The present invention provides an adhesive composition including an ethylene/alpha-olefin copolymer; and a tackifier, wherein the ethylene/alpha-olefin copolymer has narrow molecular weight distribution together with a low density and an ultra low molecular weight, minimized number of unsaturated functional groups, and particularly a small amount of vinylidene among the unsaturated functional groups, thereby showing excellent physical properties.

The present invention provides an adhesive composition including an ethylene/alpha-olefin copolymer; and a tackifier, wherein the ethylene/alpha-olefin copolymer has narrow molecular weight distribution together with a low density and an ultra low molecular weight, minimized number of unsaturated functional groups, and particularly a small amount of vinylidene among the unsaturated functional groups, thereby showing excellent physical properties.

The present invention provides an ethylene/alpha-olefin copolymer satisfying the following conditions (a) to (d): (a) density: 0.850 to 0.910 g/cc, (b) melt index (MI, 190° C., 2.16 kg load conditions): 0.1 to 100 dg/min, (c) molecular weight distribution (MWD): 1.5 to 3.0, and (d) a R.sub.v value of 0.18 to 0.59.

The present invention provides an ethylene/alpha-olefin copolymer satisfying the following conditions (a) to (d): (a) density: 0.850 to 0.910 g/cc, (b) melt index (MI, 190° C., 2.16 kg load conditions): 0.1 to 100 dg/min, (c) molecular weight distribution (MWD): 1.5 to 3.0, and (d) a R.sub.v value of 0.18 to 0.59.

The present invention relates to a polymer comprising moieties derived from ethylene and moieties derived from 1-hexene, wherein the polymer has: (a) a density of ≥910 and ≤930 kg/m.sup.3 as determined in accordance with ASTM D1505 (2010); (b) a melt mass-flow rate of ≥0.5 and ≤5.0 g/10 min, as determined in accordance with ASTM D1238 (2013) at a temperature of 190° C. under a load of 2.16 kg; (c) a fraction that is not eluted in analytical temperature rising elution fractionation (a-TREF) at a temperature ≥30.0° C. of ≥8.0 wt %, with regard to the total weight of the polymer; and (d) a fraction eluted in a-TREF at a temperature ≥94.0° C. of ≥20.0 wt %, with regard to the total weight of the polymer. Such polymer allows for the production of bi-directionally oriented films having a particularly desirable ability to be stretched at a high stretching ratio, in both the machine direction and in the transverse direction, and particularly to be stretched to a high stretching ratio in the machine direction and the transverse direction combined. Further this polymer allows for production of bi-directionally oriented films within a particularly and desirably broad temperature range in which the stretching can be performed without imparting any deficiencies of hampering the film production processes in continuous film production.

The present invention relates to a polymer comprising moieties derived from ethylene and moieties derived from 1-hexene, wherein the polymer has: (a) a density of ≥910 and ≤930 kg/m.sup.3 as determined in accordance with ASTM D1505 (2010); (b) a melt mass-flow rate of ≥0.5 and ≤5.0 g/10 min, as determined in accordance with ASTM D1238 (2013) at a temperature of 190° C. under a load of 2.16 kg; (c) a fraction that is not eluted in analytical temperature rising elution fractionation (a-TREF) at a temperature ≥30.0° C. of ≥8.0 wt %, with regard to the total weight of the polymer; and (d) a fraction eluted in a-TREF at a temperature ≥94.0° C. of ≥20.0 wt %, with regard to the total weight of the polymer. Such polymer allows for the production of bi-directionally oriented films having a particularly desirable ability to be stretched at a high stretching ratio, in both the machine direction and in the transverse direction, and particularly to be stretched to a high stretching ratio in the machine direction and the transverse direction combined. Further this polymer allows for production of bi-directionally oriented films within a particularly and desirably broad temperature range in which the stretching can be performed without imparting any deficiencies of hampering the film production processes in continuous film production.

The present disclosure provides a linear low density polyethylene composition, tapes, fibers and filaments, artificial turfs, and method of making the same. The linear low density polyethylene composition according to the present disclosure exhibits each of the following properties: (1) a CEF fraction from 70 to 90° C. of equal to or greater than 80% of the total CEF fractions; (2) a melt index, I.sub.2, measured according to ASTM D 1238 (2.16 kg @190° C.), in the range of equal to or greater than 2.0 g/10 min and equal to or less than 5.0 g/10 min; and (3) a melt flow ratio, I.sub.10/I.sub.2, of equal to or less than 6.7.

The present disclosure provides a linear low density polyethylene composition, tapes, fibers and filaments, artificial turfs, and method of making the same. The linear low density polyethylene composition according to the present disclosure exhibits each of the following properties: (1) a CEF fraction from 70 to 90° C. of equal to or greater than 80% of the total CEF fractions; (2) a melt index, I.sub.2, measured according to ASTM D 1238 (2.16 kg @190° C.), in the range of equal to or greater than 2.0 g/10 min and equal to or less than 5.0 g/10 min; and (3) a melt flow ratio, I.sub.10/I.sub.2, of equal to or less than 6.7.

Metallocene complexes represented by the structure below are useful for alpha olefin oligomerization in the presence of an activator to generate polyalphaolefins having a high percentage of vinylidene termination and relatively low Mn values.

##STR00001##

M is a group 4 transition metal. A is a bridging group having one bridging atom extending between a first indenyl ring and a second indenyl ring. Each X is independently an anionic ligand, or two Xs are joined and bound to M to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand. R.sup.1, R.sup.1′, R.sup.3, R.sup.3′, R.sup.4, R.sup.4′, R.sup.7 and R.sup.7′ are hydrogen. R.sup.5, R.sup.5′, R.sup.6, and R.sup.6′ are independently a C.sub.1-C.sub.10, optionally substituted, hydrocarbyl group, or R.sup.5 and R.sup.6 and/or R.sup.5′ and R.sup.6′ are bonded together to form an optionally substituted hydrocarbyl ring structure.

Metallocene complexes represented by the structure below are useful for alpha olefin oligomerization in the presence of an activator to generate polyalphaolefins having a high percentage of vinylidene termination and relatively low Mn values.

##STR00001##

M is a group 4 transition metal. A is a bridging group having one bridging atom extending between a first indenyl ring and a second indenyl ring. Each X is independently an anionic ligand, or two Xs are joined and bound to M to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand. R.sup.1, R.sup.1′, R.sup.3, R.sup.3′, R.sup.4, R.sup.4′, R.sup.7 and R.sup.7′ are hydrogen. R.sup.5, R.sup.5′, R.sup.6, and R.sup.6′ are independently a C.sub.1-C.sub.10, optionally substituted, hydrocarbyl group, or R.sup.5 and R.sup.6 and/or R.sup.5′ and R.sup.6′ are bonded together to form an optionally substituted hydrocarbyl ring structure.