C08F2500/32

Multiple non-coordinating anion activators for propylene-ethylene-diene monomer polymerization reactions

This invention relates to production of propylene-predominant copolymers using a transition metal complex and at least two different non-coordinating anion activators. An olefinic feed comprising a C.sub.3-C.sub.40 alpha olefin, ethylene, and a diene monomer is contacted under polymerization reaction conditions with a catalyst system comprising a first non-coordinating anion activator, a second non-coordinating borate activator differing from the first non-coordinating anion activator, and a transition metal complex comprising a tetrahydro-s-indacenyl or tetrahydro-as-indacenyl group bound to a group 3-6 transition metal. A molar ratio of the first non-coordinating anion activator to the second non-coordinating anion activator is sufficient to produce a melt flow rate under the polymerization reaction conditions for the resulting copolymer of about 30 g/10 min or below as determined by ASTM D-1238 (230 C., 2.16 kg).

Multiple non-coordinating anion activators for propylene-ethylene-diene monomer polymerization reactions

This invention relates to production of propylene-predominant copolymers using a transition metal complex and at least two different non-coordinating anion activators. An olefinic feed comprising a C.sub.3-C.sub.40 alpha olefin, ethylene, and a diene monomer is contacted under polymerization reaction conditions with a catalyst system comprising a first non-coordinating anion activator, a second non-coordinating borate activator differing from the first non-coordinating anion activator, and a transition metal complex comprising a tetrahydro-s-indacenyl or tetrahydro-as-indacenyl group bound to a group 3-6 transition metal. A molar ratio of the first non-coordinating anion activator to the second non-coordinating anion activator is sufficient to produce a melt flow rate under the polymerization reaction conditions for the resulting copolymer of about 30 g/10 min or below as determined by ASTM D-1238 (230 C., 2.16 kg).

OPTICAL LENS

The optical lens of the present invention contains a molded product constituted with a cyclic olefin-based copolymer having a constitutional unit (A) derived from an -olefin having 2 to 20 carbon atoms, a constitutional unit (B) derived from a cyclic olefin, and a constitutional unit (C) derived from an aromatic vinyl compound represented by a specific chemical formula.

OPTICAL LENS

The optical lens of the present invention contains a molded product constituted with a cyclic olefin-based copolymer having a constitutional unit (A) derived from an -olefin having 2 to 20 carbon atoms, a constitutional unit (B) derived from a cyclic olefin, and a constitutional unit (C) derived from an aromatic vinyl compound represented by a specific chemical formula.

Processes for producing high propylene content PEDM having low glass transition temperatures using tetrahydroindacenyl catalyst systems

The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene-diene terpolymer typically comprising from 30 to 55 mol % ethylene, from 69.09 to 45 mol % C.sub.3 to C.sub.40 comonomer, and from 0.01 to 7 mol % diene wherein the Tg of the terpolymer is 28 C. or less. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.

Processes for producing high propylene content PEDM having low glass transition temperatures using tetrahydroindacenyl catalyst systems

The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene-diene terpolymer typically comprising from 30 to 55 mol % ethylene, from 69.09 to 45 mol % C.sub.3 to C.sub.40 comonomer, and from 0.01 to 7 mol % diene wherein the Tg of the terpolymer is 28 C. or less. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.

COPOLYMER OF ETHYLENE AND OF MYRCENE

A copolymer of ethylene and of myrcene, in which the ethylene units represent between 50 mol % and 95 mol % of the ethylene units and of the myrcene units, and the myrcene units of 1,2 and 3,4 configuration represent more than 50 mol % of the myrcene units, is provided. Such a copolymer exhibits an improved compromise between the degree of crystallinity and the stiffness. It therefore makes it possible to widen the field of application of ethylene-rich diene copolymers in rubber compositions, and also to increase the production capacity of a unit for the synthesis of ethylene-rich diene polymers.

COPOLYMER OF ETHYLENE AND OF MYRCENE

A copolymer of ethylene and of myrcene, in which the ethylene units represent between 50 mol % and 95 mol % of the ethylene units and of the myrcene units, and the myrcene units of 1,2 and 3,4 configuration represent more than 50 mol % of the myrcene units, is provided. Such a copolymer exhibits an improved compromise between the degree of crystallinity and the stiffness. It therefore makes it possible to widen the field of application of ethylene-rich diene copolymers in rubber compositions, and also to increase the production capacity of a unit for the synthesis of ethylene-rich diene polymers.

ETHYLENE/ALPHA-OLEFIN INTERPOLYMER COMPOSITIONS WITH IMPROVED LONG TERM HEAT AGING PERFORMANCE
20200399456 · 2020-12-24 ·

A first composition comprising a first ethylene/-olefin/diene interpolymer and a second ethylene/-olefin interpolymer, and wherein the first composition comprises from 0.1 to 1.0 wt % diene, based on the weight of the first composition, and wherein the first composition comprises from 40 to 70 wt % ethylene, based on the weight of the first composition.

ETHYLENE/ALPHA-OLEFIN INTERPOLYMER COMPOSITIONS WITH IMPROVED LONG TERM HEAT AGING PERFORMANCE
20200399456 · 2020-12-24 ·

A first composition comprising a first ethylene/-olefin/diene interpolymer and a second ethylene/-olefin interpolymer, and wherein the first composition comprises from 0.1 to 1.0 wt % diene, based on the weight of the first composition, and wherein the first composition comprises from 40 to 70 wt % ethylene, based on the weight of the first composition.