This invention relates homogeneous (typically solution) polymerization of propylene and optional olefin comonomer using metallocene catalyst compounds having a 1,5,6,7-tetrahydro-s-indacenyl moiety bridged to another indacenyl moiety or bridged to a substituted or unsubstituted indenyl moiety.

This invention relates homogeneous (typically solution) polymerization of propylene and optional olefin comonomer using metallocene catalyst compounds having a 1,5,6,7-tetrahydro-s-indacenyl moiety bridged to another indacenyl moiety or bridged to a substituted or unsubstituted indenyl moiety.

The present disclosure relates to comb-block copolymers and methods thereof. In some embodiments, a copolymer includes a first block comprising an ethylene-propylene copolymer; and a second block comprising a high density polyethylene. In some embodiments, a polyethylene composition includes the copolymer and a branched vinyl/vinylidene-terminated high density polyethylene. In some embodiments, a process for producing a polyethylene composition includes polymerizing ethylene, at a temperature of at least 100° C., by introducing the ethylene to a first catalyst system having a first catalyst compound and a first activator to form a branched vinyl/vinylidene-terminated high density polyethylene. The process includes introducing the branched vinyl/vinylidene-terminated high density polyethylene to additional ethylene, propylene, and a second catalyst system having a second catalyst compound and a second activator. The process includes obtaining the polyethylene composition.

The present disclosure relates to comb-block copolymers and methods thereof. In some embodiments, a copolymer includes a first block comprising an ethylene-propylene copolymer; and a second block comprising a high density polyethylene. In some embodiments, a polyethylene composition includes the copolymer and a branched vinyl/vinylidene-terminated high density polyethylene. In some embodiments, a process for producing a polyethylene composition includes polymerizing ethylene, at a temperature of at least 100° C., by introducing the ethylene to a first catalyst system having a first catalyst compound and a first activator to form a branched vinyl/vinylidene-terminated high density polyethylene. The process includes introducing the branched vinyl/vinylidene-terminated high density polyethylene to additional ethylene, propylene, and a second catalyst system having a second catalyst compound and a second activator. The process includes obtaining the polyethylene composition.

Blown films, especially monolayer blown films, of high stiffness, the blown films comprising at least 95.0 wt % of a specific propylene-1-butene random copolymer.

Blown films, especially monolayer blown films, of high stiffness, the blown films comprising at least 95.0 wt % of a specific propylene-1-butene random copolymer.

A polymeric composition including in weight percent of the polymeric composition: (a) 10 wt % to 30 wt % of a polyolefin elastomer; (b) 1 wt % to 20 wt % of a polypropylene-based polymer; (c) greater than 1 wt % to 20 wt % of a crystalline block composite; (d) 1 wt % to 10 wt % of a maleated polyolefin elastomer; and (e) 40 wt % to 80 wt % of a halogen free flame-retardant filler.

The present invention relates to an olefin-based polymer satisfying conditions as follow: (1) a melt index (MI, 190° C., 2.16 kg load conditions) is from 0.1 g/10 min to 10.0 g/10 min, (2) a density (d) is from 0.860 g/cc to 0.880 g/cc, and (3) T(90)−T(50)≤50 and T(95)−T(90)≥10 are satisfied when measured by a differential scanning calorimetry precise measurement method (SSA). The olefin-based polymer according to the present invention is a low-density olefin-based polymer introducing a highly crystalline region and showing high mechanical rigidity.

The present invention relates to an olefin-based polymer satisfying conditions as follow: (1) a melt index (MI, 190° C., 2.16 kg load conditions) is from 0.1 g/10 min to 10.0 g/10 min, (2) a density (d) is from 0.860 g/cc to 0.880 g/cc, and (3) T(90)−T(50)≤50 and T(95)−T(90)≥10 are satisfied when measured by a differential scanning calorimetry precise measurement method (SSA). The olefin-based polymer according to the present invention is a low-density olefin-based polymer introducing a highly crystalline region and showing high mechanical rigidity.

The present disclosure provides a process. In an embodiment, the process includes contacting ethylene and butene under polymerization conditions at a temperature greater than 125C with a catalyst system. The catalyst system includes (i) a first polymerization catalyst having the structure of Formula (III), (ii) a second polymerization catalyst having the structure of Formula (I), and (iii) a chain shuttling agent. The process includes forming an ethylene/butene multi-block copolymer having LCB/1000C greater than or equal to 0.06. The present disclosure provides the resultant composition produced by the process. In an embodiment, the composition includes an ethylene/butene multi-block copolymer having LCB/1000C greater than or equal to 0.06.