Patent classifications
C08F2500/32
CYCLIC OLEFIN-BASED COPOLYMER, CYCLIC OLEFIN-BASED COPOLYMER COMPOSITION, MOLDED ARTICLE, AND MEDICAL CONTAINER
Described is a cyclic olefin-based copolymer has a constitutional unit (A) derived from an α-olefin having 2 to 20 carbon atoms, a constitutional unit (B) derived from a cyclic olefin without an aromatic ring, and a constitutional unit (C) derived from a cyclic olefin having an aromatic ring. Also described is a medical container containing a cyclic olefin-based copolymer having a constitutional unit (A) derived from an α-olefin having 2 to 20 carbon atoms, a constitutional unit (B) derived from a cyclic olefin without an aromatic ring, and a constitutional unit (C) derived from a cyclic olefin having an aromatic ring.
Processes for producing high propylene content PEDM having low glass transition temperatures using tetrahydroindacenyl catalyst systems
The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene-diene terpolymer typically comprising from 30 to 55 mol % ethylene, from 69.09 to 45 mol % C.sub.3 to C.sub.40 comonomer, and from 0.01 to 7 mol % diene wherein the Tg of the terpolymer is −28° C. or less. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.
Processes for producing high propylene content PEDM having low glass transition temperatures using tetrahydroindacenyl catalyst systems
The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene-diene terpolymer typically comprising from 30 to 55 mol % ethylene, from 69.09 to 45 mol % C.sub.3 to C.sub.40 comonomer, and from 0.01 to 7 mol % diene wherein the Tg of the terpolymer is −28° C. or less. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.
Rubber composition and tire
Provided is a rubber composition that can achieve excellent breaking resistance while having high operability. A rubber composition comprises: a rubber component containing a multicomponent copolymer that contains a conjugated diene unit, a non-conjugated olefin unit, and an aromatic vinyl unit; and an α-olefin having a number-average molecular weight (Mn) of 50 to 1,000.
Rubber composition and tire
Provided is a rubber composition that can achieve excellent breaking resistance while having high operability. A rubber composition comprises: a rubber component containing a multicomponent copolymer that contains a conjugated diene unit, a non-conjugated olefin unit, and an aromatic vinyl unit; and an α-olefin having a number-average molecular weight (Mn) of 50 to 1,000.
SYNDIOTACTIC PROPYLENE-BASED ETHYLENE- PROPYLENE COPOLYMERS
Provided is syndiotactic polypropylene-based ethylene-propylene copolymers comprising a) 5 to 15% by weight of ethylene and 85 to 95% by weight of propylene; b) 60 to 90% rr triads; c) Mw (LS) of 10 to 250 kg/mol; and d) no substantial melting peak, wherein the heat of fusion of the peak is 5 J/g or less as determined by differential scanning calorimetry at a scan rate of 10° C./min (ASTM D3418-03).
SYNDIOTACTIC PROPYLENE-BASED ETHYLENE- PROPYLENE COPOLYMERS
Provided is syndiotactic polypropylene-based ethylene-propylene copolymers comprising a) 5 to 15% by weight of ethylene and 85 to 95% by weight of propylene; b) 60 to 90% rr triads; c) Mw (LS) of 10 to 250 kg/mol; and d) no substantial melting peak, wherein the heat of fusion of the peak is 5 J/g or less as determined by differential scanning calorimetry at a scan rate of 10° C./min (ASTM D3418-03).
MOLDED PRODUCT COMPRISING POLARIZED OLEFIN-BASED POLYMER AND PROPERTY THEREOF
The object of the invention is to provide a novel olefin-based molded product useful for various applications.
An olefin-based molded product comprising a polymer including a structural unit of at least one polar olefin monomer represented by the general formula (I) CH2=CH—R.sup.2—Z(R.sup.1)n is provided. In the formula, Z is a hetero atom selected from the group consisting of nitrogen, oxygen, phosphorus, sulfur, and selenium; R.sup.1 is a substituted or unsubstituted hydrocarbyl group having 1 to 30 carbon atoms; n is an integer of 1 or 2 depending on the atomic species of Z; and R.sup.2 is a substituted or unsubstituted hydrocarbylene group having 2 to 20 carbon atoms.
MOLDED PRODUCT COMPRISING POLARIZED OLEFIN-BASED POLYMER AND PROPERTY THEREOF
The object of the invention is to provide a novel olefin-based molded product useful for various applications.
An olefin-based molded product comprising a polymer including a structural unit of at least one polar olefin monomer represented by the general formula (I) CH2=CH—R.sup.2—Z(R.sup.1)n is provided. In the formula, Z is a hetero atom selected from the group consisting of nitrogen, oxygen, phosphorus, sulfur, and selenium; R.sup.1 is a substituted or unsubstituted hydrocarbyl group having 1 to 30 carbon atoms; n is an integer of 1 or 2 depending on the atomic species of Z; and R.sup.2 is a substituted or unsubstituted hydrocarbylene group having 2 to 20 carbon atoms.
PRODUCTION METHOD FOR CYCLIC OLEFIN COPOLYMER AND CATALYST COMPOSITION FOR COPOLYMERIZATION OF NORBORNENE MONOMER AND ETHYLENE
A production method for a cyclic olefin copolymer which is capable of efficiently producing a cyclic olefin copolymer by copolymerizing monomers including a norbornene monomer and ethylene while suppressing the formation of a polyethylene-like impurity, and a catalyst composition for the copolymerization of a norbornene monomer and ethylene. Monomers including a norbornene monomer and ethylene are polymerized in the presence of a metal-containing catalyst, and the metal-containing catalyst has a structure in which a nitrogen atom is bonded to a transition metal of Group 4 of the periodic table and an atom of Group 15 of the periodic table.