Provided is a copolymer consisting essentially of ethylene units, tetrafluoroethylene units, and hexafluoropropylene units, wherein a molar ratio (Et units/TFE units) of the ethylene (Et) units to the tetrafluoroethylene (TFE) units is 52.0/48.0 to 56.0/44.0, and a content of the hexafluoropropylene units is 19.0 to 21.0 mol % based on the total monomer units constituting the copolymer.

Provided is a copolymer consisting essentially of ethylene units, tetrafluoroethylene units, and hexafluoropropylene units, wherein a molar ratio (Et units/TFE units) of the ethylene (Et) units to the tetrafluoroethylene (TFE) units is 52.0/48.0 to 56.0/44.0, and a content of the hexafluoropropylene units is 19.0 to 21.0 mol % based on the total monomer units constituting the copolymer.

What is disclosed is a Ziegler-Natta catalyzed ethylene and alpha-olefin LLDPE copolymer having a unique composition distribution and long chain-branching. The polymers of the present invention inherently exhibit outstanding melt strength with great bubble stability, sufficient flexibility, excellent gel performance, as well as desirable mechanical properties such as balanced toughness and stiffness, which are desirable properties for thick gauge film applications. Specifically, the polymers of the present invention.

What is disclosed is a Ziegler-Natta catalyzed ethylene and alpha-olefin LLDPE copolymer having a unique composition distribution and long chain-branching. The polymers of the present invention inherently exhibit outstanding melt strength with great bubble stability, sufficient flexibility, excellent gel performance, as well as desirable mechanical properties such as balanced toughness and stiffness, which are desirable properties for thick gauge film applications. Specifically, the polymers of the present invention.

The invention is directed to a beta nucleated heterophasic propylene copolymer composition (HPPC).

The invention is directed to a beta nucleated heterophasic propylene copolymer composition (HPPC).

Processes for forming a polypropylene composition are provided herein comprising the steps of making a first propylene-based copolymer having a molecular weight distribution between 3 to 8.5, and making a second propylene-based polymer in the presence of the first propylene-based polymer to produce the polypropylene composition having a high molecular weight tail in the amount of between 1.0 wt. % and 10.0 wt. %. The polypropylene compositions produced have a broad molecular weight distribution and high molecular weight tail to provide improved stiffness while retaining toughness.

Processes for forming a polypropylene composition are provided herein comprising the steps of making a first propylene-based copolymer having a molecular weight distribution between 3 to 8.5, and making a second propylene-based polymer in the presence of the first propylene-based polymer to produce the polypropylene composition having a high molecular weight tail in the amount of between 1.0 wt. % and 10.0 wt. %. The polypropylene compositions produced have a broad molecular weight distribution and high molecular weight tail to provide improved stiffness while retaining toughness.

Provided herein are methods of polymerizing α-olefin monomer with a catalyst and hydrogen in a slurry to produce low molecular weight polyolefins. Hydrogen is vented from the low molecular weight polyolefins and then the low molecular weight polyolefins are further polymerized in a gas phase to produce a polyolefin having a molecular weight distribution of between 4.0 and 30 and a flexural modulus between 1500 mPa and 2500 mPa.

Provided herein are methods of polymerizing α-olefin monomer with a catalyst and hydrogen in a slurry to produce low molecular weight polyolefins. Hydrogen is vented from the low molecular weight polyolefins and then the low molecular weight polyolefins are further polymerized in a gas phase to produce a polyolefin having a molecular weight distribution of between 4.0 and 30 and a flexural modulus between 1500 mPa and 2500 mPa.