The present invention relates to an olefin-based polymer, which has (1) a density (d) ranging from 0.85 to 0.90 g/cc, (2) a melt index (MI, 190° C., 2.16 kg load conditions) ranging from 0.1 g/10 min to 15 g/10 min, (3) the density (d) and the melt temperature (Tm) satisfying Tm (° C.)=a×d−b of Equation 1 (2,350<a<2,500, and 1,900<b<2,100), and (4) a ratio (hardness/Tm) of the hardness (shore A) to the melt temperature (Tm) in a range of 1.0 to 1.3. The olefin-based polymer according to the present invention exhibits excellent anti-blocking properties due to having improved hardness as a low-density olefin-based polymer.

The present invention relates to an olefin-based polymer, which has (1) a density (d) ranging from 0.85 to 0.90 g/cc, (2) a melt index (MI, 190° C., 2.16 kg load conditions) ranging from 0.1 g/10 min to 15 g/10 min, (3) the density (d) and the melt temperature (Tm) satisfying Tm (° C.)=a×d−b of Equation 1 (2,350<a<2,500, and 1,900<b<2,100), and (4) a ratio (hardness/Tm) of the hardness (shore A) to the melt temperature (Tm) in a range of 1.0 to 1.3. The olefin-based polymer according to the present invention exhibits excellent anti-blocking properties due to having improved hardness as a low-density olefin-based polymer.

The present invention relates to use of optionally monosubstituted 2,2-di(tetrahydrofuryl)methanes, as internal donors in Ziegler-Natta catalysts to obtain polymers with desirable properties. The present disclosure further concerns Ziegler-Natta catalyst components comprising said optionally monosubstituted 2,2-di(tetrahydrofuryl)methanes and Ziegler-Natta catalysts for olefin polymerization comprising said Ziegler-Natta catalyst components as well as a method for preparing the same and their use in providing polyolefins.

The present invention relates to use of optionally monosubstituted 2,2-di(tetrahydrofuryl)methanes, as internal donors in Ziegler-Natta catalysts to obtain polymers with desirable properties. The present disclosure further concerns Ziegler-Natta catalyst components comprising said optionally monosubstituted 2,2-di(tetrahydrofuryl)methanes and Ziegler-Natta catalysts for olefin polymerization comprising said Ziegler-Natta catalyst components as well as a method for preparing the same and their use in providing polyolefins.

The purpose of the present invention is to provide a propylene-based block copolymer, the deposition thereof on the inner wall of the polymerization vessel having been sufficiently inhibited. The propylene-based block copolymer of the present invention has a flowability evaluation value of 40% or less, the value being calculated with the following equation wherein X (sec) is the number of seconds over which 100 g of the copolymer having ordinary temperature falls from a stainless-steel funnel having an inner diameter of 11.9 mm and Y (sec) is the number of seconds over which 100 g of the copolymer which has been held at 80° C. for 24 hours under a load of 10 kg falls from the funnel having an inner diameter of 11.9 mm.
Flowability evaluation value (%)={(Y/X)−1}×100.

The purpose of the present invention is to provide a propylene-based block copolymer, the deposition thereof on the inner wall of the polymerization vessel having been sufficiently inhibited. The propylene-based block copolymer of the present invention has a flowability evaluation value of 40% or less, the value being calculated with the following equation wherein X (sec) is the number of seconds over which 100 g of the copolymer having ordinary temperature falls from a stainless-steel funnel having an inner diameter of 11.9 mm and Y (sec) is the number of seconds over which 100 g of the copolymer which has been held at 80° C. for 24 hours under a load of 10 kg falls from the funnel having an inner diameter of 11.9 mm.
Flowability evaluation value (%)={(Y/X)−1}×100.

The object of the invention is to provide a novel olefin-based molded product useful for various applications. An olefin-based molded product comprising a polymer including a structural unit of at least one polar olefin monomer represented by the general formula (I) CH.sub.2═CH—R.sup.2—Z(R.sup.1).sub.n is provided. In the formula, Z is a hetero atom selected from the group consisting of nitrogen, oxygen, phosphorus, sulfur, and selenium; R.sup.1 is a substituted or unsubstituted hydrocarbyl group having 1 to 30 carbon atoms; n is an integer of 1 or 2 depending on the atomic species of Z; and R.sup.2 is a substituted or unsubstituted hydrocarbylene group having 2 to 20 carbon atoms.

Processes of polymerizing olefins include contacting ethylene, a (C.sub.3-C.sub.40)alpha-olefin comonomer, and a solvent in the presence of a chain transfer agent and a catalyst system, the catalyst system comprising a metal-ligand complex according to formula (I).

##STR00001##

Processes of polymerizing olefins include contacting ethylene, a (C.sub.3-C.sub.40)alpha-olefin comonomer, and a solvent in the presence of a chain transfer agent and a catalyst system, the catalyst system comprising a metal-ligand complex according to formula (I).

##STR00001##

An object of the present invention is to provide a resin composition and a molded article each having suppressed surface stickiness while having high stress-relaxing ability and vibration-absorbing ability at room temperature. A resin composition (X) containing 10 to 50 parts by mass of a thermoplastic resin (A) and 50 to 90 parts by mass of an inorganic substance (B), wherein a tan δ peak temperature and tan δ peak value, obtained by performing dynamic viscoelastic measurement at a frequency of 10 rad/s (1.6 Hz) in the temperature range of −40 to 150° C., are 0° C. or higher and 60° C. or lower, and 0.8 or more and 5.0 or less, respectively.