub.5H.sub.cR.sup.2.sub.d)HfX.sub.2. The second catalyst compound includes at least one of the following general formulas:

##STR00001##

##STR00002##

In both catalyst systems, the R groups can be independently selected from any number of substituents, including, for example, H, a hydrocarbyl group, a substituted hydrocarbyl group, or a heteroatom group, among others.