The present invention is directed towards random-heterophasic propylene copolymers with a specific ratio of stiffness to impact balance and specific relation between glass transition temperature and comonomer content. The invention is further directed to articles comprising said random-heterophasic propylene copolymer and their use.

Provided is a polyfunctional vinyl aromatic copolymer having reactivity and solubility that can be used for manufacturing a copolymer rubber and a copolymer rubber material having processability, strength and homogeneity obtained therefrom. The polyfunctional vinyl aromatic copolymer includes: 0.5 mol % or more and 40 mol % or less of a structural unit (a) derived from a divinyl aromatic compound and 60 mol % or more and 99.5 mol % or less of a structural unit (b) derived from a monovinyl aromatic compound, in which at least some of the structural units (a) are a crosslinked structural unit (a2) represented by the following Formula (2) and a vinyl-group-containing structural unit (a1) represented by the following Formula (1):

##STR00001##

in the formulas, R.sup.1's independently represent an aromatic hydrocarbon group having 6 to 30 carbon atoms.

Provided is a polyfunctional vinyl aromatic copolymer having reactivity and solubility that can be used for manufacturing a copolymer rubber and a copolymer rubber material having processability, strength and homogeneity obtained therefrom. The polyfunctional vinyl aromatic copolymer includes: 0.5 mol % or more and 40 mol % or less of a structural unit (a) derived from a divinyl aromatic compound and 60 mol % or more and 99.5 mol % or less of a structural unit (b) derived from a monovinyl aromatic compound, in which at least some of the structural units (a) are a crosslinked structural unit (a2) represented by the following Formula (2) and a vinyl-group-containing structural unit (a1) represented by the following Formula (1):

##STR00001##

in the formulas, R.sup.1's independently represent an aromatic hydrocarbon group having 6 to 30 carbon atoms.

4-methyl-1-pentene based resin foam containing a 4-methyl-1-pentene based resin, and having an expansion ratio of 3 times or more is prepared. When measured in a decalin solvent at 135° C., an intrinsic viscosity [η] of the 4-methyl-1-pentene based resin may be 0.5 to 5 dl/g. The 4-methyl-1-pentene based resin may have a glass transition temperature of 0° C. to 80° C. The 4-methyl-1-pentene based resin may have a melting point. The 4-methyl-1-pentene based resin may be a 4-methyl-1-pentene/C.sub.2-20α-olefin copolymer (in particular, 4-methyl-1-pentene/C.sub.2-4α-olefin copolymer). The expansion ratio of the 4-methyl-1-pentene based resin foam may be 10 times or greater.

4-methyl-1-pentene based resin foam containing a 4-methyl-1-pentene based resin, and having an expansion ratio of 3 times or more is prepared. When measured in a decalin solvent at 135° C., an intrinsic viscosity [η] of the 4-methyl-1-pentene based resin may be 0.5 to 5 dl/g. The 4-methyl-1-pentene based resin may have a glass transition temperature of 0° C. to 80° C. The 4-methyl-1-pentene based resin may have a melting point. The 4-methyl-1-pentene based resin may be a 4-methyl-1-pentene/C.sub.2-20α-olefin copolymer (in particular, 4-methyl-1-pentene/C.sub.2-4α-olefin copolymer). The expansion ratio of the 4-methyl-1-pentene based resin foam may be 10 times or greater.

Provided is a cyclic olefin-based resin composition including a cyclic olefin-based polymer (A), and a hindered amine compound (Y) that contains a piperidyl group represented by General Formula (1) and a carboxylic acid amide group represented by General Formula (2) within the same molecule.

##STR00001##

The present disclosure relates to poly(alpha-olefin)s and methods for making poly(alpha-olefin)s. A poly(alpha-olefin) may include about 95 wt % or greater C.sub.10-C.sub.18 alpha-olefin content and have a weight average molecular weight of from about 1,000,000 g/mol to about 10,000,000 g/mol. A method for forming a poly(alpha-olefin) may include introducing one or more C.sub.10-C.sub.18 alpha-olefins to a catalyst system comprising a catalyst compound and an activator. The method may include obtaining poly(alpha-olefin)s comprising about 95 wt % or greater C.sub.10-C.sub.18 alpha-olefin content and having a weight average molecular weight of from about 1,000,000 g/mol to about 10,000,000 g/mol.

The present disclosure relates to poly(alpha-olefin)s and methods for making poly(alpha-olefin)s. A poly(alpha-olefin) may include about 95 wt % or greater C.sub.10-C.sub.18 alpha-olefin content and have a weight average molecular weight of from about 1,000,000 g/mol to about 10,000,000 g/mol. A method for forming a poly(alpha-olefin) may include introducing one or more C.sub.10-C.sub.18 alpha-olefins to a catalyst system comprising a catalyst compound and an activator. The method may include obtaining poly(alpha-olefin)s comprising about 95 wt % or greater C.sub.10-C.sub.18 alpha-olefin content and having a weight average molecular weight of from about 1,000,000 g/mol to about 10,000,000 g/mol.

This invention relates bisindenyl metallocene catalyst compounds having long (at least 4 carbon atoms) linear alkyl groups substituted at the two position and substituted or unsubstituted aryl groups at the four position and process using such catalyst compounds, particularly in the solution process at higher temperatures.

This invention relates bisindenyl metallocene catalyst compounds having long (at least 4 carbon atoms) linear alkyl groups substituted at the two position and substituted or unsubstituted aryl groups at the four position and process using such catalyst compounds, particularly in the solution process at higher temperatures.