The present disclosure provides a composition. In an embodiment, the composition is an ethylene-based polymer composition formed by high pressure (greater or equal to 100 MPa) free radical polymerization. The ethylene-based polymer composition includes ethylene monomer and a mixture of hydroxyl-terminated polybutadiene molecules (PB-OH). Each PB-OH molecule includes internal alkene groups and terminal alkene groups. Each PB-OH molecule has more internal alkene groups than terminal alkene groups.

A composition comprising an ethylene/alpha-olefin interpolymer that comprises the following properties: a) a total unsaturation/1000C≥0.30; b) a molecular weight distribution (MWD)≤3.0; c) a TGIC broadness parameter B.sub.1/4≤8.0. A solution N polymerization process to prepare an ethylene/alpha-olefin/interpolymer, said process comprising polymerizing, in one reactor, at a reactor temperature ≥150° C., a reaction mixture comprising ethylene, an alpha-olefin, a solvent, and a metal complex as described herein. A method to determine the TGIC broadness parameter B.sub.1/x of a polymer composition comprising one or more olefin-based polymers.

A composition comprising an ethylene/alpha-olefin interpolymer that comprises the following properties: a) a total unsaturation/1000C≥0.30; b) a molecular weight distribution (MWD)≤3.0; c) a TGIC broadness parameter B.sub.1/4≤8.0. A solution N polymerization process to prepare an ethylene/alpha-olefin/interpolymer, said process comprising polymerizing, in one reactor, at a reactor temperature ≥150° C., a reaction mixture comprising ethylene, an alpha-olefin, a solvent, and a metal complex as described herein. A method to determine the TGIC broadness parameter B.sub.1/x of a polymer composition comprising one or more olefin-based polymers.

Process for obtaining polyethylene with an MFI (190° C./2.16 kg) of at least 4 g/10 minutes and a melt strength (190° C.) of at least 8.0 cN, said process involving extrusion of low density polyethylene (LDPE) with an MFI of at least 5 g/10 minutes and a vinyl content of less than 0.25 terminal vinyl groups per 1000 C-atoms (measured with NMR in deuterated tetrachloroethane solution)—in the presence of 500-5,000 ppm, based on the weight of low density polyethylene, of an organic peroxide.

Process for obtaining polyethylene with an MFI (190° C./2.16 kg) of at least 4 g/10 minutes and a melt strength (190° C.) of at least 8.0 cN, said process involving extrusion of low density polyethylene (LDPE) with an MFI of at least 5 g/10 minutes and a vinyl content of less than 0.25 terminal vinyl groups per 1000 C-atoms (measured with NMR in deuterated tetrachloroethane solution)—in the presence of 500-5,000 ppm, based on the weight of low density polyethylene, of an organic peroxide.

An object of the present invention is to provide a composition capable of allowing for production of a crosslinked foamed product suitable for applications of footwear parts such as soles and excellent in properties such as lightweight properties, heat shrinkability, compression set and mechanical strength in a well-balanced manner, a foamed product using the composition and a footwear part using the same. An ethylene copolymer composition including an ethylene copolymer (A) satisfying all the following requirements (A-a), (A-b), (A-c) and (A-d), ethylene/α-olefin having 3 to 20 carbon atoms/non-conjugated polyene copolymer rubber (B), and, if necessary, an ethylene/polar monomer copolymer (C); (A-a) a vinyl group content per 1,000 carbon atoms is 0.025 to 0.3, (A-b) MFR.sub.10/MFR.sub.2.16 is 7 to 20, (A-c) a density is 0.850 to 0.910 g/cm.sup.3, and (A-d) a melt flow rate is 0.01 to 200 g/10 min.

An object of the present invention is to provide a composition capable of allowing for production of a crosslinked foamed product suitable for applications of footwear parts such as soles and excellent in properties such as lightweight properties, heat shrinkability, compression set and mechanical strength in a well-balanced manner, a foamed product using the composition and a footwear part using the same. An ethylene copolymer composition including an ethylene copolymer (A) satisfying all the following requirements (A-a), (A-b), (A-c) and (A-d), ethylene/α-olefin having 3 to 20 carbon atoms/non-conjugated polyene copolymer rubber (B), and, if necessary, an ethylene/polar monomer copolymer (C); (A-a) a vinyl group content per 1,000 carbon atoms is 0.025 to 0.3, (A-b) MFR.sub.10/MFR.sub.2.16 is 7 to 20, (A-c) a density is 0.850 to 0.910 g/cm.sup.3, and (A-d) a melt flow rate is 0.01 to 200 g/10 min.

The present disclosure provides an ethylene-based polymer composition formed by high pressure (greater or equal to 100 MPa) free radical polymerization. The ethylene-based polymer composition includes ethylene monomer and a mixture of hydrocarbon-based molecules, each hydrocarbon-based molecule comprising three or more terminal alkene groups. The ethylene-based polymer has a melt index (MI) from 0.1 to 1.0 g/10 min.

The present disclosure provides an ethylene-based polymer composition formed by high pressure (greater or equal to 100 MPa) free radical polymerization. The ethylene-based polymer composition includes ethylene monomer and a mixture of hydrocarbon-based molecules, each hydrocarbon-based molecule comprising three or more terminal alkene groups. The ethylene-based polymer has a melt index (MI) from 0.1 to 1.0 g/10 min.

A semicrystalline plastic composition comprising: a semicrystalline plastic and an additive dispersed therein. The semicrystalline plastic includes a polymeric chain comprising repeat units of an oligomeric or polymeric chain and the additive comprises a supramolecular building block and an oligomeric or polymeric tail. The oligomeric or polymeric tail of the additive having the same repeat units as the polymeric chain of the semicrystalline plastic. The additive forming a plurality of sheet-like structures through hydrogen bonding. The sheet-like structures, interacting through non-covalent interaction, form crystallized additive domains within the semicrystalline plastic.